Trifluoromethyl-substituted selenium ylide: a broadly applicable electrophilic trifluoromethylating reagent

2019 ◽  
Vol 6 (13) ◽  
pp. 2205-2209 ◽  
Author(s):  
Hangming Ge ◽  
Qilong Shen
Keyword(s):  
Boronic Acids ◽  
Electrophilic Reagent ◽  
Enol Ethers ◽  
Silyl Enol Ethers

An easily available, air/moisture insensitive and broadly applicable electrophilic reagent trifluoromethyl-substituted selenium ylide 1a and its reactions with a variety of nucleophiles including β-ketoesters and silyl enol ethers, aryl/heteroaryl boronic acids, electron-rich heteroarenes and sulfinates were described.

Electrophilic Amination: An Update

Synlett ◽  
2019 ◽  
Vol 30 (13) ◽  
pp. 1525-1535 ◽  
Author(s):  
Zhe Zhou ◽  
László Kürti
Keyword(s):  
Boronic Acids ◽  
Enol Ethers ◽  
Electrophilic Amination ◽  
Silyl Enol Ethers ◽  
Recent Advances

In this account, we provide an overview of some recent advances in electrophilic amination methodologies that have been developed in the Kürti group over the last seven years. Our group’s focus has been to develop novel amination methodologies that directly yield N-unprotected amine products.1 Introduction2 Amination of Boronic Acids3 Aziridination of Unactivated Olefins4 Rhodium-Catalyzed C–H Amination of Arenes5 Synthesis of Carbazoles6 Amination of Aryl- and Alkylmetals7 Doubly Electrophilic N-Linchpin Reagents8 Aza-Rubottom Oxidation of Silyl Enol Ethers9 Summary

Addition of Allylsilanes and Silyl Enol Ethers to Small Oxygenated Rings: New Tools for Organic Synthesis

2014 ◽  
Vol 18 (5) ◽  
pp. 525-546 ◽  
Author(s):  
Carmen Hernandez-Cervantes ◽  
Miriam Alvarez-Corral ◽  
Manuel Munoz-Dorado ◽  
Ignacio Rodriguez-Garcia
Keyword(s):  
Organic Synthesis ◽  
Enol Ethers ◽  
Silyl Enol Ethers

Bench‐Stable Electrophilic Fluorinating Reagents for Highly Selective Mono‐ and Difluorination of Silyl Enol Ethers

2021 ◽  
Author(s):  
Kohsuke Aikawa ◽  
KyoKo Nozaki ◽  
Takashi Okazoe ◽  
Yuichiro Ishibashi ◽  
Akiya Adachi
Keyword(s):  
Enol Ethers ◽  
Silyl Enol Ethers

ChemInform Abstract: Lewis-Acid-Induced Reactions of α-Methoxyglycinamide Derivatives with Silyl Enol Ethers. Formation of 3-Amino-2-pyrrolidinones and 3- Amino-2-pyrrolinones.

ChemInform ◽  
2010 ◽  
Vol 23 (48) ◽  
pp. no-no
Author(s):  
E. C. ROOS ◽  
H. HIEMSTRA ◽  
W. N. SPECKAMP ◽  
B. KAPTEIN ◽  
J. KAMPHUIS ◽  
...  
Keyword(s):  
Lewis Acid ◽  
Enol Ethers ◽  
Silyl Enol Ethers

ChemInform Abstract: Allylation and Benzylation of Enolates Derived from β- Phenylselanyl Silyl Enol Ethers.

ChemInform ◽  
2010 ◽  
Vol 28 (38) ◽  
pp. no-no
Author(s):  
S. PONTHIEUX ◽  
F. OUTURQUIN ◽  
C. PAULMIER
Keyword(s):  
Enol Ethers ◽  
Silyl Enol Ethers
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