Nanoplatelet modulation in 2D/3D perovskite targeting efficient light-emitting diodes

Nanoscale ◽  
2018 ◽  
Vol 10 (41) ◽  
pp. 19322-19329 ◽  
Author(s):  
Tian Wu ◽  
Yingguo Yang ◽  
Yatao Zou ◽  
Yusheng Wang ◽  
Chen Wu ◽  
...  

A perovskite film achieves PLQY of ∼61% by suppressing NMA2PbBr4 growth with incorporation of organic molecules. Consequently, a perovskite LED device yields current efficiency of 46.8 cd A−1 with external quantum efficiency of 14.9%.

2019 ◽  
Vol 48 (5) ◽  
pp. 1892-1899 ◽  
Author(s):  
Guang-Zhao Lu ◽  
Zhen-Long Tu ◽  
Liang Liu ◽  
You-Xuan Zheng ◽  
Yue Zhao

Two efficient green platinum(ii) cyclometalated complexes were applied in organic light-emitting diodes showing good performances with a peak current efficiency of 88.50 cd A−1 and a peak external quantum efficiency of 26.90% with mild efficiency roll-off.


Nanoscale ◽  
2018 ◽  
Vol 10 (23) ◽  
pp. 11103-11109 ◽  
Author(s):  
Wenyu Ji ◽  
Huaibin Shen ◽  
Han Zhang ◽  
Zhihui Kang ◽  
Hanzhuang Zhang

The interactions between QDs and s-NiO can be largely suppressed through introducing a ultrathin Al2O3passivating layer. This highest current efficiency (external quantum efficiency) of 34.1 cd A−1(8.1%) is achieved.


2021 ◽  
Vol 12 (1) ◽  
Author(s):  
Yuwei Guo ◽  
Sofia Apergi ◽  
Nan Li ◽  
Mengyu Chen ◽  
Chunyang Yin ◽  
...  

AbstractPerovskite light emitting diodes suffer from poor operational stability, exhibiting a rapid decay of external quantum efficiency within minutes to hours after turn-on. To address this issue, we explore surface treatment of perovskite films with phenylalkylammonium iodide molecules of varying alkyl chain lengths. Combining experimental characterization and theoretical modelling, we show that these molecules stabilize the perovskite through suppression of iodide ion migration. The stabilization effect is enhanced with increasing chain length due to the stronger binding of the molecules with the perovskite surface, as well as the increased steric hindrance to reconfiguration for accommodating ion migration. The passivation also reduces the surface defects, resulting in a high radiance and delayed roll-off of external quantum efficiency. Using the optimized passivation molecule, phenylpropylammonium iodide, we achieve devices with an efficiency of 17.5%, a radiance of 1282.8 W sr−1 m−2 and a record T50 half-lifetime of 130 h under 100 mA cm−2.


Molecules ◽  
2021 ◽  
Vol 26 (15) ◽  
pp. 4615
Author(s):  
Dovydas Blazevicius ◽  
Daiva Tavgeniene ◽  
Simona Sutkuviene ◽  
Ernestas Zaleckas ◽  
Ming-Ruei Jiang ◽  
...  

Pyridinyl-carbazole fragments containing low molar mass compounds as host derivatives H1 and H2 were synthesized, investigated, and used for the preparation of electro-phosphorescent organic light-emitting devices (PhOLEDs). The materials demonstrated high stability against thermal decomposition with the decomposition temperatures of 361–386 °C and were suitable for the preparation of thin amorphous and homogeneous layers with very high values of glass transition temperatures of 127–139 °C. It was determined that triplet energy values of the derivatives are, correspondingly, 2.82 eV for the derivative H1 and 2.81 eV for the host H2. The new derivatives were tested as hosts of emitting layers in blue, as well as in green phosphorescent OLEDs. The blue device with 15 wt.% of the iridium(III)[bis(4,6-difluorophenyl)-pyridinato-N,C2′]picolinate (FIrpic) emitter doping ratio in host material H2 exhibited the best overall characteristics with a power efficiency of 24.9 lm/W, a current efficiency of 23.9 cd/A, and high value of 10.3% of external quantum efficiency at 100 cd/m2. The most efficient green PhOLED with 10 wt% of Ir(ppy)3 {tris(2-phenylpyridine)iridium(III)} in the H2 host showed a power efficiency of 34.1 lm/W, current efficiency of 33.9 cd/A, and a high value of 9.4% for external quantum efficiency at a high brightness of 1000 cd/m2, which is required for lighting applications. These characteristics were obtained in non-optimized PhOLEDs under an ordinary laboratory atmosphere and could be improved in the optimization process. The results demonstrate that some of the new host materials are very promising components for the development of efficient phosphorescent devices.


2017 ◽  
Vol 5 (23) ◽  
pp. 5749-5756 ◽  
Author(s):  
Lingcheng Chen ◽  
Shumeng Wang ◽  
Zhimin Yan ◽  
Junqiao Ding ◽  
Lixiang Wang

By fully encapsulating the heteroleptic red Ir complex with carbazole dendrons, solution-processed nondoped electrophosphorescent devices reveal over 10% EQE.


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