Ultra-small Mo2N on SBA-15 as a highly efficient promoter of low-loading Pd for catalytic hydrogenation

Nanoscale ◽  
2018 ◽  
Vol 10 (47) ◽  
pp. 22348-22356 ◽  
Author(s):  
Xusheng Cheng ◽  
Dongxu Wang ◽  
Jiancong Liu ◽  
Xin Kang ◽  
Haijing Yan ◽  
...  
Keyword(s):  
Catalytic Hydrogenation ◽  
Hydrogenation Reaction ◽  
Highly Efficient

Ultra-small Mo2N (2–3 nm) was uniformly anchored onto mesoporous SBA-15, which can be used as a highly efficient promoter of low-loading Pd for the hydrogenation reaction.

Catalytic asymmetric hydrogenation reaction by in situ formed ultra-fine metal nanoparticles in live thermophilic hydrogen-producing bacteria

Nanoscale ◽  
2021 ◽  
Author(s):  
Wei Bing ◽  
Faming Wang ◽  
Yuhuan Sun ◽  
Jinsong Ren ◽  
Xiaogang Qu
Keyword(s):  
Metal Nanoparticles ◽  
Catalytic Hydrogenation ◽  
Asymmetric Hydrogenation ◽  
Environmentally Friendly ◽  
Hydrogenation Reaction ◽  
Highly Efficient ◽  
Hydrogenation Reactions ◽  
Live Bacteria ◽  
Catalytic Asymmetric Hydrogenation

An environmentally friendly biomimetic strategy has been presented and validated for the catalytic hydrogenation reaction in live bacteria. In situ formed ultra-fine metal nanoparticles can realize highly efficient asymmetric hydrogenation reactions.

Nanometer Scale Spectroscopic Visualization of Catalytic Sites During a Hydrogenation Reaction on a Pd/Au Bimetallic Catalyst

2020 ◽  
Author(s):  
hao yin ◽  
Liqing Zheng ◽  
Wei Fang ◽  
Yin-Hung Lai ◽  
Nikolaus Porenta ◽  
...  
Keyword(s):  
Catalytic Hydrogenation ◽  
Density Functional ◽  
Hydrogen Transfer ◽  
Bimetallic Catalyst ◽  
Local Environment ◽  
Hydrogenation Reaction ◽  
Boundary Density ◽  
Catalytic Sites ◽  
Powerful Analytical Tool ◽  
Tip Enhanced Raman Spectroscopy

<p>Understanding the mechanism of catalytic hydrogenation at the local environment requires chemical and topographic information involving catalytic sites, active hydrogen species and their spatial distribution. Here, tip-enhanced Raman spectroscopy (TERS) was employed to study the catalytic hydrogenation of chloro-nitrobenzenethiol on a well-defined Pd(sub-monolayer)/Au(111) bimetallic catalyst (<i>p</i><sub>H2</sub>=1.5 bar, 298 K), where the surface topography and chemical fingerprint information were simultaneously mapped with nanoscale resolution (≈10 nm). TERS imaging of the surface after catalytic hydrogenation confirms that the reaction occurs beyond the location of Pd sites. The results demonstrate that hydrogen spillover accelerates hydrogenation at the Au sites within 20 nm from the bimetallic Pd/Au boundary. Density functional theory was used to elucidate the thermodynamics of interfacial hydrogen transfer. We demonstrate that TERS as a powerful analytical tool provides a unique approach to spatially investigate the local structure-reactivity relationship in catalysis.</p>

Nanometer Scale Spectroscopic Visualization of Catalytic Sites During a Hydrogenation Reaction on a Pd/Au Bimetallic Catalyst

2020 ◽  
Author(s):  
Hao Yin ◽  
Liqing Zheng ◽  
Wei Fang ◽  
Yin-Hung Lai ◽  
Nikolaus Porenta ◽  
...  
Keyword(s):  
Catalytic Hydrogenation ◽  
Density Functional ◽  
Hydrogen Transfer ◽  
Bimetallic Catalyst ◽  
Local Environment ◽  
Hydrogenation Reaction ◽  
Boundary Density ◽  
Catalytic Sites ◽  
Powerful Analytical Tool ◽  
Tip Enhanced Raman Spectroscopy

<p>Understanding the mechanism of catalytic hydrogenation at the local environment requires chemical and topographic information involving catalytic sites, active hydrogen species and their spatial distribution. Here, tip-enhanced Raman spectroscopy (TERS) was employed to study the catalytic hydrogenation of chloro-nitrobenzenethiol on a well-defined Pd(sub-monolayer)/Au(111) bimetallic catalyst (<i>p</i><sub>H2</sub>=1.5 bar, 298 K), where the surface topography and chemical fingerprint information were simultaneously mapped with nanoscale resolution (≈10 nm). TERS imaging of the surface after catalytic hydrogenation confirms that the reaction occurs beyond the location of Pd sites. The results demonstrate that hydrogen spillover accelerates hydrogenation at the Au sites within 20 nm from the bimetallic Pd/Au boundary. Density functional theory was used to elucidate the thermodynamics of interfacial hydrogen transfer. We demonstrate that TERS as a powerful analytical tool provides a unique approach to spatially investigate the local structure-reactivity relationship in catalysis.</p>

Highly efficient catalytic hydrogenation of nitrophenols by sewage sludge derived biochar

2021 ◽  
pp. 117360
Author(s):  
Xiaoya Ren ◽  
Lin Tang ◽  
Jiajia Wang ◽  
Eydhah Almatrafi ◽  
Haopeng Feng ◽  
...  
Keyword(s):  
Sewage Sludge ◽  
Catalytic Hydrogenation ◽  
Highly Efficient

Gas-liquid catalytic hydrogenation reaction in small catalyst channel

AIChE Journal ◽  
2005 ◽  
Vol 51 (8) ◽  
pp. 2285-2297 ◽  
Author(s):  
Wei Liu ◽  
Shantanu Roy ◽  
Xiaodong Fu
Keyword(s):  
Catalytic Hydrogenation ◽  
Hydrogenation Reaction

scholarly journals Bimetallic Au–Pd alloy nanoparticles supported on MIL-101(Cr) as highly efficient catalysts for selective hydrogenation of 1,3-butadiene

RSC Advances ◽  
2020 ◽  
Vol 10 (55) ◽  
pp. 33417-33427
Author(s):  
Lili Liu ◽  
Xiaojing Zhou ◽  
Luxia Guo ◽  
Shijuan Yan ◽  
Yingjie Li ◽  
...  
Keyword(s):  
High Activity ◽  
Selective Hydrogenation ◽  
Hydrogenation Reaction ◽  
Alloy Nanoparticles ◽  
Highly Efficient ◽  
Alloy Particles ◽  
Pd Alloy ◽  
Butadiene Hydrogenation

Bimetallic Au–Pd alloy particles stabilized by MIL-101(Cr) showed high activity and butene selectivity for 1,3-butadiene hydrogenation reaction.

Recyclable catalyst for catalytic hydrogenation of phenylacetylene by coupling Pd nanoparticles with highly compressible graphene aerogels

RSC Advances ◽  
2014 ◽  
Vol 4 (104) ◽  
pp. 59977-59980 ◽  
Author(s):  
Xu Zhang ◽  
Zhiyu Wang ◽  
Shuang Li ◽  
Chunlei Wang ◽  
Jieshan Qiu
Keyword(s):  
Graphene Oxide ◽  
Catalytic Hydrogenation ◽  
Chemical Reduction ◽  
Pd Nanoparticles ◽  
Catalytic Performance ◽  
Hydrogenation Reaction ◽  
Recyclable Catalyst ◽  
Graphene Aerogels ◽  
Excellent Catalytic Performance

Highly compressible graphene aerogels were made by chemical reduction of graphene oxide with HI, which act as recyclable catalyst to exhibit excellent catalytic performance towards selective semi-hydrogenation reaction after loading Pd nanoparticles.

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