scholarly journals Hierarchically porous N-doped carbon derived from supramolecular assembled polypyrrole as a high performance supercapacitor electrode material

RSC Advances ◽  
2018 ◽  
Vol 8 (33) ◽  
pp. 18714-18722 ◽  
Author(s):  
Li Lai ◽  
Yu Zhao ◽  
Shu Ying ◽  
Lanlan Li ◽  
Zhong Ma ◽  
...  

Hierarchically porous N-doped carbon with optimized morphology exhibits an enhanced specific capacitance of 435.6 F g−1 at 0.5 A g−1 and 96.1% capacitance retention after 5000 cycles in 1 M H2SO4.

2020 ◽  
Vol 8 (5) ◽  
pp. 2463-2471 ◽  
Author(s):  
Jiye Li ◽  
Weimiao Zhang ◽  
Xu Zhang ◽  
Liyao Huo ◽  
Jiayi Liang ◽  
...  

Micro/meso-porous carbon nanofibers have been successfully prepared and directly adopted as a supercapacitor electrode material with high specific capacitance, area normalized capacitance and excellent cycling stability.


2014 ◽  
Vol 2 (39) ◽  
pp. 16640-16644 ◽  
Author(s):  
Jie Yang ◽  
Peixun Xiong ◽  
Cheng Zheng ◽  
Heyuan Qiu ◽  
Mingdeng Wei

A layered structure Ni-based MOF was firstly used as the electrode material for a supercapacitor and exhibited a large specific capacitance of 1127 F g−1 at 0.5 A g−1.


2021 ◽  
Vol 11 (1) ◽  
Author(s):  
Jeongpil Kim ◽  
Jeong-Hyun Eum ◽  
Junhyeok Kang ◽  
Ohchan Kwon ◽  
Hansung Kim ◽  
...  

AbstractHerein, we introduce a simple method to prepare hierarchical graphene with a tunable pore structure by activating graphene oxide (GO) with a two-step thermal annealing process. First, GO was treated at 600 °C by rapid thermal annealing in air, followed by subsequent thermal annealing in N2. The prepared graphene powder comprised abundant slit nanopores and micropores, showing a large specific surface area of 653.2 m2/g with a microporous surface area of 367.2 m2/g under optimized conditions. The pore structure was easily tunable by controlling the oxidation degree of GO and by the second annealing process. When the graphene powder was used as the supercapacitor electrode, a specific capacitance of 372.1 F/g was achieved at 0.5 A/g in 1 M H2SO4 electrolyte, which is a significantly enhanced value compared to that obtained using activated carbon and commercial reduced GO. The performance of the supercapacitor was highly stable, showing 103.8% retention of specific capacitance after 10,000 cycles at 10 A/g. The influence of pore structure on the supercapacitor performance was systematically investigated by varying the ratio of micro- and external surface areas of graphene.


2021 ◽  
Vol 9 (5) ◽  
pp. 2948-2958
Author(s):  
Bing Wang ◽  
Shuo Liu ◽  
Lin Liu ◽  
Wen-Wei Song ◽  
Yue Zhang ◽  
...  

The three-component PCN-224/PEDOT/PMo12 supercapacitor electrode material is designed to offer high area capacitance, good cycle stability and mechanical flexibility.


Energies ◽  
2019 ◽  
Vol 12 (6) ◽  
pp. 1143 ◽  
Author(s):  
Anil Yedluri ◽  
Tarugu Anitha ◽  
Hee-Je Kim

Hierarchical NiMoO4/NiMoO4 nanoflowers were fabricated on highly conductive flexible nickel foam (NF) substrates using a facile hydrothermal method to achieve rapid charge-discharge ability, high energy density, long cycling lifespan, and higher flexibility for high-performance supercapacitor electrode materials. The synthesized composite electrode material, NF/NiMoO4/NiMoO4 with a nanoball-like NF/NiMoO4 structure on a NiMoO4 surface over a NF substrate, formed a three-dimensional interconnected porous network for high-performance electrodes. The novel NF/NiMoO4/NiMoO4 nanoflowers not only enhanced the large surface area and increased the electrochemical activity, but also provided an enhanced rapid ion diffusion path and reduced the charge transfer resistance of the entire electrode effectively. The NF/NiMoO4/NiMoO4 composite exhibited significantly improved supercapacitor performance in terms of a sustained cycling life, high specific capacitance, rapid charge-discharge capability, high energy density, and good rate capability. Electrochemical analysis of the NF/NiMoO4/NiMoO4 nanoflowers fabricated on the NF substrate revealed ultra-high electrochemical performance with a high specific capacitance of 2121 F g−1 at 12 mA g−1 in a 3 M KOH electrolyte and 98.7% capacitance retention after 3000 cycles at 14 mA g−1. This performance was superior to the NF/NiMoO4 nanoball electrode (1672 F g−1 at 12 mA g−1 and capacitance retention 93.4% cycles). Most importantly, the SC (NF/NiMoO4/NiMoO4) device displayed a maximum energy density of 47.13 W h kg−1, which was significantly higher than that of NF/NiMoO4 (37.1 W h kg−1). Overall, the NF/NiMoO4/NiMoO4 composite is a suitable material for supercapacitor applications.


2021 ◽  
Author(s):  
Daniel M. Mijailovic ◽  
Vuk V. Radmilović ◽  
Uros C. Lacnjevac ◽  
Dusica B Stojanovic ◽  
Karen Bustillo ◽  
...  

We herein report a simple two–step procedure for fabricating tetragonal CoMn2O4 spinel nanocrystals on carbon fibers. The battery–type behavior of these composite fibers arises from the redox activity of CoMn2O4...


2021 ◽  
Author(s):  
Yaseen Muhammad ◽  
Ata ur Rahman ◽  
Hamsa Noreen ◽  
Zeeshan Nawaz ◽  
Javed Iqbal Saggu ◽  
...  

The preparation of a stable, efficient, inexpensive and high capacitance electrode material for supercapacitors is posing great challenges for the researchers. In this report, we demonstrate the synthesis of stable,...


RSC Advances ◽  
2014 ◽  
Vol 4 (66) ◽  
pp. 34739-34750 ◽  
Author(s):  
Alfin Kurniawan ◽  
L. K. Ong ◽  
Fredi Kurniawan ◽  
C. X. Lin ◽  
Felycia E. Soetaredjo ◽  
...  

For the first time, porous carbon microfibers co-doped with N/P/K were synthesized from cane molasses by combination of electrospinning and carbonization techniques and its electrochemical application to electrode materials for supercapacitors was investigated.


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