Highly stable Y(iii)-based metal organic framework with two molecular building block for selective adsorption of C2H2 and CO2 over CH4

2018 ◽  
Vol 5 (5) ◽  
pp. 1193-1198 ◽  
Author(s):  
Xing Duan ◽  
Ran Lv ◽  
Zhenguo Ji ◽  
Bin Li ◽  
Yuanjing Cui ◽  
...  
Keyword(s):  
Chemical Stability ◽  
Building Block ◽  
Selective Adsorption ◽  
Metal Organic Framework ◽  
Selective Separation ◽  
Molecular Building Block ◽  
Metal Organic ◽  
Thermal And Chemical Stability ◽  
Organic Framework

A novel microporous MOF ZJU-16 exhibited high thermal and chemical stability and moderately high selective separation of C2H2/CH4 and CO2/CH4.

Incorporation of an intact dimeric Zr12 oxo cluster from a molecular precursor in a new zirconium metal–organic framework

2018 ◽  
Vol 54 (22) ◽  
pp. 2735-2738 ◽  
Author(s):  
Andrey A. Bezrukov ◽  
Karl W. Törnroos ◽  
Erwan Le Roux ◽  
Pascal D. C. Dietzel
Keyword(s):  
Building Block ◽  
Metal Organic Framework ◽  
Metal Organic Frameworks ◽  
Molecular Building Block ◽  
Molecular Precursor ◽  
Metal Organic ◽  
Zirconium Metal ◽  
Organic Framework

A dimeric Zr12 oxo cluster was used as new molecular building block in construction of metal–organic frameworks utilizing the precursor approach.

A heterometallic metal–organic framework based on multi-nuclear clusters exhibiting high stability and selective gas adsorption

2019 ◽  
Vol 48 (1) ◽  
pp. 278-284 ◽  
Author(s):  
Dongmei Wang ◽  
Zihua Liu ◽  
Lili Xu ◽  
Chunxia Li ◽  
Dian Zhao ◽  
...  
Keyword(s):  
Chemical Stability ◽  
High Performance ◽  
High Stability ◽  
Gas Adsorption ◽  
Metal Organic Framework ◽  
Gas Storage ◽  
Nuclear Clusters ◽  
Metal Organic ◽  
Thermal And Chemical Stability ◽  
Organic Framework

Porous In/Tb-CBDA has been successfully synthesized in the light of the heterometallic cooperative crystallization (HCC) approach. In/Tb-CBDA with high thermal and chemical stability exhibited high performance for gas storage and separation.

A new two-dimensional cadmium metal–organic framework: poly[bis(4,7-diphenyl-1,10-phenanthroline)(μ3-5-nitroisophthalato)cadmium(II)]

2012 ◽  
Vol 68 (11) ◽  
pp. m306-m308
Author(s):  
Jun-Wei Ye ◽  
Li-Mei Zhao ◽  
Wei Li ◽  
Gui-Ling Ning
Keyword(s):  
Building Block ◽  
General Position ◽  
Metal Organic Framework ◽  
Building Blocks ◽  
Two Dimensional ◽  
Aromatic Rings ◽  
Molecular Building Block ◽  
Cadmium Metal ◽  
Metal Organic ◽  
Organic Framework

In the title cadmium metal–organic framework complex, [Cd(C8H3NO6)(C24H16N2)]nor [Cd(NIPH)(dpphen)] (NIPH is nitroisophthalate and dpphen is 4,7-diphenyl-1,10-phenanthroline), the unique CdIIcation in a general position is coordinated by four carboxy O atoms from three symmetry-related NIPH anions and two N atoms from a dpphen ligand. The CdIIcations are bridged by pairs of NIPH anions to generate a dinuclear molecular building block, [Cd2N4(CO2R)4], with a Cd...Cd separation of 4.0936 (10) Å. Each such building block is connected to four adjacent dinuclear building blocks by NIPH anions, resulting in a two-dimensional layer framework in thebcplane. The dpphen ligands occupy the space between these layers and are linked by π–π interactions, with a separation of 3.4541 (6) Å between the central aromatic rings of inversion-related dpphen ligands. The thermogravimetric and photoluminescent properties of the complex have also been investigated.

Investigation on Zr-based metal-organic framework (MOF-801) for high-performance separation of light alkanes

2021 ◽  
Author(s):  
Hao Liu ◽  
Boran Li ◽  
Yayun Zhao ◽  
Chunlong Kong ◽  
Chen Zhou ◽  
...  
Keyword(s):  
Chemical Stability ◽  
High Performance ◽  
Metal Organic Framework ◽  
Synthesis Method ◽  
Light Alkanes ◽  
Separation Selectivity ◽  
Metal Organic ◽  
High Separation ◽  
Thermal And Chemical Stability ◽  
Organic Framework

A Zr-based metal-organic framework (MOF-801) with high thermal and chemical stability was prepared by solvethermal synthesis method. Notably, MOF-801 exhibits high separation selectivity for C3H8/CH4 and C2H6/CH4, making it possible...

A stable anionic metal–organic framework with open coordinated sites: selective separation toward cationic dyes and sensing properties

CrystEngComm ◽  
2019 ◽  
Vol 21 (7) ◽  
pp. 1159-1167 ◽  
Author(s):  
Wei Gao ◽  
Feng Liu ◽  
Chang-Wei Pan ◽  
Xiu-Mei Zhang ◽  
Jie-Ping Liu ◽  
...  
Keyword(s):  
Selective Adsorption ◽  
Metal Organic Framework ◽  
Selective Separation ◽  
Cationic Dyes ◽  
Sensing Properties ◽  
Luminescent Sensor ◽  
Metal Organic ◽  
Organic Framework

A multifunctional anionic metal–organic framework was successfully synthesized using a new pyridyl–tricarboxylate ligand. It could be applied as a luminescent sensor for Fe3+ ions and TNP and it showed selective adsorption of cationic dyes.

scholarly journals A Thorium Metal‐Organic Framework with Outstanding Thermal and Chemical Stability

2019 ◽  
Vol 25 (29) ◽  
pp. 7114-7118 ◽  
Author(s):  
Korey P. Carter ◽  
J. August Ridenour ◽  
Mark Kalaj ◽  
Christopher L. Cahill
Keyword(s):  
Chemical Stability ◽  
Metal Organic Framework ◽  
Metal Organic ◽  
Thermal And Chemical Stability ◽  
Organic Framework

An exceptionally stable functionalized metal–organic framework for lithium storage

2015 ◽  
Vol 51 (4) ◽  
pp. 697-699 ◽  
Author(s):  
Yichao Lin ◽  
Qiuju Zhang ◽  
Chongchong Zhao ◽  
Huailong Li ◽  
Chunlong Kong ◽  
...  
Keyword(s):  
Chemical Stability ◽  
Metal Organic Framework ◽  
Lithium Storage ◽  
Metal Organic ◽  
Li Storage ◽  
Thermal And Chemical Stability ◽  
Storage Ability ◽  
Organic Framework

A new functionalized MOF with remarkable thermal and chemical stability, and Li storage ability has been designed and synthesized.

Selective adsorption and separation of C2 hydrocarbons in a “flexible-robust” metal–organic framework based on a guest-dependent gate-opening effect

2020 ◽  
Vol 56 (41) ◽  
pp. 5520-5523
Author(s):  
Peng-Dan Zhang ◽  
Xue-Qian Wu ◽  
Tao He ◽  
Lin-Hua Xie ◽  
Qiang Chen ◽  
...  
Keyword(s):  
Selective Adsorption ◽  
Metal Organic Framework ◽  
Gate Opening ◽  
Metal Organic ◽  
C2 Hydrocarbons ◽  
Organic Framework

The selective adsorption and separation of C2 hydrocarbons have been achieved in a “flexible-robust” MOF based on a guest-dependent gate-opening effect.

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