Electrocatalytic water oxidation studies of a tetranuclear Cu(ii) complex with cubane-like core Cu4(μ3-O)4

2019 ◽  
Vol 43 (11) ◽  
pp. 4640-4647 ◽  
Author(s):  
Wei-Song Gao ◽  
Jin-Miao Wang ◽  
Ning-Ning Shi ◽  
Chang-Neng Chen ◽  
Yu-Hua Fan ◽  
...  
Keyword(s):  
Water Oxidation ◽  
Tetranuclear Cluster ◽  
Alkaline Conditions

A bio-inspired cubane-like tetranuclear cluster [Cu4(pdmH)4(OAc)2](NO3)2·3H2O can electrocatalyze water oxidation under aqueous alkaline conditions through a PCET process.

Surprisingly Low Reactivity of Layered Manganese Oxide toward Water Oxidation in Fe/Ni-Free Electrolyte under Alkaline Conditions

2022 ◽  
Author(s):  
Mahya Salmanion ◽  
Ivan Kondov ◽  
Matthias Vandichel ◽  
Pavlo Aleshkevych ◽  
Mohammad Mahdi Najafpour
Keyword(s):  
Manganese Oxide ◽  
Water Oxidation ◽  
Alkaline Conditions ◽  
Layered Manganese Oxide

CaMoO4 nanosheet arrays for efficient and durable water oxidation electrocatalysis under alkaline conditions

2018 ◽  
Vol 54 (40) ◽  
pp. 5066-5069 ◽  
Author(s):  
Ying Gou ◽  
Qin Liu ◽  
Xifeng Shi ◽  
Abdullah M. Asiri ◽  
Jianming Hu ◽  
...  
Keyword(s):  
Water Oxidation ◽  
Nickel Foam ◽  
Alkaline Water ◽  
Nanosheet Arrays ◽  
Alkaline Conditions ◽  
Catalyst Electrode

CaMoO4 nanosheet arrays grown in situ on nickel foam (CaMoO4/NF) act as a superior 3D catalyst electrode for alkaline water oxidation with high long-term durability.

Recovered spinel MnCo2O4 from spent lithium-ion batteries for enhanced electrocatalytic oxygen evolution in alkaline medium

2017 ◽  
Vol 46 (41) ◽  
pp. 14382-14392 ◽  
Author(s):  
Subramanian Natarajan ◽  
S. Anantharaj ◽  
Rajesh J. Tayade ◽  
Hari C. Bajaj ◽  
Subrata Kundu
Keyword(s):  
Lithium Ion Batteries ◽  
Oxygen Evolution ◽  
Alkaline Medium ◽  
Water Oxidation ◽  
Lithium Ion ◽  
Chemical Treatments ◽  
Alkaline Conditions ◽  
Physical And Chemical ◽  
Spent Libs

The recovery of spinel MnCo2O4 from spent LIBs was achieved by a set of physical and chemical treatments, their employment for water oxidation in alkaline conditions was studied, and it was found that the recovered spinel MnCo2O4 were more effective than recovered monometallic oxides.

Dicopper(ii) tetrapyridyl complexes incorporated with ancillary ligands for effective water oxidation

2020 ◽  
Vol 44 (28) ◽  
pp. 12194-12200 ◽  
Author(s):  
Wen-Hui Pi ◽  
Qi-Jun Li ◽  
Min Wu ◽  
Xiao-Lin Zhou ◽  
Jia-Ni Wei ◽  
...  
Keyword(s):  
Water Oxidation ◽  
Oxidation Catalysis ◽  
Ancillary Ligands ◽  
Water Oxidation Catalysis ◽  
Alkaline Conditions ◽  
Diamine Ligands ◽  
Effective Water

Water oxidation catalysis of dicopper(ii) tetrapyridyl complexes under alkaline conditions was improved by diamine ligands.

Remarkable enhancement of the alkaline oxygen evolution reaction activity of NiCo2O4 by an amorphous borate shell

2017 ◽  
Vol 4 (9) ◽  
pp. 1546-1550 ◽  
Author(s):  
Xuqiang Ji ◽  
Xiang Ren ◽  
Shuai Hao ◽  
Fengyu Xie ◽  
Fengli Qu ◽  
...  
Keyword(s):  
Oxygen Evolution ◽  
Oxygen Evolution Reaction ◽  
Water Oxidation ◽  
Oxidation Activity ◽  
Alkaline Conditions

Surface introduction of an amorphous borate shell on NiCo2O4 greatly boosts its electrochemical water oxidation activity under alkaline conditions. To achieve 10 mA cm−2 in 1.0 M KOH, NiCo2O4@Ni–Co–B/CC needs an overpotential of only 270 mV.

scholarly journals Ultra-small and highly dispersive iron oxide hydroxide as an efficient catalyst for oxidation reactions: a Swiss-army-knife catalyst

2021 ◽  
Vol 11 (1) ◽  
Author(s):  
Mojtaba Amini ◽  
Younes Mousazade ◽  
Zahra Zand ◽  
Mojtaba Bagherzadeh ◽  
Mohammad Mahdi Najafpour
Keyword(s):  
Iron Oxide ◽  
Water Oxidation ◽  
Sulfide Oxidation ◽  
Oxidation Reactions ◽  
Efficient Catalyst ◽  
Oxide Hydroxide ◽  
Alkaline Conditions ◽  
Epoxidation Of Alkenes ◽  
A Current ◽  
Electrochemical Oxygen

AbstractUltra-small and highly dispersive (< 10 nm) iron oxide hydroxide is characterized by some methods. The compound is an efficient and stable catalyst for alcohol oxidation, organic sulfide oxidation, and epoxidation of alkenes in the presence of H2O2. The electrochemical oxygen-evolution reaction of the iron oxide hydroxide is also tested under acidic, neutral, and alkaline conditions. In the presence of the iron oxide hydroxide, excellent conversions (75–100%) and selectivities of substrates (92–97%), depending on the nature of the sulfide, were obtained. Benzylalcohols having electron-donating and-withdrawing substituents in the aromatic ring were oxidized to produce the corresponding aldehydes with excellent conversion (65–89%) and selectivity (96–100%) using this iron oxide hydroxide. The conversion of styrene and cyclooctene toward the epoxidation in the presence of this catalyst are 60 and 53%, respectively. Water oxidation for the catalysts was investigated at pH 2, 6.7, 12, and 14. The onset of OER at pH 14 is observed with a 475 mV overpotential. At 585 mV overpotential, a current density of more than 0.18 mA/cm2 and a turnover frequency of 1.5/h is observed. Operando high-resolution visible spectroscopy at pH 14, similar to previously reported investigations, shows that Fe(IV)=O is an intermediate for water oxidation.

scholarly journals Nanosized (Ni1−xZnx)Fe2O4 for water oxidation

2019 ◽  
Vol 1 (2) ◽  
pp. 686-695 ◽  
Author(s):  
Somayeh Mehrabani ◽  
Jitendra Pal Singh ◽  
Robabeh Bagheri ◽  
Abdul Ghafar Wattoo ◽  
Zhenlun Song ◽  
...  
Keyword(s):  
Water Oxidation ◽  
Good Catalyst ◽  
Alkaline Conditions

Nanosized (Ni1−xZnx)Fe2O4 is a good catalyst for water oxidation under alkaline conditions.

scholarly journals Electrocatalytic water oxidation at amorphous trimetallic oxides based on FeCoNiOx

RSC Advances ◽  
2017 ◽  
Vol 7 (68) ◽  
pp. 43083-43089 ◽  
Author(s):  
Md Abu Sayeed ◽  
Anthony P. O'Mullane
Keyword(s):  
Oxygen Evolution ◽  
Oxygen Evolution Reaction ◽  
Water Oxidation ◽  
Alkaline Conditions

The rapid electrochemical formation of amorphous FeCoNiOxis reported which is both active and stable for the oxygen evolution reaction under alkaline conditions.

Controlled phosphating: a novel strategy toward NiP3@CeO2 interface engineering for efficient oxygen evolution electrocatalysis

2020 ◽  
Vol 49 (36) ◽  
pp. 12581-12585
Author(s):  
Guangyu Ma ◽  
Xiaoqiang Du ◽  
Xiaoshuang Zhang
Keyword(s):  
Oxygen Evolution ◽  
Water Oxidation ◽  
Interface Engineering ◽  
Oxidation Activity ◽  
Alkaline Conditions ◽  
Novel Strategy

NiP3@CeO2 catalysts exhibit excellent water oxidation activity (an overpotential of 200 mV@ 25 mA cm−2) under alkaline conditions.

Sign in / Sign up

Export Citation Format

Share Document