scholarly journals Effects of pore surfaces on the electronic states of metal complexes formed on bipyridine periodic mesoporous organosilica

2019 ◽  
Vol 43 (6) ◽  
pp. 2471-2478 ◽  
Author(s):  
Soichi Shirai ◽  
Minoru Waki ◽  
Yoshifumi Maegawa ◽  
Yuri Yamada ◽  
Shinji Inagaki
Keyword(s):  
Metal Complexes ◽  
Electronic Properties ◽  
Theoretical Study ◽  
Electronic States ◽  
Surface Structures ◽  
Pore Surface ◽  
Periodic Mesoporous Organosilica ◽  
Mesoporous Organosilica

A combined experimental–theoretical study clarifies correlations between the pore-surface structures and the electronic properties of metal complexes on BPy-PMO.

Periodic Mesoporous Organosilica Derivatives Bearing a High Density of Metal Complexes on Pore Surfaces

2011 ◽  
Vol 123 (49) ◽  
pp. 11871-11875 ◽  
Author(s):  
Minoru Waki ◽  
Norihiro Mizoshita ◽  
Takao Tani ◽  
Shinji Inagaki
Keyword(s):  
Metal Complexes ◽  
High Density ◽  
Periodic Mesoporous Organosilica ◽  
Mesoporous Organosilica

Fine-Tuning Electronic Properties of Luminescent Pt(II) Complexes via Vertex-Differentiated Coordination of Sterically Invariant Carborane-Based Ligands

2018 ◽  
Author(s):  
Kent O. Kirlikovali ◽  
Jonathan C. Axtell ◽  
Kierstyn Anderson ◽  
Peter I. Djurovich ◽  
Arnold L. Rheingold ◽  
...  
Keyword(s):  
Coordination Chemistry ◽  
Metal Complexes ◽  
Electronic Properties ◽  
Fine Tuning ◽  
Fine Tune

We report the synthesis of two isomeric Pt(II) complexes ligated by doubly deprotonated 1,1′-bis(<i>o</i>-carborane) (<b>bc</b>). This work provides a potential route to fine-tune the electronic properties of luminescent metal complexes by virtue of vertex-differentiated coordination chemistry of carborane-based ligands.

Light-harvesting photocatalysis for H2 evolution by methylacridone-bridged periodic mesoporous organosilica

2021 ◽  
Vol 287 ◽  
pp. 119965
Author(s):  
Yasutomo Goto ◽  
Ken-ichi Yamanaka ◽  
Masataka Ohashi ◽  
Yoshifumi Maegawa ◽  
Shinji Inagaki
Keyword(s):  
Light Harvesting ◽  
H2 Evolution ◽  
Periodic Mesoporous Organosilica ◽  
Mesoporous Organosilica

Synthesis and Electronic Properties of Transition Metal Complexes Containing Sulfonamidoquinoline Ligands

Polyhedron ◽  
2021 ◽  
pp. 115269
Author(s):  
Matthew T. Gole ◽  
Patrick Pauls ◽  
Sage F. Hartlaub ◽  
Chip Nataro ◽  
Lauren M. Rossiter ◽  
...  
Keyword(s):  
Transition Metal ◽  
Metal Complexes ◽  
Electronic Properties ◽  
Transition Metal Complexes

Structural, vibrational and electronic properties of α′-Ga2S3 under compression

2021 ◽  
Author(s):  
S. Gallego-Parra ◽  
R. Vilaplana ◽  
O. Gomis ◽  
E. Lora da Silva ◽  
A. Otero-de-la-Roza ◽  
...  
Keyword(s):  
Electronic Properties ◽  
Theoretical Study ◽  
Low Pressure ◽  
Electron Pairs ◽  
System P ◽  
Pressure Phase

We report a joint experimental and theoretical study of the low-pressure phase of α′-Ga2S3 under compression. The structural, vibrational, topological and electronic properties have been evaluated to reveal the relevance of the vacancy channels and the single and double lone electron pairs in the pressure behaviour of this system.

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