Facile synthesis of N-doped graphene supported porous cobalt molybdenum oxynitride nanodendrites for the oxygen reduction reaction

Nanoscale ◽  
2019 ◽  
Vol 11 (3) ◽  
pp. 1205-1216 ◽  
Author(s):  
Kamaldeep Sharma ◽  
David Hui ◽  
Nam Hoon Kim ◽  
Joong Hee Lee

Herein, the porous Co–Mo-ON/NG alloy nanodendrites offer comparable ORR activity, superior electrochemical stability, long term durability for 2000 cycles with almost zero degradation and greater resistance to methanol compared to commercial Pt/C catalysts both in acidic and basic media.

ChemCatChem ◽  
2015 ◽  
Vol 8 (1) ◽  
pp. 163-170 ◽  
Author(s):  
Fuping Pan ◽  
Youxin Duan ◽  
Xinkai Zhang ◽  
Junyan Zhang

2016 ◽  
Vol 4 (10) ◽  
pp. 3678-3682 ◽  
Author(s):  
Shuqin Peng ◽  
Hongmei Jiang ◽  
Youming Zhang ◽  
Lu Yang ◽  
Shuqin Wang ◽  
...  

Co and N co-doped graphene networks derived from polyaniline nanofibers can show high oxygen reduction activity in acidic solutions.


2021 ◽  
Author(s):  
Ershuai Liu ◽  
Qingying Jia ◽  
Jun Yang ◽  
Kai Sun ◽  
Li Jiao ◽  
...  

Among various metal nanoparticles supported on metal oxide (MMO) catalysts, the Pt/NbOx/C system has promising oxygen reduction reaction (ORR) activity as cathode for proton exchange membrane fuel cells (PEMFCs). Herein, we study a series of Pt/NbOx/C catalysts with tunable structural and electronic properties via physical vapor deposition and unravel the nature of metal and metal oxide interaction (MMOI) by characterizing this system under reactive conditions. By conducting in situ X-ray absorption spectroscopy (XAS) experiments, we demonstrate the Pt preferably interacts with O but not Nb in the Pt/NbOx/C system and such Pt-O interaction benefits the ORR activity via electronic effect rather than strain effect. We also provide clear evidence for the formation of metallic Nb phase at the early stage of PEMFC operation and identify severe particle growth of Pt after long-term PEMFC operation. These findings deepen our understanding of the degradation mechanism of MMO catalysts during long-term PEMFC operation.


2015 ◽  
Vol 3 (14) ◽  
pp. 7659-7665 ◽  
Author(s):  
Dong Wook Chang ◽  
Hyun-Jung Choi ◽  
Jong-Beom Baek

We developed a facile, versatile method to prepare pyridinic N-rich nitrogen-doped graphene nanoplatelets (PN-GNs), which show unique electrocatalytic activities toward the oxygen reduction reaction with enhanced long-term cycle stability and good tolerance to methanol crossover.


2018 ◽  
Vol 20 (17) ◽  
pp. 11994-12004 ◽  
Author(s):  
Naoto Todoroki ◽  
Ryutaro Kawamura ◽  
Masato Asano ◽  
Ren Sasakawa ◽  
Shuntaro Takahashi ◽  
...  

The oxygen reduction reaction (ORR) activity and electrochemical stability of well-defined n monolayer (ML)-Pt/PtxNi100−x(111) (n = 2 and 4; x = 75, 50, and 25) model electrocatalyst surfaces were investigated in this study.


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