Polymerization-induced self-assembly of liquid crystalline ABC triblock copolymers with long solvophilic chains

2018 ◽  
Vol 9 (28) ◽  
pp. 3944-3951 ◽  
Author(s):  
Meng Huo ◽  
Zhengyi Wan ◽  
Min Zeng ◽  
Yen Wei ◽  
Jinying Yuan
Keyword(s):  
Self Assembly ◽  
Liquid Crystalline ◽  
Triblock Copolymers ◽  
The Self ◽  
Abc Triblock Copolymers ◽  
Assembly Behavior

Polymerization-induced self-assembly was exploited to investigate the self-assembly behavior of liquid crystalline triblock copolymers with long solvophilic chains.

scholarly journals Influence of nucleobase stoichiometry on the self-assembly of ABC triblock copolymers

2016 ◽  
Vol 52 (48) ◽  
pp. 7564-7567 ◽  
Author(s):  
Keren Zhang ◽  
Samantha J. Talley ◽  
Ya Peng Yu ◽  
Robert B. Moore ◽  
Mitsuhiro Murayama ◽  
...  
Keyword(s):  
Long Range ◽  
Self Assembly ◽  
Triblock Copolymers ◽  
The Self ◽  
Patterned Substrates ◽  
Abc Triblock Copolymers ◽  
Self Assembled

ABC triblock copolymers bearing adenine- and thymine-functionalized external blocks self-assembled into long-range, ordered lamellar microphase-separated morphologies on non-patterned substrates.

scholarly journals The Monoglyceride Content Affects the Self-Assembly Behavior, Rheological Properties, Syringeability, and Mucoadhesion of In Situ–Gelling Liquid Crystalline Phase

2016 ◽  
Vol 105 (8) ◽  
pp. 2355-2364 ◽  
Author(s):  
Kariane M. Nunes ◽  
Cristian C.C. Teixeira ◽  
Renata C.K. Kaminski ◽  
Victor H.V. Sarmento ◽  
Renê O. Couto ◽  
...  
Keyword(s):  
Rheological Properties ◽  
Crystalline Phase ◽  
Self Assembly ◽  
Liquid Crystalline ◽  
The Self ◽  
Liquid Crystalline Phase ◽  
Assembly Behavior ◽  
In Situ Gelling

Self-Assembly Behavior of N-Methly-N-Hexadecyl-Pyrrolidinium Bromide in Water

2012 ◽  
Vol 557-559 ◽  
pp. 611-614 ◽  
Author(s):  
Jin Hua He ◽  
Cui Hua Li ◽  
Lian An Qian ◽  
Jian Hong Liu ◽  
Qian Ling Zhang
Keyword(s):  
Ionic Liquid ◽  
Liquid Crystals ◽  
Crystalline Phase ◽  
Self Assembly ◽  
Liquid Crystalline ◽  
Hexagonal Phase ◽  
The Self ◽  
Package Effect ◽  
Ionic Liquid Crystals ◽  
Assembly Behavior

N-methyl-N-hexadecylpyrrolidinium bromide (IL) was synthesized for the design of ionic liquid crystals which is a fascinating class of molecular materials, offering the combination of order and mobility. In binary mixtures with water, lyotropic liquid crystalline phase appears in the range of IL content from 35% to 70% and the temperature range from -1.1 to 24 °C in the heating run. The SAXS curves explored the self-assembly processes and hexagonal phase of the IL apparent sol. The saturated aliphatic ionic liquid in water assemble less tightly compared with aromatic ionic liquid based on imidazolium in water, which is due to the absence of aromatic package effect.

Synthesis, characterization and self-assembly behavior of zwitterionic amphiphilic triblock copolymers bearing pendant amino acid residues

RSC Advances ◽  
2015 ◽  
Vol 5 (116) ◽  
pp. 96181-96188 ◽  
Author(s):  
Xiaohong Shang ◽  
Xiaoshan Fan ◽  
Shaohui Yang ◽  
Zhengzheng Xie ◽  
Yuming Guo ◽  
...  
Keyword(s):  
Amino Acid ◽  
Self Assembly ◽  
Triblock Copolymers ◽  
The Self ◽  
Amino Acid Residues ◽  
Assembly Behavior

Zwitterionic amphiphilic triblock copolymers bearing pendant amino acid residues PAGE/cys-b-PCL-b-PEG were synthesized and characterized. The self-assembly behavior of the copolymers was studied.

Influence of variations in liquid-crystalline content upon the self-assembly behavior of siloxane-based block copolymers

Soft Matter ◽  
2008 ◽  
Vol 4 (6) ◽  
pp. 1279 ◽  
Author(s):  
Eric Verploegen ◽  
Tejia Zhang ◽  
Nicholas Murlo ◽  
Paula T. Hammond
Keyword(s):  
Block Copolymers ◽  
Self Assembly ◽  
Liquid Crystalline ◽  
The Self ◽  
Assembly Behavior

Dissipative particle dynamics simulation on the self-assembly of linear ABC triblock copolymers under rigid spherical confinements

e-Polymers ◽  
2017 ◽  
Vol 17 (4) ◽  
pp. 321-331 ◽  
Author(s):  
Xiaoqiang Liu ◽  
Chun Zhou ◽  
Honggang Xia ◽  
Yang Zhou ◽  
Weidong Jiang
Keyword(s):  
Self Assembly ◽  
Triblock Copolymers ◽  
Dissipative Particle Dynamics ◽  
Particle Dynamics ◽  
The Self ◽  
Dynamics Simulation ◽  
Block Sequence ◽  
Abc Triblock Copolymers ◽  
Dynamics Simulations ◽  
Dissipative Particle Dynamics Simulation

AbstractAlthough a great deal of unique nanostructures were already obtained from polymer self-assemblies in terms of conventional parameters, the self-assembly under the confinement is still not well understood. Here, dissipative particle dynamics simulations were used to explore the self-assemble behaviors of linear ABC triblock copolymers under rigid spherical confinements. First several unusual morphologies, such as multilayer onion, coupled helix, and stacked lamella, were distinguished from the total 210 simulations. Second, the influences of three important parameters (block sequence, wall selectivity, and spherical radius) on the morphologies were discussed in detail. Finally, the dynamics evolution of several typical aggregates was examined. This simulation enriches micelle morphologies for the self-assembly of linear ABC triblock copolymers under rigid spherical confinements and is helpful to understand the formation of valuable nanostructures from linear ABC terpolymers.

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