Multifunctional reduced graphene oxide-CVD graphene core–shell fibers

Nanoscale ◽  
2019 ◽  
Vol 11 (26) ◽  
pp. 12637-12642 ◽  
Author(s):  
Yong Seok Choi ◽  
Chang-su Yeo ◽  
Sang Jin Kim ◽  
Jin-Young Lee ◽  
Youngsoo Kim ◽  
...  

The graphene-based fiber structure with rGO cores and CVD graphene shells, showing an outstanding electrical conductivity and electrochemical performance with enhanced mechanical stability and durability.

Molecules ◽  
2020 ◽  
Vol 25 (6) ◽  
pp. 1295 ◽  
Author(s):  
Katerina Vrettos ◽  
Konstantinos Spyrou ◽  
Vasilios Georgakilas

Graphene aerogel (GA) is a lightweight, porous, environmentally friendly, 3D structured material with interesting properties, such as electrical conductivity, a high surface area, and chemical stability, which make it a powerful tool in energy storage, sensing, catalyst support, or environmental applications. However, the poor mechanical stability that often characterizes graphene aerogels is a serious obstacle for their use in such applications. Therefore, we report here the successful mechanical reinforcement of GA with carbon fibers (CFs) by combining reduced graphene oxide (rGO) and CFs in a composite material. The surfaces of the CFs were first successfully desized and enriched with epoxy groups using epichloridrine. Epoxy-functionalized CFs (epoxy-CFs) were further covered by reduced graphene oxide (rGO) nanosheets, using triethylene tetramine (TETA) as a linker. The rGO-covered CFs were finally incorporated into the GA, affording a stiff monolithic aerogel composite. The as-prepared epoxy-CF-reinforced GA was characterized by spectroscopic and microscopic techniques and showed enhanced electrical conductivity and compressive strength. The improved electrical and mechanical properties of the GA-CFs composite could be used, among other things, as electrode material or strain sensor applications.


Molecules ◽  
2019 ◽  
Vol 24 (23) ◽  
pp. 4247 ◽  
Author(s):  
Rita Petrucci ◽  
Isabella Chiarotto ◽  
Leonardo Mattiello ◽  
Daniele Passeri ◽  
Marco Rossi ◽  
...  

Natural methylxanthines, caffeine, theophylline and theobromine, are widespread biologically active alkaloids in human nutrition, found mainly in beverages (coffee, tea, cocoa, energy drinks, etc.). Their detection is thus of extreme importance, and many studies are devoted to this topic. During the last decade, graphene oxide (GO) and reduced graphene oxide (RGO) gained popularity as constituents of sensors (chemical, electrochemical and biosensors) for methylxanthines. The main advantages of GO and RGO with respect to graphene are the easiness and cheapness of synthesis, the notable higher solubility in polar solvents (water, among others), and the higher reactivity towards these targets (mainly due to – interactions); one of the main disadvantages is the lower electrical conductivity, especially when using them in electrochemical sensors. Nonetheless, their use in sensors is becoming more and more common, with the obtainment of very good results in terms of selectivity and sensitivity (up to 5.4 × 10−10 mol L−1 and 1.8 × 10−9 mol L−1 for caffeine and theophylline, respectively). Moreover, the ability of GO to protect DNA and RNA from enzymatic digestion renders it one of the best candidates for biosensors based on these nucleic acids. This is an up-to-date review of the use of GO and RGO in sensors.


2021 ◽  
pp. 004051752199547
Author(s):  
Min Hou ◽  
Xinghua Hong ◽  
Yanjun Tang ◽  
Zimin Jin ◽  
Chengyan Zhu ◽  
...  

Functionalized knitted fabric, as a kind of flexible, wearable, and waterproof material capable of conductivity, sensitivity and outstanding hydrophobicity, is valuable for multi-field applications. Herein, the reduced graphene oxide (RGO)-coated knitted fabric (polyester/spandex blended) is prepared, which involves the use of graphite oxide (GO) by modified Hummers method and in-situ chemical reduction with hydrazine hydrate. The treated fabric exhibits a high electrical conductivity (202.09 S/cm) and an outstanding hydrophobicity (140°). The outstanding hydrophobicity is associated with the morphology of the fabric and fiber with reference to pseudo-infiltration. These properties can withstand repeated bending and washing without serious deterioration, maintaining good electrical conductivity (35.70 S/cm) and contact angle (119.39°) after eight standard washing cycles. The material, which has RGO architecture and continuous loop mesh structure, can find wide use in smart garment applications.


2016 ◽  
Vol 4 (40) ◽  
pp. 15302-15308 ◽  
Author(s):  
Zhigao Luo ◽  
Jiang Zhou ◽  
Lirong Wang ◽  
Guozhao Fang ◽  
Anqiang Pan ◽  
...  

We report the synthesis of a novel 2D hybrid nanosheet constructed by few layered MoSe2 grown on reduced graphene oxide (rGO), which exhibits excellent electrochemical performance as anodes for lithium ion batteries.


RSC Advances ◽  
2015 ◽  
Vol 5 (107) ◽  
pp. 88409-88413 ◽  
Author(s):  
Libang Kuai ◽  
Yong Zhou ◽  
Wengguang Tu ◽  
Ping Li ◽  
Haijin Li ◽  
...  

An all-solid-state Z-scheme was constructed for the photocatalytic reduction of CO2, consisting of CdS and TiO2 as photocatalysts, and reduced graphene oxide as a solid electron mediator.


RSC Advances ◽  
2013 ◽  
Vol 3 (29) ◽  
pp. 11807 ◽  
Author(s):  
Changdong Gu ◽  
Heng Zhang ◽  
Xiuli Wang ◽  
Jiangping Tu

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