Metalloporphyrin-bound Janus nanocomposites with dual stimuli responsiveness for nanocatalysis in living radical polymerization

Nanoscale ◽  
2018 ◽  
Vol 10 (41) ◽  
pp. 19254-19261 ◽  
Author(s):  
Xue Li ◽  
Jia Le Li ◽  
Wen Gang Huang ◽  
Xian-Zheng Zhang ◽  
Bin Zhang ◽  
...  
Keyword(s):  
Radical Polymerization ◽  
Living Radical Polymerization ◽  
Polymerization Kinetics ◽  
Polymer Composition ◽  
External Stimuli

The capability to spatiotemporally regulate polymerization kinetics in response to dual external stimuli of light and magnetism offers exciting pathways to precisely manipulate polymer composition and sequence.

Influences of the Structural Design of RAFT Agents on Living Radical Polymerization Kinetics

2003 ◽  
pp. 551-569 ◽  
Author(s):  
Thomas P. Davis ◽  
Christopher Barner-Kowollik ◽  
T. L. Uyen Nguyen ◽  
Martina H. Stenzel ◽  
John F. Quinn ◽  
...  
Keyword(s):  
Radical Polymerization ◽  
Structural Design ◽  
Living Radical Polymerization ◽  
Polymerization Kinetics

scholarly journals One-pot synthesis for gradient copolymers via concurrent tandem living radical polymerization: mild and selective transesterification of methyl acrylate through Al(acac)3 with common alcohols

RSC Advances ◽  
2021 ◽  
Vol 11 (42) ◽  
pp. 26049-26055
Author(s):  
Tam Thi-Thanh Huynh ◽  
Si Eun Kim ◽  
Soon Cheon Kim ◽  
Jin Chul Kim ◽  
Young Il Park ◽  
...  
Keyword(s):  
Radical Polymerization ◽  
Methyl Acrylate ◽  
Living Radical Polymerization ◽  
One Pot ◽  
Gradient Copolymers ◽  
One Pot Synthesis

The acrylate based gradient copolymers were successfully synthesized by concurrent tandem living radical polymerization using Al(acac)3 as cocatalyst with common alcohols.

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