scholarly journals Correlation between electrochemical properties and stress corrosion cracking of super 13Cr under an HTHP CO2 environment

RSC Advances ◽  
2018 ◽  
Vol 8 (43) ◽  
pp. 24679-24689 ◽  
Author(s):  
Xiaoqi Yue ◽  
Mifeng Zhao ◽  
Lei Zhang ◽  
Huijuan Zhang ◽  
Dapeng Li ◽  
...  

The degradation of a surface film induces pitting corrosion, which further increases SCC susceptibility.

CORROSION ◽  
1981 ◽  
Vol 37 (2) ◽  
pp. 104-115 ◽  
Author(s):  
T. M. Devine ◽  
B. J. Drummond

Abstract The ability of various intergranular corrosion and pitting corrosion tests to detect sensitization and intergranular stress corrosion cracking susceptibility in high temperature water of duplex 308 stainless steel was evaluated. The duplex alloy contained 10 v/o ferrite and had a specific austenite-ferrite interfacial area of 930 cm2/cm3. The intergranular corrosion resistance of the alloy following 30 different aging treatments was determined in boiling acidified CU-CUSO4 solution (A262E), boiling 65% HNO3 (A262C), and by an electrolytic etch test in 10% oxalic acid (A262A). The pitting corrosion resistance was evaluated by potentiodynamic and galvanostatic tests in 0.1 N HCl at room temperature. The results of all five tests were compared to the results of slow extension rate stress corrosion cracking tests conducted at 550 F in high purity water containing 8 ppm dissolved oxygen. The microstructural features responsible for the corrosion in each test were determined. The A262E test was found to attack the chromium depleted zones in the material. The A262C test preferentially corroded the chromium depleted zones but also dissolved, albeit to a much less extent, the chromium rich phases such as M23C6. The A262A test primarily attacked chromium rich phases. Pitting corrosion was confined to the chromium depleted zones. The results of the A262E test and the galvanostatic pitting test agreed quite closely with the results of the stress corrosion cracking test. There was considerable scatter in the weight loss measurements obtained in the A262C test. The latter could detect the presence of a severely sensitized microstructure but was incapable of distinguishing between mildly sensitized and unsensitized materials. Although pitting was largely confined to the chromium depleted boundaries, unless the sample was severely sensitized, there was considerable scatter in the measured values of the pitting potential. This precluded the use of the latter as a parameter to characterize the degree of sensitization. The A262A test results exhibited the least correlation with the results of the stress corrosion cracking tests. Since the A262A test attacks chromium rich phases such as M23C6, samples which were aged long enough to intergranularly precipitate M23C6 but not long enough to produce chromium depleted zones of sufficient width or contiguity, nevertheless were severely corroded in the A262A test. And samples which were aged long enough to replenish the chromium depleted zones still failed the A262A test because of the continued presence of the chromium rich grain boundary carbides. These tests were also conducted on samples of sensitized and unsensitized austenitic 308 stainless steel. The results were consistent with the findings of the duplex alloy tests.


2020 ◽  
Vol MA2020-02 (12) ◽  
pp. 1268-1268
Author(s):  
Vinicio Ynciarte Leiva ◽  
Leonardo Caseres ◽  
James Dante ◽  
Brendy Carolina Rincon Troconis

2011 ◽  
Vol 1 (2) ◽  
Author(s):  
S. Sujita

The aim of this study is to investigate the effect of shot peening on stress corrosion cracking of a low carbon steel in ocean water environment. The dimension of specimens were prepared in accordance with the ASTM G39. The hardness testing was carried out using microvickers with 0,25 kgf load in the longitudinal direction. The corrosion cracking test was immersed into artificial sea water for about 7 months. The test shows that the pitting corrosion is dominantly nucleated at the metal film interface. The biggest pitting corrosion was occurred under the static loading of 70 for the specimens unpeened. The presence of pitting corrosion promotes stress corrosion cracking. The cracking has a intergranular branched morphology which is typical for the chloride cracking of low carbon steel


2020 ◽  
Vol 38 (1) ◽  
pp. 1-24
Author(s):  
Mariano A. Kappes

AbstractFluorides, bromides, and iodides, despite being less common than chlorides, are present in various environments of industrial relevance. Stainless steels suffer pitting corrosion in solutions of all halides except fluorides, which can be understood considering that fluoride is the anion of a weak acid. The aggressiveness of the rest of the halides for pitting corrosion is on the order Cl− > Br− > I− for stainless steels with Mo content below 3 wt.%. Mo is not as effective in inhibiting Br− pitting corrosion as it is for inhibiting Cl− pitting corrosion. Most of those observations were rationalized based on the effect of anions on pit growth kinetics. Sensitized austenitic stainless steel suffers stress corrosion cracking (SCC) in solutions of all halides, albeit chlorides seem to be the most aggressive. Fluoride SCC is relevant for SCC under insulation of stainless steels, and standards and regulations developed to mitigate this problem consider this ion as aggressive as chloride. For the solubilized stainless steels, aggressiveness toward SCC is in the order Cl− > Br−. The SCC of solubilized stainless steels was not observed in solutions of F− and I−, and the possible reasons for this fact are discussed.


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