scholarly journals Recent advances in homogeneous borrowing hydrogen catalysis using earth-abundant first row transition metals

2019 ◽  
Vol 17 (7) ◽  
pp. 1595-1607 ◽  
Author(s):  
Benjamin G. Reed-Berendt ◽  
Kurt Polidano ◽  
Louis C. Morrill

The review highlights the recent advances (2013-present) in the use of earth-abundant first row transition metals in homogeneous borrowing hydrogen catalysis.

Catalysts ◽  
2021 ◽  
Vol 11 (1) ◽  
pp. 58
Author(s):  
Sylwia Kostera ◽  
Maurizio Peruzzini ◽  
Luca Gonsalvi

The use of CO2 as a C1 building block for chemical synthesis is receiving growing attention, due to the potential of this simple molecule as an abundant and cheap renewable feedstock. Among the possible reductants used in the literature to bring about CO2 reduction to C1 derivatives, hydroboranes have found various applications, in the presence of suitable homogenous catalysts. The current minireview article summarizes the main results obtained since 2016 in the synthetic design of main group, first and second row transition metals for use as catalysts for CO2 hydroboration.


RSC Advances ◽  
2021 ◽  
Vol 11 (13) ◽  
pp. 7146-7179
Author(s):  
P. V. Saranya ◽  
Mohan Neetha ◽  
Thaipparambil Aneeja ◽  
Gopinathan Anilkumar

Spirooxindoles are used as anticancer-, antiviral-, antimicrobial agents etc. The use of transition metals as catalysts for the synthesis of spirooxindoles is advancing rapidly. Here, we focus on recent advances in transition metal-catalyzed synthesis of spirooxindoles.


Synthesis ◽  
2017 ◽  
Vol 49 (12) ◽  
pp. 2589-2604 ◽  
Author(s):  
Kristen Gettys ◽  
Zhishi Ye ◽  
Mingji Dai

Piperazine ranks as the third most common N-heterocycle appearing in small-molecule pharmaceuticals. This review highlights recent advances in methods development for the construction of the piperazine­ ring system with particular emphasis on preparing carbon-substituted piperazines.1 Introduction2 Reduction of (Di)ketopiperazine3 N-Alkylation4 Transition-Metal-Catalyzed/Mediated Piperazine Synthesis4.1 The SnAP and SLAP Methods4.2 Palladium-Catalyzed Cyclization4.3 Gold-Catalyzed Cyclization4.4 Other Metal-Catalyzed/Mediated Cyclization4.5 Borrowing Hydrogen Strategy4.6 Imine Reductive Cyclization5 Reduction of Pyrazines6 Miscellaneous7 Conclusion


2018 ◽  
Vol 47 (45) ◽  
pp. 16019-16026 ◽  
Author(s):  
Claudio Saracini ◽  
Shunichi Fukuzumi ◽  
Yong-Min Lee ◽  
Wonwoo Nam

This Frontier article reviews recent advances on the excited state reactivity of earth-abundant metal–oxygen complexes.


ACS Catalysis ◽  
2020 ◽  
Vol 10 (19) ◽  
pp. 10886-10904
Author(s):  
Shuyan Gong ◽  
Yu-Xiao Zhang ◽  
Zhiqiang Niu

Molecules ◽  
2017 ◽  
Vol 22 (11) ◽  
pp. 1901 ◽  
Author(s):  
Sophie Bezzenine-Lafollée ◽  
Richard Gil ◽  
Damien Prim ◽  
Jérôme Hannedouche

2018 ◽  
Vol 59 (10) ◽  
pp. 862-868 ◽  
Author(s):  
Nimmakuri Rajesh ◽  
Nagaraju Barsu ◽  
Basker Sundararaju

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