Synthesis of α,β-unsaturated esters of perfluoropolyalkylethers (PFPAEs) based on hexafluoropropylene oxide units for photopolymerization

Céline Bonneaud; Mélanie Decostanzi; Julia Burgess; Giuseppe Trusiano; Trevor Burgess; Roberta Bongiovanni; Christine Joly-Duhamel; Chadron M. Friesen

doi:10.1039/c8ra06354k

Synthesis of α,β-unsaturated esters of perfluoropolyalkylethers (PFPAEs) based on hexafluoropropylene oxide units for photopolymerization

RSC Advances ◽

10.1039/c8ra06354k ◽

2018 ◽

Vol 8 (57) ◽

pp. 32664-32671 ◽

Cited By ~ 5

Author(s):

Céline Bonneaud ◽

Mélanie Decostanzi ◽

Julia Burgess ◽

Giuseppe Trusiano ◽

Trevor Burgess ◽

...

Keyword(s):

Uv Curable ◽

Unsaturated Esters ◽

Steglich Esterification ◽

Hexafluoropropylene Oxide

Hydrophobic macromonomers synthesized by Steglich esterification to generate UV-curable materials.

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Correction: Synthesis of α,β-unsaturated esters of perfluoropolyalkylethers (PFPAEs) based on hexafluoropropylene oxide units for photopolymerization

RSC Advances ◽

10.1039/d0ra90036b ◽

2020 ◽

Vol 10 (30) ◽

pp. 17416-17417

Author(s):

Céline Bonneaud ◽

Mélanie Decostanzi ◽

Julia Burgess ◽

Giuseppe Trusiano ◽

Trevor Burgess ◽

...

Keyword(s):

Unsaturated Esters ◽

Hexafluoropropylene Oxide

Correction for ‘Synthesis of α,β-unsaturated esters of perfluoropolyalkylethers (PFPAEs) based on hexafluoropropylene oxide units for photopolymerization’ by Céline Bonneaud et al., RSC Adv., 2018, 8, 32664–32671.

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UV Curable Organic-Inorganic Hybrid Materials

MRS Proceedings ◽

10.1557/proc-628-cc6.14 ◽

2000 ◽

Vol 628 ◽

Cited By ~ 1

Author(s):

Guang-Way Jang ◽

Ren-Jye Wu ◽

Yuung-Ching Sheen ◽

Ya-Hui Lin ◽

Chi-Jung Chang

Keyword(s):

Hybrid Materials ◽

Colloidal Silica ◽

Sol Gel ◽

Solution Ph ◽

Uv Curable ◽

Inorganic Hybrid ◽

Degradation Temperature ◽

Sol Gel Process ◽

The Stability ◽

Thermal Degradation Temperature

This work successfully prepared an UV curable organic-inorganic hybrid material consisting of organic modified colloidal silica. Applications of UV curable organic-inorganic hybrid materials include abrasion resistant coatings, photo-patternable thin films and waveguides. Colloidal silica containing reactive functional groups were also prepared by reacting organic silane and tetraethyl orthosilicate (TEOS) using sol-gel process. In addition, the efficiency of grafting organic moiety onto silica nanoparticles was investigated by applying TGA and FTIR techniques. Experimental results indicated a strong interdependence between surface modification efficiency and solution pH. Acrylate-SiO2 hybrid formation could result in a shifting of thermal degradation temperature of organic component from about 200°C to near 400°C. In addition, the stability of organic modified colloidal silica in UV curable formula and the physical properties of resulting coatings were discussed. Furthermore, the morphology of organic modified colloidal silica was investigated by performing TEM and SEM studies‥

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