scholarly journals 1,2,3-Triazole based bisphosphine, 5-(diphenylphosphanyl)-1-(2-(diphenylphosphanyl)-phenyl)-4-phenyl-1H-1,2,3-triazole: an ambidentate ligand with switchable coordination modes

RSC Advances ◽  
2018 ◽  
Vol 8 (45) ◽  
pp. 25704-25718 ◽  
Author(s):  
Latchupatula Radhakrishna ◽  
Madhusudan K. Pandey ◽  
Maravanji S. Balakrishna
Keyword(s):  
Transition Metal ◽  
Cyclization Reaction ◽  
Transition Metal Chemistry ◽  
Metal Chemistry ◽  
Coordination Modes ◽  
Ambidentate Ligand

This paper describes the synthesis of a triazole based bisphosphine and its transition metal chemistry and catalytic utility in Cu-free Sonogashira alkynylation/cyclization reaction.

Transition metal chemistry in synthetically viable alkaline earth complexes M(Cp)3– (M = Ca, Sr, Ba)

2021 ◽  
Author(s):  
Bin Huo ◽  
Rui Sun ◽  
Bo Jin ◽  
Lingfei Hu ◽  
Jian-Hong Bian ◽  
...  
Keyword(s):  
Transition Metal ◽  
Oxidation State ◽  
Alkaline Earth ◽  
Transition Metal Chemistry ◽  
Metal Chemistry

We predicted the stable alkaline earth complexes M(Cp)3– (M = Ca, Sr, Ba; Cp = cyclopentadienyl), where the M centers were in their stable +2 oxidation state and mimicked the...

Transition metal chemistry

1971 ◽  
Vol 28 (3) ◽  
pp. 391-397 ◽  
Author(s):  
F.T. Delbeke ◽  
E.G. Claeys ◽  
G.P. van der Kelen
Keyword(s):  
Transition Metal ◽  
Transition Metal Chemistry ◽  
Metal Chemistry
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