4-Hydroxybenzaldehyde derived Schiff base gelators: case of the sustainability or rupturing of imine bonds towards the selective sensing of Ag+and Hg2+ionsviasol–gel methodology

2019 ◽  
Vol 43 (13) ◽  
pp. 5139-5149 ◽  
Author(s):  
Atanu Panja ◽  
Kumaresh Ghosh
Keyword(s):  
Schiff Base ◽  
Metal Ions ◽  
Schiff Bases ◽  
Sol Gel ◽  
Eye Detection ◽  
Naked Eye ◽  
Naked Eye Detection

The cholesterol appended hydroxybenzaldehyde derived Schiff bases1–4have been designed and synthesized. They are suitable for the naked-eye detection of metal ions such as Hg2+and Ag+using sol–gel methodology involving either rupturing or maintaining the imine bonds.

Cholesterol decorated pyridinium urea and carbamate as π-gelators for selective recognition of F- ions

2021 ◽  
Vol 05 ◽  
Author(s):  
Santanu Panja ◽  
Kumaresh Ghosh
Keyword(s):  
Sol Gel ◽  
Functional Materials ◽  
Materials Chemistry ◽  
Eye Detection ◽  
Fluoride Ions ◽  
Biologically Relevant ◽  
Design And Synthesis ◽  
Naked Eye ◽  
Visual Sensing ◽  
Naked Eye Detection

Aim: Design and synthesis of new molecules capable of forming self-assembled gels are indispensable to harvest new functional materials. Supramolecular gels have potential in many areas particularly in biology and materials chemistry. Of the different types of applications, visual sensing of biologically relevant ionic analytes is a fairly recent trend. Here we describe naked eye detection of fluoride ions involving sol-gel methodology. Methods: To execute this, cholesterol substituted pyridinium salts 1-4 have been designed and synthesized of which compounds 3 and 4 served as potential gelators for the naked eye detection of F- ions in DMSO and DMSO-H2O (1:1, v/v) respectively. Results: Gelation study reveals that not only the aromatic surface is crucial for the self-aggregation of molecules via π-π stacking interactions, but also polarity, rigidity and conformational flexibility of the molecules that govern the intermolecular association of gelators are important. Conclusion: Moreover, incorporation of fluorophores (naphthalene) as aromatic surface in the molecular designs, promotes the gelator molecules to execute sensing behavior for F- with high degree of sensitivity in solution phase also.

scholarly journals A rhodamine-based dual chemosensor for the naked-eye detection of Hg2+ and enhancement of the fluorescence emission for Fe3+

2020 ◽  
Vol 19 (12) ◽  
pp. 1690-1696
Author(s):  
Jian-Peng Hu ◽  
Hao-Hang Yang ◽  
Qi Lin ◽  
Hong Yao ◽  
You-Ming Zhang ◽  
...  
Keyword(s):  
Metal Ions ◽  
Fluorescence Emission ◽  
Eye Detection ◽  
Naked Eye ◽  
Rhodamine Derivative ◽  
Turn On ◽  
Trimesoyl Chloride ◽  
Naked Eye Detection

Herein, we synthesized a trimesoyl chloride–rhodamine derivative TR. TR exhibited metal ions complexation induced photophysical ‘turn-on’ signaling responses to Hg2+ and Fe3+.

Naked-eye detection of F− and AcO− ions by Schiff base receptor

2011 ◽  
Vol 132 (8) ◽  
pp. 536-540 ◽  
Author(s):  
Sasanka Dalapati ◽  
Md. Akhtarul Alam ◽  
Sankar Jana ◽  
Nikhil Guchhait
Keyword(s):  
Schiff Base ◽  
Eye Detection ◽  
Naked Eye ◽  
Naked Eye Detection
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