scholarly journals New electroactive macromonomers and multi-responsive PEDOT graft copolymers

2018 ◽  
Vol 9 (27) ◽  
pp. 3780-3790 ◽  
Author(s):  
Sara Marina ◽  
Daniele Mantione ◽  
Kasina ManojKumar ◽  
Vijayakrishna Kari ◽  
Junkal Gutierrez ◽  
...  

Poly(3,4-ethylenedioxithiophene) (PEDOT) is the conducting polymer with the biggest prospects in the field of organic electronics due to its high electrical conductivity and transparency as thin films.

2020 ◽  
Vol 02 (03) ◽  
pp. 223-228
Author(s):  
Dafei Yuan ◽  
Xiaozhang Zhu

Developing stable and solution-processable highly conductive polymers has been the research goal in organic electronics since the first demonstration of metallic conductive polyacetylene. Here, we used a unique quinoid-resonant building block thieno[3,4-b]thiophene (TbT) to develop a new water-dispersible conducting polymer, PTbT-Me:PSS. Linear polymerization and large surfactant counterion, poly(styrenesulfonate) (PSS−), were introduced, which enabled a high electrical conductivity of 68 S cm−1 and exhibited water-dispersible property. Interchain bipolaron was found in PTbT-Me:PSS when compared with polaron in PEDOT:PSS in their conducting mechanism. Moreover, we applied this highly conductive PTbT-Me:PSS as the solution-processed polymer thermoelectric material and a decent power factor of 3.1 μW m−1 K−2 was achieved.


ACS Nano ◽  
2009 ◽  
Vol 3 (6) ◽  
pp. 1373-1378 ◽  
Author(s):  
Yude Wang ◽  
Torsten Brezesinski ◽  
Markus Antonietti ◽  
Bernd Smarsly

2007 ◽  
Vol 352 ◽  
pp. 315-318 ◽  
Author(s):  
Akihiko Ito ◽  
Hiroshi Masumoto ◽  
Takashi Goto

Epitaxial BaRuO3 (BRO) and CaRuO3 (CRO) thin films were prepared on (001), (110) and (111) SrTiO3 (STO) single-crystal substrates by laser ablation, and their microstructures and anisotropy of electrical conductivity were investigated. The (205) (104), (110) and (009) oriented BRO thin films, and (001), (110) and (110) oriented CRO thin films were grown epitaxially on (001), (110) and (111) STO substrates with in-plain orientation, respectively. The (009) BRO thin film and (001) CRO thin film has a flat surface result from a good lattice matching to STO substrates. The (205) (104) BRO thin film and (111) CRO thin film exhibited orthogonal- and hexagonal-shaped texture, respectively. The (110) BRO thin film and (110) CRO thin film showed an island growth due to (110) surface feature of cubic perovskite structure. Epitaxial BRO and CRO thin films have a high electrical conductivity with a metallic conduction, the (111) CRO thin films exhibited the highest conductivity of 1.4×105 S·m-1.


2020 ◽  
Vol 8 (48) ◽  
pp. 17254-17260
Author(s):  
Amélie Schultheiss ◽  
Alexandre Carella ◽  
Stéphanie Pouget ◽  
Jérôme Faure-Vincent ◽  
Renaud Demadrille ◽  
...  

A careful control of the water content during PEDOT polymerization allow to reach extremely high electrical conductivity.


2015 ◽  
Vol 35 (8) ◽  
pp. 731-741 ◽  
Author(s):  
Andrzej Katunin ◽  
Katarzyna Krukiewicz

Abstract This article deals with the electrical conductivity of a composite of two polymers, one of which is a conducting polymer, whereas the second is a dielectric. The problem was formulated within the framework of electrical percolation, i.e., the percolation thresholds, which allow for a high electrical conductivity, is under investigation. For this purpose, a numerical model was developed, and its parameters were analyzed and discussed. Based on the determined thresholds, it was possible to evaluate the weight ratios of the conducting-dielectric polymers in a composite. The proposed approach allows for reducing the manufacturing cost of composite material with respect to conducting polymers with simultaneous retaining of high conductance properties of conducting polymers, as well as durability and flexibility of dielectrics.


2015 ◽  
Vol 3 (39) ◽  
pp. 10256-10266 ◽  
Author(s):  
Ivan Puchades ◽  
Colleen C. Lawlor ◽  
Christopher M. Schauerman ◽  
Andrew R. Bucossi ◽  
Jamie E. Rossi ◽  
...  

Electronic-type-separated SWCNTs thin-films were used to demonstrate that the strength of the redox potential of dopants influences their electrical conductivity enhancement.


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