Hybrid hollow spheres of carbon@CoxNi1−xMoO4 as advanced electrodes for high-performance asymmetric supercapacitors

Nanoscale ◽  
2019 ◽  
Vol 11 (7) ◽  
pp. 3281-3291 ◽  
Author(s):  
Junsheng Lin ◽  
Lei Yao ◽  
Zheling Li ◽  
Peixin Zhang ◽  
Wenhua Zhong ◽  
...  

Hollow carbon nanospheres decorated with CoxNi1−xMoO4 nanosheets showed extraordinary rate performance and cycling stability as electrodes in supercapacitors.

2021 ◽  
Author(s):  
Bei Li ◽  
Ling Xie ◽  
Yanping Liu ◽  
Dongrui Yao ◽  
Lei Yao ◽  
...  

Abstract Taking advantage of both Faradaic and carbonaceous materials is an efficient way to synthesize composite electrodes with enhanced performance for supercapacitors. In this study, NiCo2S4 nanoflakes were grown on the surface of nitrogen-doped hollow carbon nanospheres (NHCSs), forming a NiCo2S4/NHCS composite with a core-shell structure. This three-dimensionally confined growth of NiCo2S4 can effectively inhibit its aggregation and facilitate mass transport and charge transfer. Accordingly, the NiCo2S4/NHCS composite exhibited high cycling stability with only 9.2% capacitance fading after 10,000 cycles, outstanding specific capacitance of 902 F g−1 at 1 A g−1, and it retained 90.6% of the capacitance at 20 A g−1. Moreover, an asymmetric supercapacitor composed of NiCo2S4/NHCS and activated carbon electrodes delivered remarkable energy density (31.25 Wh kg−1 at 750 W kg−1), excellent power density (15003 W kg−1 at 21.88 Wh kg−1), and satisfactory cycling stability (13.4% capacitance fading after 5000 cycles). The outstanding overall performance is attributed to the synergistic effect of the NiCo2S4 shell and NHSC core, which endows the composite with a stable structure, high electrical conductivity, abundant active reaction sites, and short ion-transport pathways. The synthesized NiCo2S4/NHCS composite is a competitive candidate for the electrodes of high-performance supercapacitors.


CrystEngComm ◽  
2020 ◽  
Vol 22 (21) ◽  
pp. 3588-3597 ◽  
Author(s):  
Xiangchen Zhao ◽  
Guiling Niu ◽  
Hongxun Yang ◽  
Jiaojiao Ma ◽  
Mengfei Sun ◽  
...  

New MIL-88A@polyoxometalates microrods have been constructed via a simple one-step hydrothermal method, exhibiting the improved lithium storage capacity, rate performance and cycling stability.


2018 ◽  
Vol 6 (4) ◽  
pp. 1802-1808 ◽  
Author(s):  
Ke Li ◽  
Yanshan Huang ◽  
Jingjing Liu ◽  
Mansoor Sarfraz ◽  
Phillips O. Agboola ◽  
...  

Three-dimensional graphene frameworks enable the development of stretchable asymmetric supercapacitors with a record high energy density of 77.8 W h kg−1, and also excellent stretchability and superior cycling stability.


2017 ◽  
Vol 5 (27) ◽  
pp. 14301-14309 ◽  
Author(s):  
S. Kamari Kaverlavani ◽  
S. E. Moosavifard ◽  
A. Bakouei

Increasing demand for green energy storage systems, arising from the rapid development of portable electronics, has triggered tremendous research efforts for designing new or high-performance electrodes.


2018 ◽  
Vol 5 (16) ◽  
pp. 2242-2249 ◽  
Author(s):  
Zhongbing Wang ◽  
Hongwen Qiang ◽  
Zihao Zhu ◽  
Jinpeng Liu ◽  
Chunnian Chen ◽  
...  

2020 ◽  
Vol 1 (3) ◽  
pp. 481-494 ◽  
Author(s):  
Jingzhou Ling ◽  
Hanbo Zou ◽  
Wei Yang ◽  
Shengzhou Chen

The NiCoP@C-ULAs composite with high conductivity, abundant pores and good physical structure shows high specific capacity and excellent cycling stability.


2019 ◽  
Vol 7 (18) ◽  
pp. 11117-11126 ◽  
Author(s):  
Linlin Wang ◽  
Bo Lu ◽  
Saisai Wang ◽  
Wei Cheng ◽  
Yufeng Zhao ◽  
...  

N/O dual dopant porous carbon nanocapsules simultaneously attain ultrafast lithium and sodium storage with both a high capacity and an ultralong cycling stability.


Sign in / Sign up

Export Citation Format

Share Document