scholarly journals Modeling of the surface plasmon resonance tunability of silver/gold core–shell nanostructures

RSC Advances ◽  
2018 ◽  
Vol 8 (35) ◽  
pp. 19616-19626 ◽  
Author(s):  
Dab Chahinez ◽  
Thomas Reji ◽  
Ruediger Andreas

Tunable plasmonic noble metal nanoparticles are indispensable for chemical sensors and optical near field enhancement applications.

Nanomaterials ◽  
2021 ◽  
Vol 11 (7) ◽  
pp. 1728
Author(s):  
Joshua Fernandes ◽  
Sangmo Kang

The near-field enhancement and localized surface plasmon resonance (LSPR) on the core-shell noble metal nanostructure surfaces are widely studied for various biomedical applications. However, the study of the optical properties of new plasmonic non-spherical nanostructures is less explored. This numerical study quantifies the optical properties of spherical and non-spherical (prolate and oblate) dimer nanostructures by introducing finite element modelling in COMSOL Multiphysics. The surface plasmon resonance peaks of gold nanostructures should be understood and controlled for use in biological applications such as photothermal therapy and drug delivery. In this study, we find that non-spherical prolate and oblate gold dimers give excellent tunability in a wide range of biological windows. The electromagnetic field enhancement and surface plasmon resonance peak can be tuned by varying the aspect ratio of non-spherical nanostructures, the refractive index of the surrounding medium, shell thickness, and the distance of separation between nanostructures. The absorption spectra exhibit considerably greater dependency on the aspect ratio and refractive index than the shell thickness and separation distance. These results may be essential for applying the spherical and non-spherical nanostructures to various absorption-based applications.


Author(s):  
Prabhash Prasannan Geetha ◽  
Ajith Ramachandran ◽  
Swapna S. Nair

Surface Plasmon Resonance (SPR) is an attracting property of certain transition metals when they are synthesized in nano-range giving rise to promising optical applications. However, most SPR and associated applications are limited to the noble metal nanoparticles, which limits their potential due to high production cost. We report surface plasmon resonance in copper-copper oxide core-shell quantum dots synthesized via chemical route studied by using UV-Visible spectrophotometry. Tuning of the plasmonic resonance with respect to the particle diameter is achieved by an inexpensive all chemical route. Photoluminescence measurements also support the data. This size reduction leads to remarkable changes in its optical response as compared to the bulk metal. The results point towards applications of these materials in tunable SPR based biosensors.


2008 ◽  
Vol 368-372 ◽  
pp. 797-799 ◽  
Author(s):  
Chien Jung Huang ◽  
Pin Hsiang Chiu ◽  
Yeong Her Wang

This paper describes a sol-gel (SG) method for the coating of gold nanoparticles with uniform shells of amorphous silica. The thickness of silica could be conveniently controlled in the range of 10 to 120 nm by increasing the amount of water. Although spherical gold nanoparticles generally have a surface plasmon resonance (SPR) at a wavelength of about 520 nm, a spherical gold core with a silica shell offers a very highly tunable SPR wavelength depending on the thickness of the silica shell.


2014 ◽  
Vol 50 (90) ◽  
pp. 13893-13895 ◽  
Author(s):  
Xingguang Zhang ◽  
Aijun Du ◽  
Huaiyong Zhu ◽  
Jianfeng Jia ◽  
Jun Wang ◽  
...  

The catalytic performance of zeolites can be boosted by the electric near-field enhancement (ENFE) of plasmonic Au-NPs induced by the localised surface plasmon resonance (LSPR) under visible light irradiation.


2021 ◽  
Author(s):  
SAQIB JAMIL ◽  
Adnan Daud Khan ◽  
Javed Iqbal ◽  
Waqas Farooq

Abstract We theoretically demonstrated a kind of plasmon coupled elliptical nanostructure to achieve a vast range of applications based on nanolaser or spaser with high intensity. To overcome the ohmic losses, the plasmon ellipse is composed of the gold film substrate with a gain media. A simple ellipse has been chosen from which variety of dimer configurations have been formed by symmetry alteration technique which are then tested for different light polarizations and gap variations. The proposed model supports localized surface plasmon resonance mode (LSPR). Moreover, the localized surface plasmon resonance (LSPR) property of the proposed nanostructure is numerically analysed by the finite-element method (FEM) and the results shows that the electric field intensity (EFI) can be amplified to a large values by symmetry breaking in the elliptical nanostructure. Various plasmon modes can be excited by selecting the appropriate gain media. In addition to this, a compact tunable multi-wavelength nanolaser (spaser) can be developed by using this model. Giant near field enhancement (NFE) and high LSPR enable this structure to be promising for spaser applications such as surface enhanced Raman spectroscopy, sensing, lithography, imaging, dental applications and much more.


RSC Advances ◽  
2021 ◽  
Vol 11 (5) ◽  
pp. 2733-2743
Author(s):  
Parisa Talebi ◽  
Harishchandra Singh ◽  
Ekta Rani ◽  
Marko Huttula ◽  
Wei Cao

Surface plasmonic resonance enabled Ni@NiO/NiCO3 core–shell nanostructures as promising photocatalysts for hydrogen evolution under visible light.


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