scholarly journals Performance and fuel cell applications of reacted ball-milled MgH2/5.3 wt% TiH2 nanocomposite powders

RSC Advances ◽  
2018 ◽  
Vol 8 (67) ◽  
pp. 38175-38185 ◽  
Author(s):  
Mohamed Sherif El-Eskandarany ◽  
Abdullah Alkandary ◽  
Fahad Aldakheel ◽  
Mariam Al-Saidi ◽  
Fahad Al-Ajmi ◽  
...  

The present study aimed to enhance the kinetics behavior and destabilize the thermal stability of MgH2 powder by high-energy milling of Mg powder under 50 bar of H2 for several hours using Ti-balls as the milling media.

RSC Advances ◽  
2020 ◽  
Vol 10 (43) ◽  
pp. 25717-25720
Author(s):  
Albina A. Valeeva ◽  
Svetlana Z. Nazarova ◽  
Hartmuth Schröttner ◽  
Evgeny Yu. Gerasimov ◽  
Andrey A. Rempel

The effect of high-energy milling and long-term annealing on the stability of Ti2O3 nanocrystals was studied using a magnetic susceptibility method.


1998 ◽  
pp. 236-251 ◽  
Author(s):  
A.I. Balabanovich ◽  
W. Schnabel ◽  
G.F. Levchik ◽  
S.V. Levchik ◽  
C.A. Wilkie

Membranes ◽  
2020 ◽  
Vol 10 (12) ◽  
pp. 426
Author(s):  
Murli Manohar ◽  
Dukjoon Kim

This present work focused on the aromatic polymer (poly (1,4-phenylene ether-ether-sulfone); SPEES) interconnected/ cross-linked with the aliphatic monomer (2-acrylamido-2-methyl-1-propanesulfonic; AMPS) with the sulfonic group to enhance the conductivity and make it flexible with aliphatic chain of AMPS. Surprisingly, it produced higher conductivity than that of other reported work after the chemical stability was measured. It allows optimizing the synthesis of polymer electrolyte membranes with tailor-made combinations of conductivity and stability. Membrane structure is characterized by 1H NMR and FT-IR. Weight loss of the membrane in Fenton’s reagent is not too high during the oxidative stability test. The thermal stability of the membrane is characterized by TGA and its morphology by SEM and SAXS. The prepared membranes improved proton conductivity up to 0.125 Scm−1 which is much higher than that of Nafion N115 which is 0.059 Scm−1. Therefore, the SPEES-AM membranes are adequate for fuel cell at 50 °C with reduced relative humidity (RH).


2010 ◽  
Vol 645-648 ◽  
pp. 439-442 ◽  
Author(s):  
Michael Weidner ◽  
Lia Trapaidze ◽  
Gerhard Pensl ◽  
Sergey A. Reshanov ◽  
Adolf Schöner ◽  
...  

Intrinsic defects in 3C-SiC are generated by implantation of H+- and He+-ions or irra¬diation with high energy electrons. The defect parameters and the thermal stability of the observed defects are determined. The capture-cross-section of the W6-center is directly measured by variation of the filling pulse length. The charge state of the W6-center is obtained from double-correlated DLTS investigations according to the Poole-Frenkel effect.


2016 ◽  
Vol 9 ◽  
pp. 82-89
Author(s):  
Maya Radune ◽  
Michael Zinigrad ◽  
David Fuks ◽  
S. Hayun ◽  
Nachum Frage

Supersaturated titanium-aluminum nitride (Ti1-xAlxN) is a very attractive material for a wide range of applications due to its high oxidation and wear resistance accompanied by high strength, hardness, thermal conductivity and thermal shock resistance. Currently, its applications are limited to coatings obtained by physical or chemical deposition. Bulk materials based on Ti1-xAlxN may be fabricated by powder metallurgy approach using powders synthesized by high-energy ball milling (HEBM), which composition corresponds to supersaturated Ti1-xAlxN solid solution. In the present study, thermal stability of the supersaturated Ti1-xAlxN solid solution was investigated. According to the quasi-binary TiN-AlN phase diagram, constructed using density functional theory (DFT) analysis, the concentration ranges, where decomposition takes place through spinodal decomposition or through nucleation and growth, were determined. Experimental study on thermal stability of solid Ti1-xAlxN solution powder was conducted by means of differential scanning calorimetry (DSC), Brunauer-Emmited-Teller (BET) and XRD. The results indicated that spinodal decomposition of Ti1-xAlxN starts at 800°C, while at temperature higher than 1300°C regular decomposition (nucleation and growth) is occur.


2018 ◽  
Vol 11 (5) ◽  
pp. 1271-1279 ◽  
Author(s):  
U.-H. Kim ◽  
D.-W. Jun ◽  
K.-J. Park ◽  
Q. Zhang ◽  
P. Kaghazchi ◽  
...  

W-doping produced the two-phase (Fm3̄m and R3̄m) structure which improved the cycling and thermal stability of the Ni-rich layered cathodes.


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