Biobased bismaleimide resins with high renewable carbon content, heat resistance and flame retardancy via a multi-functional phosphate from clove oil

2019 ◽  
Vol 3 (1) ◽  
pp. 78-85 ◽  
Author(s):  
Jia-Tao Miao ◽  
Li Yuan ◽  
Guozheng Liang ◽  
Aijuan Gu
Keyword(s):  
Heat Resistance ◽  
Carbon Content ◽  
Flame Retardancy ◽  
Clove Oil ◽  
Thermosetting Resin ◽  
Bismaleimide Resins

A eugenol-derived flame retarding thermosetting resin with a high renewable carbon content and heat resistance is prepared via a biobased multi-functional phosphate.

Hexa(eugenol)cyclotriphosphazene modified bismaleimide resins with unique thermal stability and flame retardancy

2017 ◽  
Vol 113 ◽  
pp. 77-84 ◽  
Author(s):  
Xinfang Zhang ◽  
Raheel Akram ◽  
Shuangkun Zhang ◽  
Hanlin Ma ◽  
Zhanpeng Wu ◽  
...  
Keyword(s):  
Thermal Stability ◽  
Flame Retardancy ◽  
Bismaleimide Resins

Synthesis and characterization of a phosphorus-containing flame retardant with double bonds and its application in bismaleimide resins

RSC Advances ◽  
2015 ◽  
Vol 5 (123) ◽  
pp. 101480-101486 ◽  
Author(s):  
Song Li ◽  
Hongxia Yan ◽  
Shuyao Feng ◽  
Song Niu
Keyword(s):  
Mechanical Properties ◽  
Thermal Stability ◽  
Flame Retardant ◽  
Flame Retardancy ◽  
Synthesis And Characterization ◽  
Bismaleimide Resin ◽  
Phosphorus Containing ◽  
Reactive Phosphorus ◽  
Bismaleimide Resins

A novel reactive phosphorus-containing flame retardant was synthesized and used to modify bismaleimide resin. According to investigations, the modified bismaleimide resin has good mechanical properties, thermal stability and flame retardancy.

Carborane-containing bismaleimide resins with excellent heat resistance and dimensional stability

2020 ◽  
pp. 095400832094893
Author(s):  
Yuane Wu ◽  
Gong Chen ◽  
Longfei Gao ◽  
Wei Zhang ◽  
Song Li
Keyword(s):  
Heat Resistance ◽  
Thermal Property ◽  
Dimensional Stability ◽  
Coefficient Of Thermal Expansion ◽  
Weight Fraction ◽  
Curing Temperature ◽  
Bismaleimide Resin ◽  
H Nmr ◽  
Ft Ir ◽  
Bismaleimide Resins

Novel carborane-containing bismaleimides with excellent heat resistance and dimensional stability for advanced composites are presented. First, a new kind of carborane-containing mono-maleimido-terminated monomer 1-(4-tolyl)-2-(4-maleimido phenyl)- o-carborane (CB-MI) was synthesized and characterized by FT-IR and 1H-NMR. Then, it was used as a modifier for bismaleimide resin 4,4’-bismaleimidodiphenylmethane (BDM) with different weight fraction of CB-MI. The curing behavior and thermal property of the CB-MI/BDM resin systems were studied and presented here. Results displayed that a wide processing window and low curing temperature provided a good processability for the CB-MI/BDM resin system. Due to the effect of carborane groups, the char yield at 600°C of the cured resin systems tended to be increased with the addition of CB-MI. Moreover, the coefficient of thermal expansion of the resin was found to be reduced with the increase of CB-MI, indicative of a remarkable dimensional stability. This study might open up great opportunities for the preparation and design of various novel bismaleimides in a simple and feasible way and the resins with good thermal property and processability at the same time.

Sign in / Sign up

Export Citation Format

Share Document