Visible light-induced aerobic oxidative cross-coupling of glycine esters with α-angelicalactone: a facile pathway to γ-lactams

2018 ◽  
Vol 16 (36) ◽  
pp. 6728-6734 ◽  
Author(s):  
Huang Zhou ◽  
Xiaorong Yang ◽  
Shilin Li ◽  
Yin Zhu ◽  
Ying Li ◽  
...  
Keyword(s):  
Visible Light ◽  
Cross Coupling ◽  
Rapid Synthesis ◽  
Metal Free

A rapid synthesis of substituted γ-lactams is achieved via metal-free photocatalyzed aerobic oxidative dehydrogenative formal [2 + 3] cyclization of glycine esters with α-angelicalactone.

scholarly journals Metal-Free C-Se Cross-Coupling Enabled by Photoinduced Intermolecular Charge Transfer

2021 ◽  
Author(s):  
Chen Zhu ◽  
Serik Zhumagazy ◽  
Huifeng Yue ◽  
Magnus Rueping
Keyword(s):  
Charge Transfer ◽  
Visible Light ◽  
Electron Donor ◽  
Cross Coupling ◽  
Metal Free ◽  
Intermolecular Charge Transfer ◽  
Donor Acceptor

Metal-free C-Se cross-couplings via the formation of electron-donor-acceptor (EDA) complexes have been developed. The visible-light induced reactions can be applied for the synthesis of a series of unsymmetrical diaryl selenides...

Photoinduced Oxidative Cross-Coupling for O–S Bond Formation: A Facile Synthesis of Alkyl Benzenesulfonates

Synlett ◽  
2017 ◽  
Vol 28 (13) ◽  
pp. 1558-1563 ◽  
Author(s):  
Aiwen Lei ◽  
Atul Singh ◽  
Hong Yi ◽  
Guoting Zhang ◽  
Changliang Bian ◽  
...  
Keyword(s):  
Visible Light ◽  
Bond Formation ◽  
Cross Coupling ◽  
Selective Synthesis ◽  
Mechanistic Studies ◽  
Facile Synthesis ◽  
Metal Free

We have developed a photoinduced oxidative cross-coupling of thiophenols with alcohols for O–S bond formation. The protocol uses visible light, a metal-free photocatalyst, and oxygen as the oxidant for the selective synthesis of alkyl benzenesulfonates; no ligand co-additive is necessary. Mechanistic studies suggested that the disulfide and alkyl benzenesulfinate are involved as intermediates and that the transformation proceeds by a radical pathway.

Visible light-induced aerobic oxidative cross-coupling of glycine derivatives with indoles: a facile access to 3,3′ bisindolylmethanes

2018 ◽  
Vol 5 (13) ◽  
pp. 2120-2125 ◽  
Author(s):  
Yuan Zhang ◽  
Xiaorong Yang ◽  
Huang Zhou ◽  
Shilin Li ◽  
Yin Zhu ◽  
...  
Keyword(s):  
Visible Light ◽  
Cross Coupling ◽  
Alkylation Reaction ◽  
Rapid Synthesis ◽  
Glycine Derivatives

A rapid synthesis of 3,3′-bisindolylmethanes is achieved via a photocatalyzed double Friedel–Crafts alkylation reaction between glycine derivatives and indoles.

Transition-metal-free, visible-light-induced oxidative cross-coupling for constructing β-acetylamino acrylosulfones from sodium sulfinates and enamides

2018 ◽  
Vol 5 (1) ◽  
pp. 92-97 ◽  
Author(s):  
Deli Sun ◽  
Ronghua Zhang
Keyword(s):  
Transition Metal ◽  
Visible Light ◽  
Rose Bengal ◽  
Cross Coupling ◽  
Metal Free

A visible-light-induced, Rose Bengal catalyzed photoredox process for synthesizing β-acetylamino acrylosulfones has been discovered.

Visible light-mediated cross-coupling of electrophiles: synthesis of α-amino amides from isocyanates and ketimines

2021 ◽  
Author(s):  
Junli Zhu ◽  
Cancan Dai ◽  
Mengyue Ma ◽  
Yanni Yue ◽  
Xinyuan Fan
Keyword(s):  
Visible Light ◽  
Cross Coupling ◽  
Metal Free ◽  
High Yields ◽  
Amino Amides

Cross-couplings between the electrophilic ketimines and isocyanates are achieved via the visible light-mediated reactivity inversion of the ketimines, affording the desired α-amino amides in high yields, with both metal and metal-free systems.

Visible Light-Mediated Photocatalytic Metal-Free Cross-Coupling Reaction of Alkenyl Carboxylic Acids with Diarylphosphine Oxides Leading to β-Ketophosphine Oxides

2018 ◽  
Vol 20 (18) ◽  
pp. 5947-5951 ◽  
Author(s):  
Hai-Feng Qian ◽  
Cheng-Kun Li ◽  
Zhi-Hao Zhou ◽  
Ze-Kun Tao ◽  
Adedamola Shoberu ◽  
...  
Keyword(s):  
Visible Light ◽  
Carboxylic Acids ◽  
Coupling Reaction ◽  
Cross Coupling ◽  
Metal Free ◽  
Cross Coupling Reaction

Metal-Free Visible-Light-Mediated Oxidative Cross-Coupling of Thiols with P(O)H Compounds Using Air as the Oxidant

2016 ◽  
Vol 18 (19) ◽  
pp. 5114-5117 ◽  
Author(s):  
Jian-Guo Sun ◽  
Hua Yang ◽  
Ping Li ◽  
Bo Zhang
Keyword(s):  
Visible Light ◽  
Cross Coupling ◽  
Metal Free
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