scholarly journals Preparation of PSF/FEP mixed matrix membrane with super hydrophobic surface for efficient water-in-oil emulsion separation

RSC Advances ◽  
2018 ◽  
Vol 8 (18) ◽  
pp. 10097-10106 ◽  
Author(s):  
Dawei Ji ◽  
Changfa Xiao ◽  
Shulin An ◽  
Hailiang Liu ◽  
Kaikai Chen ◽  
...  
Keyword(s):  
Hydrophobic Surface ◽  
Mixed Matrix Membrane ◽  
Separation Performance ◽  
Mixed Matrix ◽  
Oil Emulsion ◽  
Emulsion Separation ◽  
Water In Oil Emulsion

The PSF/FEP membrane with super hydrophobic and super oleophilic surface had an outstanding separation performance for water-in-oil emulsion.

Robust superhydrophobic carbon nanofiber network inlay-gated mesh for water-in-oil emulsion separation with high flux

2016 ◽  
Vol 4 (46) ◽  
pp. 17970-17980 ◽  
Author(s):  
Xiangde Lin ◽  
Jiwoong Heo ◽  
Hyejoong Jeong ◽  
Moonhyun Choi ◽  
Minwook Chang ◽  
...  
Keyword(s):  
Carbon Nanofiber ◽  
Separation Performance ◽  
High Flux ◽  
Water Emulsion ◽  
Oil Emulsion ◽  
High Durability ◽  
Emulsion Separation ◽  
Oil Water ◽  
Water In Oil Emulsion

A superhydrophobic carbon nanofiber network inlay-gated mesh with high durability and separation performance was developed for oil–water emulsion separation.

scholarly journals Multiple Amine-Contained POSS-Functionalized Organosilica Membranes for Gas Separation

Membranes ◽  
2021 ◽  
Vol 11 (3) ◽  
pp. 194
Author(s):  
Xiuxiu Ren ◽  
Masakoto Kanezashi ◽  
Meng Guo ◽  
Rong Xu ◽  
Jing Zhong ◽  
...  
Keyword(s):  
Gas Separation ◽  
Mixed Matrix Membranes ◽  
Mixed Matrix Membrane ◽  
Separation Performance ◽  
Hybrid Membranes ◽  
Mixed Matrix ◽  
Translation Model ◽  
Good Thermal Stability ◽  
Oligomeric Silsesquioxane

A new polyhedral oligomeric silsesquioxane (POSS) designed with eight –(CH2)3–NH–(CH2)2–NH2 groups (PNEN) at its apexes was used as nanocomposite uploading into 1,2-bis(triethoxysilyl)ethane (BTESE)-derived organosilica to prepare mixed matrix membranes (MMMs) for gas separation. The mixtures of BTESE-PNEN were uniform with particle size of around 31 nm, which is larger than that of pure BTESE sols. The characterization of thermogravimetric (TG) and gas permeance indicates good thermal stability. A similar amine-contained material of 3-aminopropyltriethoxysilane (APTES) was doped into BTESE to prepare hybrid membranes through a copolymerized strategy as comparison. The pore size of the BTESE-PNEN membrane evaluated through a modified gas-translation model was larger than that of the BTESE-APTES hybrid membrane at the same concentration of additions, which resulted in different separation performance. The low values of Ep(CO2)-Ep(N2) and Ep(N2) for the BTESE-PNEN membrane at a low concentration of PNEN were close to those of copolymerized BTESE-APTES-related hybrid membranes, which illustrates a potential CO2 separation performance by using a mixed matrix membrane strategy with multiple amine POSS as particles.

scholarly journals THE EFFECT OF TYPE ZEOLITE ON THE GAS TRANSPORT PROPERTIES OF POLYIMIDE-BASED MIXED MATRIX MEMBRANES

REAKTOR ◽  
2008 ◽  
Vol 12 (2) ◽  
pp. 68 ◽  
Author(s):  
Tutuk Djoko Kusworo ◽  
Ahmad Fauzi Ismail ◽  
Azeman Mustafa ◽  
Kang Li
Keyword(s):  
Mixed Matrix Membranes ◽  
Mixed Matrix Membrane ◽  
Separation Performance ◽  
Mixed Matrix ◽  
Scanning Calorimetry ◽  
Zeolite 4A ◽  
Intensity Changes ◽  
Zeolite Type ◽  
Type Zeolite ◽  
Matrix Membranes

The permeation rates of O2, N2, CO2 and CH4 has been studied for polyimide-polyethersulfone (PI/PES) blends-zeolite mixed matrix membranes synthesized in our laboratory. The study investigated the effect of zeolite loading and different zeolite type on the gas separation performance of these mixed matrix membranes. Frequency shifts and absorption intensity changes in the FTIR spectra of the PI/PES blends as compared with those of the pure polymers indicate that there is a mixing of polymer blends at the molecular level. Differential scanning calorimetry measurements of pure and PI/PES blends membranes have showed one unique glass transition temperature that supports the miscible character of the PI/PES mixture. The PI/PES-zeolite 4A mixed matrix membrane with 25 wt % zeolite loading produced the highest O2/N2 and CO2/CH4 selectivity of around 7.45 and 46.05, respectively.

In situ synthesis of polymer grafted ZIFs and application in mixed matrix membrane for CO2 separation

2018 ◽  
Vol 6 (7) ◽  
pp. 3151-3161 ◽  
Author(s):  
Yongqiang Gao ◽  
Zhihua Qiao ◽  
Song Zhao ◽  
Zhi Wang ◽  
Jixiao Wang
Keyword(s):  
Polymer Matrix ◽  
In Situ Synthesis ◽  
Mixed Matrix Membrane ◽  
Co2 Separation ◽  
Separation Performance ◽  
Mixed Matrix ◽  
Interfacial Compatibility ◽  
Gas Separation Performance ◽  
Functionalized Surface

PEI-g-ZIF-8 presents appropriate porous structure, amino functionalized surface and improved interfacial compatibility with the polymer matrix to endow the MMMs with excellent gas separation performance.

Gas Permeation Properties of Multiwalled Carbon Nanotubes on Polyether Block Amide (Pebax-1657)/Polyethersulfone(PES) Blend Mixed Matrix Membrane for CO2/CH4 Separation

2020 ◽  
Vol 307 ◽  
pp. 258-263
Author(s):  
Nabilah Fazil ◽  
Hilmi Mukhtar ◽  
Dzeti Farhah Mohshim ◽  
Rizwan Nasir
Keyword(s):  
Carbon Nanotubes ◽  
Gas Permeability ◽  
Gas Permeation ◽  
Superior Performance ◽  
Polymeric Membrane ◽  
Mixed Matrix Membrane ◽  
Inversion Method ◽  
Separation Performance ◽  
Mixed Matrix ◽  
Multiwalled Carbon

Mixed matrix membrane (MMM), a developing research area, is a membrane formed by incorporating fillers in the polymeric membrane to enhance gas separation performance. In this study, MMMs comprised of blend rubbery block copolymers of polyether block amide (Pebax-1657) with a glassy polyethersulfone (PES) polymer and multi-walled carbon nanotubes (MWCNTs) were synthesized by dry phase inversion method and explored further by gas permeability test. Pebax-1657/PES/MWCNTs membrane resulted in an increased permeability as well as CO2/CH4 selectivity. The Pebax-1657/PES polymer blend MMM with 10wt% of MWCNTs has shown the most superior performance of CO2 permeability, CH4 permeability and CO2/CH4 selectivity in comparison with the pure Pebax-1657 resulted in 66.3% and 11.6% difference respectively.

Janus membrane decorated via a versatile immersion-spray route: controllable stabilized oil/water emulsion separation satisfying industrial emission and purification criteria

2019 ◽  
Vol 7 (9) ◽  
pp. 4941-4949 ◽  
Author(s):  
Weifeng Zhang ◽  
Xiangyu Li ◽  
Ruixiang Qu ◽  
Yanan Liu ◽  
Yen Wei ◽  
...  
Keyword(s):  
Water Emulsion ◽  
Industrial Emission ◽  
Oil Emulsion ◽  
Highly Efficient ◽  
Oil In Water ◽  
Emulsion Separation ◽  
Oil Water ◽  
Water In Oil Emulsion

A PANI–SiNP-decorated Janus membrane was fabricated for highly efficient stabilized oil-in-water and water-in-oil emulsion separation, meeting industrial purification standards.

scholarly journals Improved Desulfurization Performance of Polyethyleneglycol Membrane by Incorporating Metal Organic Framework CuBTC

Polymers ◽  
2020 ◽  
Vol 12 (2) ◽  
pp. 414 ◽  
Author(s):  
Caibin Cai ◽  
Xiaotao Fan ◽  
Xiaolong Han ◽  
Jiding Li ◽  
Harsh Vardhan
Keyword(s):  
Operating Temperature ◽  
Metal Organic Framework ◽  
Mixed Matrix Membrane ◽  
Separation Performance ◽  
Hybrid Membranes ◽  
Mixed Matrix ◽  
Metal Organic ◽  
Pervaporation Separation ◽  
Π Complexation

In this paper, copper benzene-1,3,5-tricarboxylate (CuBTC) was incorporated into polyethylenglyol (PEG) to prepare a mixed matrix membrane (MMM) for pervaporation desulfurization. The characterization results showed that the prepared CuBTC particles had an ideal octahedral shape and micropores. The Cu2+ in CuBTC interacts with thiophene via π-complexation, thus enhancing the separation performance of the hybrid membranes. The effect of CuBTC content and the operating condition on the pervaporation performance of the MMMs was investigated. An optimal pervaporation separation performance was acquired with a permeation flux of 2.21 kg/(m2·h) and an enrichment factor of 8.79, which were increased by 100% and 39% compared with the pristine PEG membrane. Moreover, the CuBTC-filled PEG membrane showed a good stability in the long-term desulfurization under a high operating temperature of 75 °C for five days.

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