Tetranuclear rare-earth complexes: energy barrier enhancement and two-step slow magnetic relaxation activated by ligand substitution

2019 ◽  
Vol 6 (3) ◽  
pp. 756-764 ◽  
Author(s):  
Jian Gou ◽  
Shuang Liu ◽  
Yun-Juan Wang ◽  
Ling Li ◽  
Peng Ren ◽  
...  
Keyword(s):  
Magnetic Properties ◽  
Rare Earth ◽  
Energy Barrier ◽  
Magnetic Relaxation ◽  
Ligand Substitution ◽  
Rare Earth Complexes ◽  
Slow Magnetic Relaxation

The influence of tuning the β-diketone on the modulation of the magnetic properties is demonstrated.

A family of rare earth complexes with chelating furan biradicals: syntheses, structures and magnetic properties

RSC Advances ◽  
2015 ◽  
Vol 5 (91) ◽  
pp. 74864-74873 ◽  
Author(s):  
Xin Li ◽  
Ting Li ◽  
Li Tian ◽  
Zhong Yi Liu ◽  
Xiu Guang Wang
Keyword(s):  
Magnetic Properties ◽  
Rare Earth ◽  
Magnetic Relaxation ◽  
Rare Earth Complexes ◽  
Frequency Dependent ◽  
Magnetic Susceptibilities ◽  
Slow Magnetic Relaxation

Six LnIII–furan-biradical tri-spin complexes have been synthesized, they exhibit interesting magnetic properties. DyIIIcomplex shows frequency-dependent ac magnetic susceptibilities, which suggests the presence of slow magnetic relaxation.

scholarly journals A family of multi-spin rare-earth complexes based on a triazole nitronyl nitroxide radical: synthesis, structure and magnetic properties

RSC Advances ◽  
2018 ◽  
Vol 8 (28) ◽  
pp. 15480-15486 ◽  
Author(s):  
Peng Yun Chen ◽  
Ming Ze Wu ◽  
Xiu Juan Shi ◽  
Li Tian
Keyword(s):  
Magnetic Properties ◽  
Rare Earth ◽  
Magnetic Relaxation ◽  
Nitroxide Radical ◽  
Rare Earth Complexes ◽  
Nitronyl Nitroxide ◽  
Nitronyl Nitroxide Radical ◽  
Frequency Dependent ◽  
Magnetic Susceptibilities ◽  
Slow Magnetic Relaxation

Three LnIII–triazole–radical complexes have been synthesized, which exhibit interesting magnetic properties. The TbIII complex shows frequency-dependent ac magnetic susceptibilities, which suggests the presence of slow magnetic relaxation.

scholarly journals Implementation of Slow Magnetic Relaxation in a SIM-MOF Through a Structural Rearrangement

2018 ◽  
Author(s):  
Guillermo Minguez Espallargas ◽  
Javier Castells-Gil ◽  
Carlos Marti-Gastaldo ◽  
Jose J. Baldovi
Keyword(s):  
Magnetic Properties ◽  
Charge Density ◽  
Magnetic Relaxation ◽  
Structural Rearrangement ◽  
Ligand Substitution ◽  
Structural Flexibility ◽  
Coordination Environment ◽  
Substitution Process ◽  
Slow Magnetic Relaxation

<p>Here we report the structural flexibility of a Dy-based Single-Ion Magnet MOF in which its magnetic properties can be modified through a ligand substitution process involving an increase of the charge density of the coordination environment.</p>

scholarly journals Implementation of Slow Magnetic Relaxation in a SIM-MOF Through a Structural Rearrangement

2018 ◽  
Author(s):  
Guillermo Minguez Espallargas ◽  
Javier Castells-Gil ◽  
Carlos Marti-Gastaldo ◽  
Jose J. Baldovi
Keyword(s):  
Magnetic Properties ◽  
Charge Density ◽  
Magnetic Relaxation ◽  
Structural Rearrangement ◽  
Ligand Substitution ◽  
Structural Flexibility ◽  
Coordination Environment ◽  
Substitution Process ◽  
Slow Magnetic Relaxation

<p>Here we report the structural flexibility of a Dy-based Single-Ion Magnet MOF in which its magnetic properties can be modified through a ligand substitution process involving an increase of the charge density of the coordination environment.</p>

Multiple magnetic relaxation processes, magnetocaloric effect and fluorescence properties of rhombus-shaped tetranuclear rare earth complexes

2016 ◽  
Vol 45 (1) ◽  
pp. 253-264 ◽  
Author(s):  
Hong-Ling Gao ◽  
Li Jiang ◽  
Shuang Liu ◽  
Hai-Yun Shen ◽  
Wen-Min Wang ◽  
...  
Keyword(s):  
Rare Earth ◽  
Magnetocaloric Effect ◽  
Single Molecule ◽  
Energy Barrier ◽  
Magnetic Relaxation ◽  
High Energy ◽  
Rare Earth Complexes ◽  
Relaxation Processes ◽  
Single Molecule Magnet ◽  
High Energy Barrier

A multi-relaxation single-molecule magnet (SMM) of a {Dy4} complex exhibits two distinct relaxation processes, with a high energy barrier of 121 K.

(thf)2Ln(Ge9{Si(SiMe3)3}3)2 (Ln = Eu, Sm): the first coordination of metalloid germanium clusters to lanthanides

2021 ◽  
Author(s):  
Andreas Schnepf ◽  
Svetlana Klementyeva ◽  
Claudio Schrenk ◽  
Marat M Khusniyarov ◽  
Minghui Zhang
Keyword(s):  
Magnetic Properties ◽  
Rare Earth ◽  
Crystallographic Analysis ◽  
Rare Earth Complexes ◽  
Group 14 ◽  
X Ray ◽  
Germanium Clusters

We report the synthesis, structure and magnetic properties of the first rare earth complexes of metalloid group 14 clusters [(thf)2Ln(Ge9Hyp3)2] (Ln = Eu, Sm, Hyp = Si(SiMe3)3). X-ray crystallographic analysis...

Slow magnetic relaxation in dinuclear dysprosium and holmium phenoxide bridged complexes: a Dy2 single molecule magnet with a high energy barrier

2021 ◽  
Author(s):  
Matilde Fondo ◽  
Julio Corredoira-Vázquez ◽  
Ana M. Garcia-Deibe ◽  
Jesus Sanmartin Matalobos ◽  
Silvia Gómez-Coca ◽  
...  
Keyword(s):  
Crystal Structures ◽  
Single Molecule ◽  
Energy Barrier ◽  
Magnetic Relaxation ◽  
High Energy ◽  
Single Molecule Magnet ◽  
High Energy Barrier ◽  
Slow Magnetic Relaxation

Dinuclear [M(H3L1,2,4)]2 (M = Dy, Dy2; M = Ho, Ho2) complexes were isolated from an heptadentate aminophenol ligand. The crystal structures of Dy2·2THF, and the pyridine adducts Dy2·2Py and Ho2·2Py,...

Structural anisotropy of cyanido-bridged {CoII9WV6} single-molecule magnets induced by bidentate ligands: towards the rational enhancement of an energy barrier

2016 ◽  
Vol 52 (26) ◽  
pp. 4772-4775 ◽  
Author(s):  
Szymon Chorazy ◽  
Michał Rams ◽  
Anna Hoczek ◽  
Bernard Czarnecki ◽  
Barbara Sieklucka ◽  
...  
Keyword(s):  
Single Molecule ◽  
Energy Barrier ◽  
Magnetic Relaxation ◽  
Bidentate Ligands ◽  
Single Molecule Magnets ◽  
Structural Anisotropy ◽  
Slow Magnetic Relaxation

{CoII9[WV(CN)8]6} clusters capped by odd and even number of bidentate ligands reveal the improved slow magnetic relaxation due to the significant structural anisotropy.

Polyoxometalate-Supported Lanthanoid Single-Molecule Magnets

2014 ◽  
Vol 67 (11) ◽  
pp. 1542 ◽  
Author(s):  
Michele Vonci ◽  
Colette Boskovic
Keyword(s):  
Single Molecule ◽  
Energy Barrier ◽  
Magnetic Relaxation ◽  
Donor Ligands ◽  
Single Molecule Magnets ◽  
Single Molecule Magnet ◽  
Coordination Numbers ◽  
Oxygen Donor ◽  
Slow Magnetic Relaxation

Polyoxometalates are robust and versatile multidentate oxygen-donor ligands, eminently suitable for coordination to trivalent lanthanoid ions. To date, 10 very different structural families of such complexes have been found to exhibit slow magnetic relaxation due to single-molecule magnet (SMM) behaviour associated with the lanthanoid ions. These families encompass complexes with between one and four of the later lanthanoid ions: Tb, Dy, Ho, Er, and Yb. The lanthanoid coordination numbers vary between six and eleven and a range of coordination geometries are evident. The highest energy barrier to magnetisation reversal measured to date for a lanthanoid–polyoxometalate SMM is Ueff/kB = 73 K for the heterodinuclear Dy–Eu compound (Bu4N)8H4[DyEu(OH)2(γ-SiW10O36)2].

Structures, fluorescence properties and magnetic properties of a series of rhombus-shaped LnIII4 clusters: magnetocaloric effect and single-molecule-magnet behavior

2019 ◽  
Vol 43 (33) ◽  
pp. 12941-12949 ◽  
Author(s):  
Wen-Min Wang ◽  
Li Zhang ◽  
Xian-Zhen Li ◽  
Li-Yuan He ◽  
Xin-Xin Wang ◽  
...  
Keyword(s):  
Magnetic Properties ◽  
Magnetocaloric Effect ◽  
Single Molecule ◽  
Magnetic Relaxation ◽  
Magnetic Refrigeration ◽  
Fluorescence Properties ◽  
Relaxation Processes ◽  
Magnetic Studies ◽  
Single Molecule Magnet ◽  
Slow Magnetic Relaxation

A family LnIII4 clusters were successfully synthesized and structurally characterized. Magnetic studies show that Gd4 cluster displays magnetic refrigeration, while Dy4 cluster demonstrates two distinct slow magnetic relaxation processes.

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