Raman intensity enhancement of molecules adsorbed onto HfS2 flakes up to 200 layers

Nanoscale ◽  
2019 ◽  
Vol 11 (5) ◽  
pp. 2179-2185 ◽  
Author(s):  
Xiao Fei Yue ◽  
Yao Liang ◽  
Jie Jiang ◽  
Rong Gang Liu ◽  
Shou Tian Ren ◽  
...  

An optical interference effect successfully describes Raman spectra of HfS2 and Raman spectra of molecules adsorbed on HfS2.

1982 ◽  
Vol 60 (2) ◽  
pp. 174-189 ◽  
Author(s):  
J. J. C. Teixeira-Dias ◽  
V. M. Jardim-Barreto ◽  
Y. Ozaki ◽  
A. C. Storer ◽  
P. R. Carey

Infrared, Raman, and resonance Raman data are reported for ethyl and methyl dithioacetate together with data for their isotopically substituted analogs: CD3C(=S)SCH3, CH3C(=S)SCD3, 13CH3C(=S)SCH3, CH313C(=S)SCH3, CD3C(=S)SCH2CH3, CH3C(=S)SCD2CH3, and CH313C(=S)SCH2CH3. Based on these data and a normal coordinate analysis of methyl dithioacetate, assignments are proposed for the majority of bands appearing in the vibrational spectra. Using excitation wavelengths in the 324–356 nm region strong intensity enhancement is observed for Raman bands near 1195, 1100, 730, and 580 cm−1 which are assigned to stretching motions of the CCSSC skeleton. Raman excitation profiles are reported for the 1197 and 581 cm−1 bands of ethyl dithioacetate and the electronic absorbance peak near 305 nm is identified as the source of resonance Raman intensity enhancement.


1978 ◽  
Vol 56 (2) ◽  
pp. 240-245 ◽  
Author(s):  
D. J. Phelps ◽  
R. G. Carriere ◽  
K. Kumar ◽  
P. R. Carey

Resonance and preresonance Raman spectra of nine substituted trans-4-benzylidene- Δ2-oxazolin-5-ones are reported. The seven analogs with phenyl in the 2 position of the oxazolinone ring have either an electron donating or attracting group on one of the phenyl rings. Although shifts in λmax of up to 100 nm are observed the Raman spectra are very similar to that of the unsubstituted trans isomer. However, in the substituted compounds modes from the benzylidene portion may become weakly intensity enhanced. Replacing the 2-phenyl group by 2-methyl in the oxazolinone ring results in quite gross changes in the Raman spectrum. Substitution by 15N in the ring of a 2-methyloxazolinone reveals that a change in the vibrational coupling scheme occurs. Excitation profiles for the 2-phenyl and the 2-methyl analogs of 4-(p-nitrobenzylidene)oxazolinone indicate that in each compound ail intensity enhanced modes are coupled to the intense low energy absorption band near 350 nm and the intensity enhancement fits the FB2 terms of Albrecht and Hutley. However, differences in the relative intensity of the benzylidene nitro feature in the 2-methyl and 2-phenyl analogs, taken with the excitation profiles, suggest that in the 2-methyl compound the electronic transition responsible for Raman intensity enhancement is no longer primarily located in the C=C—N=C—Ph moiety.


2009 ◽  
Vol 94 (22) ◽  
pp. 223303 ◽  
Author(s):  
Suman Banerjee ◽  
Anukul Prasad Parhi ◽  
S. Sundar Kumar Iyer ◽  
Satyendra Kumar

1991 ◽  
Vol 59 (25) ◽  
pp. 3273-3275 ◽  
Author(s):  
C. M. Dai ◽  
D. S. Chuu ◽  
W. F. Hsieh

2021 ◽  
Vol 9 ◽  
Author(s):  
Yi-Fei Bao ◽  
Tao Liu ◽  
Wei-Jin Kong ◽  
Hao-Qi Luo ◽  
Yong Liu ◽  
...  

The femtosecond laser writing with double-line technique was employed to fabricate buried channel waveguides with different widths in Yb:YVO4 crystal. Model profiles of the waveguides were captured using the endface coupling setup at the wavelength of 633 nm under TE and TM polarization. Furthermore, the confocal micro-Raman spectra in bulk and waveguide areas were studied at the wavelength of 633 nm. The enhanced Raman intensity were performed in waveguide areas.


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