Selective electrochemical detection of bisphenol A using a molecularly imprinted polymer nanocomposite

2019 ◽  
Vol 43 (3) ◽  
pp. 1536-1543 ◽  
Author(s):  
Haydar Ali ◽  
Soumita Mukhopadhyay ◽  
Nikhil R. Jana
Keyword(s):  
Bisphenol A ◽  
Electrochemical Detection ◽  
Molecularly Imprinted Polymer ◽  
Polymer Nanocomposite ◽  
Imprinted Polymer ◽  
Molecularly Imprinted

A molecularly imprinted nanocomposite with covalently connected polyacrylate, β-cyclodextrin and graphene is synthesized for selective capture and electrochemical detection of bisphenol A.

scholarly journals The Establishment of Bisphenol A Sensing System Utilizing Molecularly Imprinted Polymer Receptor and Electrochemical Determination

2011 ◽  
Vol 2011 ◽  
pp. 1-4 ◽  
Author(s):  
Izumi Kubo ◽  
Nobuyuki Yokota ◽  
Yuko Nakane ◽  
Yusuke Fuchiwaki
Keyword(s):  
Aqueous Solution ◽  
Bisphenol A ◽  
Electrochemical Detection ◽  
Molecularly Imprinted Polymer ◽  
Phosphate Buffer ◽  
Packed Column ◽  
Imprinted Polymer ◽  
Molecularly Imprinted ◽  
Sensing System ◽  
Anodic Peak Current

A sensing system of bisphenol A (BPA) based on the electrochemical detection utilizing molecularly imprinted polymer (MIP) as a receptor of BPA was investigated. MIP for BPA was polymerized thermally from 4-vinylpyridine as a functional monomer and ethylene dimethacrylate (EDMA) as a cross-linker and served to prepare an MIP packed column. BPA in an aqueous solution was adsorbed to an MIP packed column and eluted by acetonitrile/phosphate buffer (60/40, v/v). From aqueous solution, BPA was adsorbed to the column and eluted completely in the eluent. The eluted BPA was electrochemically detected by cyclic voltammetry. Optimum pH and scan rate were 7.0 and 0.1 V/s in phosphate buffer. Electrochemical detection of BPA in acetonitrile/phosphate buffer was performed, and linear relationship between BPA and anodic peak current was observed at the range of 10–100 μM. In the eluent, anodic peak current of BPA was observed around 650 mV.

scholarly journals Removal of bisphenol A from aqueous media using a highly selective adsorbent of hybridization cyclodextrin with magnetic molecularly imprinted polymer

2021 ◽  
Vol 8 (3) ◽  
Author(s):  
S. Mamman ◽  
F. B. M. Suah ◽  
M. Raaov ◽  
F. S. Mehamod ◽  
S. Asman ◽  
...  
Keyword(s):  
Bisphenol A ◽  
Molecularly Imprinted Polymer ◽  
Binding Capacity ◽  
Bulk Polymerization ◽  
Resonance Spectroscopy ◽  
Template Molecule ◽  
Order Kinetic ◽  
Imprinted Polymer ◽  
Molecularly Imprinted ◽  
Magnetic Molecularly Imprinted Polymer

In this study, a unique magnetic molecularly imprinted polymer (MMIP) adsorbent towards bisphenol A (BPA) as a template molecule was developed by bulk polymerization using β-cyclodextrin (β-CD) as a co-monomer with methacrylic acid (MAA) to form MMIP MAA–βCD as a new adsorbent. β-CD was hybridized with MAA to obtain water-compactible imprinting sites for the effective removal of BPA from aqueous samples. Benzoyl peroxide and trimethylolpropane trimethacrylate were used as the initiator and cross-linker, respectively. The adsorbents were characterized by Fourier transform infrared spectroscopy, scanning electronic microscopy, transmission electron microscopy, vibrating sample magnetometer, Brunauer–Emmett–Teller and X-ray diffraction. 1 H nuclear magnetic resonance spectroscopy was used to characterize the MAA–βCD and BPA–MAA–βCD complex. Several parameters influencing the adsorption efficiency of BPA such as adsorbent dosage, pH of sample solution, contact time, initial concentrations and temperature as well as selectivity and reusability study have been evaluated. MMIP MAA–βCD showed significantly higher removal efficiency and selective binding capacity towards BPA compared to MMIP MAA owing to its unique morphology with the presence of β-CD. The kinetics data can be well described by the pseudo second-order kinetic and Freundlich isotherm and Halsey models best fitted the isotherm data. The thermodynamic studies indicated that the adsorption reaction was a spontaneous and exothermic process. Therefore, MMIP based on the hybrid monomer of MAA–βCD shows good potential of a new monomer in molecularly imprinted polymer preparation and can be used as an effective adsorbent for the removal of BPA from aqueous solutions.

Sign in / Sign up

Export Citation Format

Share Document