A fluorescent pillarene coordination polymer

2019 ◽  
Vol 10 (23) ◽  
pp. 2980-2985 ◽  
Author(s):  
Ming-Xue Wu ◽  
Ying-Wei Yang
Keyword(s):  
Coordination Polymer ◽  
Dicarboxylic Acid

A fluorescent pillarene-based coordination polymer was constructed from dicarboxylic acid-functionalized copillar[5]arene and Cr3+, for sensing of Fe3+, acetone, and nitrophenols.

A new 3-D Cd(II) coordination polymer with metallacalix[4]arene building blocks based on 2-(pyridin-2-yl)-1H-imidazole-4,5-dicarboxylic acid

2015 ◽  
Vol 68 (20) ◽  
pp. 3580-3588 ◽  
Author(s):  
Xiao-Yang Yu ◽  
Xiao Zhang ◽  
Xiao-Shu Qu ◽  
Ming-Shuo Ma ◽  
Zhi-Gang Liu ◽  
...  
Keyword(s):  
Coordination Polymer ◽  
Dicarboxylic Acid ◽  
Building Blocks

A Co(ii) 1D coordination polymer constructed from 1,3-bisbenzyl-2-oxoimidazoline-4,5-dicarboxylic acid: crystal structure and magnetic properties

2018 ◽  
Vol 42 (2) ◽  
pp. 1216-1222 ◽  
Author(s):  
Felipe Mageste Scaldini ◽  
Maria Clara Ramalho Freitas ◽  
Mario De Souza Reis ◽  
Maria Irene Yoshida ◽  
Klaus Krambrock ◽  
...  
Keyword(s):  
Crystal Structure ◽  
Magnetic Properties ◽  
Coordination Polymer ◽  
Dicarboxylic Acid ◽  
Metal Ion ◽  
Acid Crystal ◽  
1D Coordination Polymer ◽  
Solvothermal Conditions

A new complex involving 1,3-bisbenzyl-2-oxoimidazoline-4,5-dicarboxylic acid (H2L) and a cobalt(ii) metal ion designated [Co(L)(H2O)2]n has been synthesized under solvothermal conditions and characterized.

A novel copper(II) coordination polymer with 2,2′-bipyridyl-3,3′-dicarboxylic acid

2004 ◽  
Vol 61 (1) ◽  
pp. m48-m50 ◽  
Author(s):  
Bao-Zhong Zhao ◽  
Xiang-Rong Hao ◽  
Zhan-Gang Han ◽  
Qiang Fu ◽  
Ya-Guang Chen
Keyword(s):  
Coordination Polymer ◽  
Dicarboxylic Acid

A new two-dimensional manganese(II) coordination polymer based on thiophene-3,4-dicarboxylic acid

2014 ◽  
Vol 70 (7) ◽  
pp. 715-717
Author(s):  
Gui-Xia Wang ◽  
Li-Li Shang ◽  
Zhao-Hao Li ◽  
Bang-Tun Zhao
Keyword(s):  
Coordination Polymer ◽  
Dicarboxylic Acid ◽  
Ir Spectrum ◽  
Coordination Mode ◽  
The Novel ◽  
Two Dimensional ◽  
Asymmetric Unit ◽  
One Dimensional ◽  
Carboxylate Groups ◽  
Organic Linker

A novel manganese coordination polymer, poly[(μ5-thiophene-3,4-dicarboxylato)manganese(II)], [Mn(C6H2O4S)]n, was synthesized hydrothermally using 3,4-thiophenedicarboxylate (3,4-tdc2−) as the organic linker. The asymmetric unit of the complex contains an Mn2+cation and one half of a deprotonated 3,4-tdc2−anion, both residing on a twofold axis. Each Mn2+centre is six-coordinated by O atoms of bridging/chelating carboxylate groups from five 3,4-tdc2−anions, forming a slightly distorted octahedron. The Mn2+centres are bridged by 3,4-tdc2−anions to give an infinite two-dimensional layer which incorporates one-dimensional Mn–O gridlike chains, and in which the 3,4-tdc2−anion adopts a novel hexadentate chelating and μ5-bridging coordination mode. The fully deprotonated 3,4-tdc2−anion exhibits unexpected efficiency as a ligand towards the Mn2+centres, which it coordinates through all of its carboxylate O atoms to provide the novel coordination mode. The IR spectrum of the complex is also reported.

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