Rationalization of single-molecule magnet behavior in a three-coordinate Fe(iii) complex with a high-spin state (S = 5/2)

2018 ◽  
Vol 5 (10) ◽  
pp. 2486-2492 ◽  
Author(s):  
Ning Ge ◽  
Yuan-Qi Zhai ◽  
Yi-Fei Deng ◽  
You-Song Ding ◽  
Tao Wu ◽  
...  
Keyword(s):  
High Spin ◽  
Spin State ◽  
Single Molecule ◽  
High Spin State ◽  
Magnetic Behaviour ◽  
Single Molecule Magnet ◽  
Epr Measurements

A trigonal-planar Fe(iii) complex Fe[N(SiMe3)2]3 with a high spin state (S = 5/2) was investigated by magnetic and HF-EPR measurements, exhibiting distinct dynamic magnetic behaviour.

Theoretical study on the reduction reactions from solid char(N): The effect of the nearby group and the high-spin state

Energy ◽  
2019 ◽  
Vol 189 ◽  
pp. 116286 ◽  
Author(s):  
Hai Zhang ◽  
Lei Luo ◽  
Jiaxun Liu ◽  
Anyao Jiao ◽  
Jianguo Liu ◽  
...  
Keyword(s):  
High Spin ◽  
Spin State ◽  
Theoretical Study ◽  
High Spin State ◽  
Reduction Reactions

scholarly journals Supercooled high spin state in metallo-supramolecular assemblies

2007 ◽  
Vol 63 (a1) ◽  
pp. s202-s202
Author(s):  
U. Pietsch ◽  
M. Lommel ◽  
Y. Bodethin ◽  
D. Kurth ◽  
G. Schwarzl ◽  
...  
Keyword(s):  
High Spin ◽  
Spin State ◽  
High Spin State ◽  
Supramolecular Assemblies

High-Spin State Fe(III) Doped TiO2 for Electrocatalytic Nitrogen Fixation Induced by Surface F Modification

2021 ◽  
pp. 120809
Author(s):  
Guangxin Song ◽  
Rui Gao ◽  
Zhao Zhao ◽  
Yujun Zhang ◽  
Huaqiao Tan ◽  
...  
Keyword(s):  
Nitrogen Fixation ◽  
High Spin ◽  
Spin State ◽  
High Spin State ◽  
Doped Tio2

Electric Field Induced Room Temperature Null to High Spin State Switching: A Computational Prediction

2019 ◽  
Vol 2 (4) ◽  
pp. 1900005 ◽  
Author(s):  
Carlos O. Amorim ◽  
João S. Amaral ◽  
João N. Gonçalves ◽  
Vítor S. Amaral
Keyword(s):  
Electric Field ◽  
High Spin ◽  
Spin State ◽  
Room Temperature ◽  
High Spin State ◽  
Computational Prediction ◽  
State Switching

scholarly journals A Co-based single-molecule magnet confined in a barium phosphate apatite matrix with a high energy barrier for magnetization relaxation

2017 ◽  
Vol 53 (39) ◽  
pp. 5416-5419 ◽  
Author(s):  
Pavel E. Kazin ◽  
Mikhail A. Zykin ◽  
Lev A. Trusov ◽  
Artem A. Eliseev ◽  
Oxana V. Magdysyuk ◽  
...  
Keyword(s):  
High Spin ◽  
Single Molecule ◽  
Energy Barrier ◽  
High Energy ◽  
Magnetization Relaxation ◽  
Single Molecule Magnet ◽  
High Energy Barrier ◽  
Spin Reversal ◽  
Type Lattice ◽  
Apatite Type

A Co-ion introduced into the trigonal channel of an apatite-type lattice forms a magnetically anisotropic two-coordinated Co-complex with a record-high spin-reversal energy barrier.

Vibrational Coherences and Relaxation in the High-Spin State of Aqueous [FeII(bpy)3]2+

2009 ◽  
Vol 121 (39) ◽  
pp. 7320-7323 ◽  
Author(s):  
Cristina Consani ◽  
Mirabelle Prémont-Schwarz ◽  
Amal ElNahhas ◽  
Christian Bressler ◽  
Frank van Mourik ◽  
...  
Keyword(s):  
High Spin ◽  
Spin State ◽  
High Spin State
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