scholarly journals Metal-free cross-coupling of π-conjugated triazenes with unactivated arenes via photoactivation

2019 ◽  
Vol 6 (2) ◽  
pp. 152-161 ◽  
Author(s):  
Enrique Barragan ◽  
Anurag Noonikara Poyil ◽  
Chou-Hsun Yang ◽  
Haobin Wang ◽  
Alejandro Bugarin
Keyword(s):  
Cross Coupling ◽  
Coupling Reactions ◽  
Metal Free ◽  
Cross Coupling Reactions ◽  
Biaryl Compounds

A metal-free synthesis of biaryl compounds was achieved under photo-irradiation, which represents a milder alternative for cross-coupling reactions.

Selectfluor-induced C(sp2)–O coupling reaction of N-substituted anilines with hydroxylamine derivatives

2018 ◽  
Vol 16 (33) ◽  
pp. 6017-6024 ◽  
Author(s):  
Bin Sun ◽  
Shi Yin ◽  
Xiaohui Zhuang ◽  
Can Jin ◽  
Weike Su
Keyword(s):  
Coupling Reaction ◽  
Cross Coupling ◽  
Coupling Reactions ◽  
Substituted Anilines ◽  
Metal Free ◽  
Cross Coupling Reactions ◽  
Hydroxylamine Derivatives

We developed a novel metal-free method for the construction of C(sp2)–O bonds via oxidative cross-coupling reactions between various N-substituted anilines and hydroxylamine derivatives just using commercially available Selectfluor as an oxidant.

Synthesis of Alkyl-Substituted Pyrazine N -Oxides by Transition-Metal-Free Oxidative Cross-Coupling Reactions

2018 ◽  
Vol 7 (6) ◽  
pp. 1118-1123 ◽  
Author(s):  
Miao Lai ◽  
Yuan Li ◽  
Zhiyong Wu ◽  
Mingqin Zhao ◽  
Xiaoming Ji ◽  
...  
Keyword(s):  
Transition Metal ◽  
Cross Coupling ◽  
Coupling Reactions ◽  
Metal Free ◽  
Cross Coupling Reactions

Nitrimines as Reagents for Metal-Free Formal C(sp2)-C(sp2) Cross-Coupling Reactions

2014 ◽  
Vol 126 (52) ◽  
pp. 14766-14769 ◽  
Author(s):  
Veronica V. Angeles-Dunham ◽  
David M. Nickerson ◽  
Devin M. Ray ◽  
Anita E. Mattson
Keyword(s):  
Cross Coupling ◽  
Coupling Reactions ◽  
Metal Free ◽  
Cross Coupling Reactions

scholarly journals Metal-Free C-2 Alkylation of N-Oxides with Ethers via Radical Cross-Coupling Reactions

2020 ◽  
Vol 40 (6) ◽  
pp. 1766 ◽  
Author(s):  
Daoqing Dong ◽  
Guanghui Li ◽  
Demao Chen ◽  
Yuanyuan Sun ◽  
Qingqing Han ◽  
...  
Keyword(s):  
Cross Coupling ◽  
Coupling Reactions ◽  
Metal Free ◽  
Cross Coupling Reactions

ChemInform Abstract: Transition-Metal-Free Cross-Coupling Reactions by Single Electron Transfer (SET).

ChemInform ◽  
2014 ◽  
Vol 45 (42) ◽  
pp. no-no
Author(s):  
Suresh Kumar Sythana ◽  
Santhosh Unni ◽  
Yogesh M. Kshirsagar ◽  
Pundlik R. Bhagat
Keyword(s):  
Electron Transfer ◽  
Transition Metal ◽  
Cross Coupling ◽  
Single Electron ◽  
Single Electron Transfer ◽  
Coupling Reactions ◽  
Metal Free ◽  
Cross Coupling Reactions

scholarly journals Synthesis of squaraine-based alternated π-conjugated copolymers: from conventional cross-coupling reactions to metal-free polycondensation

2014 ◽  
Vol 5 (24) ◽  
pp. 7100-7108 ◽  
Author(s):  
J. Oriou ◽  
F. Ng ◽  
G. Hadziioannou ◽  
G. Garbay ◽  
M. Bousquet ◽  
...  
Keyword(s):  
Band Gap ◽  
Cross Coupling ◽  
Coupling Reactions ◽  
Low Band Gap ◽  
Metal Free ◽  
Cross Coupling Reactions ◽  
Conjugated Copolymers

Low band-gap π-conjugated copolymers based on squaraine units can be synthesized through classical Suzuki and Stille cross-coupling reactions (in blue), or through a metal-free polycondensation (in green).

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