scholarly journals Visible-light-mediated α-phosphorylation of N-aryl tertiary amines through the formation of electron-donor–acceptor complexes: synthetic and mechanistic studies

2019 ◽  
Vol 6 (1) ◽  
pp. 41-44 ◽  
Author(s):  
Valentin Quint ◽  
Nourhène Chouchène ◽  
Moheddine Askri ◽  
Jacques Lalevée ◽  
Annie-Claude Gaumont ◽  
...  
Keyword(s):  
Visible Light ◽  
Electron Donor ◽  
Secondary Phosphine ◽  
Phosphine Oxides ◽  
Tertiary Amines ◽  
Mechanistic Studies ◽  
Donor Acceptor

A visible light-mediated photocatalyst-free approach for the oxidative α-CH functionalization of N-aryl tertiary amines with secondary phosphine oxides has been developed.

scholarly journals Metal-Free C-Se Cross-Coupling Enabled by Photoinduced Intermolecular Charge Transfer

2021 ◽  
Author(s):  
Chen Zhu ◽  
Serik Zhumagazy ◽  
Huifeng Yue ◽  
Magnus Rueping
Keyword(s):  
Charge Transfer ◽  
Visible Light ◽  
Electron Donor ◽  
Cross Coupling ◽  
Metal Free ◽  
Intermolecular Charge Transfer ◽  
Donor Acceptor

Metal-free C-Se cross-couplings via the formation of electron-donor-acceptor (EDA) complexes have been developed. The visible-light induced reactions can be applied for the synthesis of a series of unsymmetrical diaryl selenides...

A visible-light-irradiated electron donor-acceptor complex-promoted radical reaction system for the C H perfluoroalkylation of quinolin-4-ols

2019 ◽  
Vol 60 (38) ◽  
pp. 151046 ◽  
Author(s):  
Yunze Li ◽  
Min Rao ◽  
Zhenwei Fan ◽  
Baoyi Nian ◽  
Yaofeng Yuan ◽  
...  
Keyword(s):  
Visible Light ◽  
Electron Donor ◽  
Radical Reaction ◽  
Reaction System ◽  
Acceptor Complex ◽  
Donor Acceptor

Visible-Light-Promoted [5 + 1] Annulation Initiated by Electron-Donor–Acceptor Complexes: Synthesis of Perfluoroalkyl-s-Triazines

2019 ◽  
Vol 21 (9) ◽  
pp. 3072-3076 ◽  
Author(s):  
Rui Wang ◽  
Lili Wang ◽  
Qin Xu ◽  
Bao-Yi Ren ◽  
Fushun Liang
Keyword(s):  
Visible Light ◽  
Electron Donor ◽  
Donor Acceptor

scholarly journals Visible-light-induced intramolecular charge transfer in the radical spirocyclisation of indole-tethered ynones

2020 ◽  
Vol 11 (5) ◽  
pp. 1353-1360 ◽  
Author(s):  
Hon Eong Ho ◽  
Angela Pagano ◽  
James A. Rossi-Ashton ◽  
James R. Donald ◽  
Ryan G. Epton ◽  
...  
Keyword(s):  
Charge Transfer ◽  
Visible Light ◽  
Electron Donor ◽  
Intramolecular Charge Transfer ◽  
Thiyl Radical ◽  
Acceptor Complex ◽  
Donor Acceptor ◽  
Radical Generation ◽  
Induced Charge

Indole-tethered ynones form an intramolecular electron donor–acceptor complex that can undergo visible-light-induced charge transfer to promote thiyl radical generation from thiols.

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