scholarly journals In situ insight into the unconventional ruthenium catalyzed growth of carbon nanostructures

Nanoscale ◽  
2018 ◽  
Vol 10 (31) ◽  
pp. 14957-14965 ◽  
Author(s):  
M. Bahri ◽  
K. Dembélé ◽  
C. Sassoye ◽  
D. P. Debecker ◽  
S. Moldovan ◽  
...  
Keyword(s):  
Carbon Source ◽  
Carbon Nanostructures ◽  
Growth Process ◽  
Medium Temperature ◽  
Ru Nanoparticles ◽  
Insight Into

We report on the in situ analysis of the growth process of carbon nanostructures catalyzed by Ru nanoparticles using syngas, a mixture of hydrogen and CO, as the carbon source at a medium temperature (500 °C).

scholarly journals Micro-Nano Carbon Structures with Platelet, Glassy and Tube-Like Morphologies

Nanomaterials ◽  
2019 ◽  
Vol 9 (9) ◽  
pp. 1242 ◽  
Author(s):  
Liu ◽  
Huang ◽  
Xiong ◽  
Wang ◽  
Chen ◽  
...  
Keyword(s):  
Carbon Source ◽  
Carbon Nanostructures ◽  
Phenol Formaldehyde ◽  
Phenol Formaldehyde Resin ◽  
Production Costs ◽  
Formaldehyde Resin ◽  
Low Carbon ◽  
Graphite Nanoplatelets ◽  
Carbon Structures

Carbon source precursors for high-grade, clean, and low-carbon refractories were obtained by in situ exfoliation of flake graphite (FG) and phenol–formaldehyde resin (PF) composites with three-roll milling (TRM) for the fabrication of graphite nanoplatelets. In addition, by using Ni(NO3)2·6H2O as a catalyst in the pyrolysis process, multidimensional carbon nanostructures were obtained with coexisting graphite nanoplatelets (GNPs), glassy carbon (GC), and carbon nanotubes (CNTs). The resulting GNPs (exfoliated 16 times) had sizes of 10–30 μm, thicknesses of 30–50 nm, and could be uniformly dispersed in GC from the PF pyrolysis. Moreover, Ni(NO3)2·6H2O played a key role in the formation and growth of CNTs from a catalytic pyrolysis of partial PF with the V–S/tip growth mechanisms. The resulting multidimensional carbon nanostructures with GNPs/GC/CNTs are attributed to the shear force of the TRM process, pyrolysis, and catalytic action of nitrates. This method reduced the production costs of carbon source precursors for low-carbon refractories, and the precursors exhibited excellent performances when fabricated on large scales.

Real-Time Spectroscopic Ellipsometry Studies of Zinc Oxide Deposition

2008 ◽  
Vol 1074 ◽  
Author(s):  
Christian Carl Fesenmaier ◽  
Xiaonan S. Li ◽  
Bobby To ◽  
Dean H. Levi
Keyword(s):  
Zinc Oxide ◽  
Real Time ◽  
Spectroscopic Ellipsometry ◽  
Indium Tin Oxide ◽  
Growth Process ◽  
Growth Zone ◽  
Constant Thickness ◽  
Zno Films ◽  
Insight Into

ABSTRACTZinc oxide is increasingly being studied as an eventual replacement for indium tin oxide as a transparent conducting oxide (TCO) for thin film solar cells. In order to better understand the growth process of ZnO, as well as provide for accurate control on the National Renewable Energy Laboratory's TCO deposition system, undoped RF-magnetron sputtered ZnO films on silicon were analyzed in situ using real-time spectroscopic ellipsometry (RTSE). A large wavelength range (245-994 nm) was measured in order to derive information about optical properties both below and above the bandgap. Atomic force microscopy (AFM) measurements were also taken to confirm ellipsometry surface roughness results and provide additional insight into the surface morphology.In light of observed poor fit of typical two-layer optical models to in situ ellipsometry data, we propose a model film structure consisting of two layers: a bulk ZnO layer of graded density that increases in thickness as the growth proceeds and a growth zone at the top of the film of approximately constant thickness with a slightly larger bandgap, lower density, and decreased excitonic absorption. Unfortunately, this model is insufficient to explain the evolution of the film during the early growth period, corresponding to film thicknesses less than 100 nm. Nevertheless, the presence of a growth zone for films above a certain thickness should provide some insight into the growth process of RF-magnetron sputtered ZnO.

scholarly journals Development of Fragility Curves for Piping and Slope Stability of River Levees

Water ◽  
2021 ◽  
Vol 13 (5) ◽  
pp. 738
Author(s):  
Nicola Rossi ◽  
Mario Bačić ◽  
Meho Saša Kovačević ◽  
Lovorka Librić
Keyword(s):  
Slope Stability ◽  
Fragility Curves ◽  
Safety Margin ◽  
Water Levels ◽  
Flood Event ◽  
Soil Parameters ◽  
Design Code ◽  
A Site ◽  
Insight Into

The design code Eurocode 7 relies on semi-probabilistic calculation procedures, through utilization of the soil parameters obtained by in situ and laboratory tests, or by the means of transformation models. To reach a prescribed safety margin, the inherent soil parameter variability is accounted for through the application of partial factors to either soil parameters directly or to the resistance. However, considering several sources of geotechnical uncertainty, including the inherent soil variability, measurement error and transformation uncertainty, full probabilistic analyses should be implemented to directly consider the site-specific variability. This paper presents the procedure of developing fragility curves for levee slope stability and piping as failure mechanisms that lead to larger breaches, where a direct influence of the flood event intensity on the probability of failure is calculated. A range of fragility curve sets is presented, considering the variability of levee material properties and varying durations of the flood event, thus providing crucial insight into the vulnerability of the levee exposed to rising water levels. The procedure is applied to the River Drava levee, a site which has shown a continuous trend of increased water levels in recent years.

Insight into the enhanced photocatalytic properties of AgBr/Ag4P2O7 composites synthesized via in situ ion exchange reaction

2021 ◽  
Vol 9 (1) ◽  
pp. 104889
Author(s):  
Wyllamanney da S. Pereira ◽  
Fabrício B. Destro ◽  
Cipriano B. Gozzo ◽  
Edson R. Leite ◽  
Júlio C. Sczancoski
Keyword(s):  
Ion Exchange ◽  
Exchange Reaction ◽  
Photocatalytic Properties ◽  
Ion Exchange Reaction ◽  
Insight Into

scholarly journals In situ synthesis of methane using Ag–GDC composite electrodes in a tubular solid oxide electrolytic cell: new insight into the role of oxide ion removal

2021 ◽  
Vol 5 (7) ◽  
pp. 2055-2064
Author(s):  
Saheli Biswas ◽  
Aniruddha P. Kulkarni ◽  
Daniel Fini ◽  
Sarbjit Giddey ◽  
Sankar Bhattacharya
Keyword(s):  
Electrolytic Cell ◽  
Composite Electrodes ◽  
Ion Removal ◽  
Single Temperature ◽  
Methanation Catalyst ◽  
Oxide Ion ◽  
Insight Into ◽  
Electrochemical Phenomenon

In situ synthesis of methane in a single-temperature zone SOEC in the absence of any methanation catalyst is a completely electrochemical phenomenon governed by the thermodynamic equilibrium of various reactions.

In situ loading of well-dispersed silver nanoparticles on nanocrystalline magnesium oxide for real-time monitoring of catalytic reactions by surface enhanced Raman spectroscopy

Nanoscale ◽  
2015 ◽  
Vol 7 (40) ◽  
pp. 16952-16959 ◽  
Author(s):  
Kaige Zhang ◽  
Gongke Li ◽  
Yuling Hu
Keyword(s):  
Raman Spectroscopy ◽  
Surface Enhanced Raman Spectroscopy ◽  
Catalytic Reactions ◽  
Reaction Intermediates ◽  
Reaction Conditions ◽  
Surface Enhanced ◽  
Surface Enhanced Raman ◽  
Nanocrystalline Magnesium Oxide ◽  
Insight Into

The surface-enhanced Raman spectroscopy (SERS) technique is of great importance for insight into the transient reaction intermediates and mechanistic pathways involved in heterogeneously catalyzed chemical reactions under actual reaction conditions, especially in water.

In situ electrochemical microcantilever bending test: A new insight into hydrogen enhanced cracking

2017 ◽  
Vol 132 ◽  
pp. 17-21 ◽  
Author(s):  
Tarlan Hajilou ◽  
Yun Deng ◽  
Bjørn Rune Rogne ◽  
Nousha Kheradmand ◽  
Afrooz Barnoush
Keyword(s):  
Bending Test ◽  
Insight Into

Multi-component in situ and in-step formation of visible-light response C-dots composite TiO2 mesocrystals

RSC Advances ◽  
2016 ◽  
Vol 6 (17) ◽  
pp. 14306-14313 ◽  
Author(s):  
Dong Yan ◽  
Yun Liu ◽  
Chun-yan Liu ◽  
Zhi-ying Zhang ◽  
Shi-dong Nie
Keyword(s):  
Carbon Source ◽  
Visible Light ◽  
Light Response ◽  
Visible Light Response

Successful in situ and in-step formation of C-dots composited TiO2 mesocrystals is closely related to the complexation between carbon source and Ti ion.

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