Waste-to-useful: a biowaste-derived heterogeneous catalyst for a green and sustainable Henry reaction

2019 ◽  
Vol 43 (5) ◽  
pp. 2134-2140 ◽  
Author(s):  
Kalyani Rajkumari ◽  
Diparjun Das ◽  
Gunindra Pathak ◽  
Lalthazuala Rokhum
Keyword(s):  
Heterogeneous Catalyst ◽  
Value Added ◽  
Waste Biomass ◽  
Waste Generation ◽  
Henry Reaction

Owing to the depletion of resources coupled with increasing waste generation, the conversion of waste biomass to value-added materials has gained interest.

scholarly journals Waste Animal Bones as Catalysts for Biodiesel Production; A Mini Review

Catalysts ◽  
2021 ◽  
Vol 11 (5) ◽  
pp. 630
Author(s):  
Fayaz Hussain ◽  
Saad Alshahrani ◽  
Muhammad Mujtaba Abbas ◽  
Haris Mahmood Khan ◽  
Asif Jamil ◽  
...  
Keyword(s):  
Catalytic Activity ◽  
Heterogeneous Catalyst ◽  
Recent Literature ◽  
Catalyst Preparation ◽  
Biodiesel Production ◽  
Waste Generation ◽  
Preparation Methods ◽  
Eu Legislation ◽  
Animal Bones ◽  
Disposal Cost

Slaughterhouse waste is considered to be an emerging issue because of its disposal cost. As an alternative, it would be a great prospect for the bioeconomy society to explore new usages of these leftover materials. As per food safety rules mentioned by EU legislation, all bone waste generated by slaughterhouses ought to be disposed of by rendering. The huge quantity of worldwide bone waste generation (130 billion kilograms per annum) is an environmental burden if not properly managed. The waste animal bones can be efficiently employed as a heterogeneous catalyst to produce biodiesel. This mini review summarized the recent literature reported for biodiesel generation using waste animal bones derived heterogeneous catalyst. It discusses the sources of bone waste, catalyst preparation methods, particularly calcination and its effects, and important characteristics of bones derived catalyst. It suggests that catalysts extracted from waste animal bones have suitable catalytic activity in transesterification of different oil sources to generate a good quality biodiesel.

scholarly journals BIOBASED ECONOMY AVAILABLE BIOMASS RESOURCES IN THE CZECH REPUBLIC

2006 ◽  
Vol 7 (3) ◽  
pp. 155-162
Author(s):  
Zdenek Wegscheider ◽  
Mojmir Sabolovic
Keyword(s):  
Human Population ◽  
Crop Production ◽  
Building Materials ◽  
Agricultural Sector ◽  
Value Added ◽  
The United States ◽  
Scale Production ◽  
Waste Biomass ◽  
Biobased Materials ◽  
Biobased Economy

During the past two decades academia, industry and government have aimed more and more their attention to the phenomenon of a biobased economy providing society with non‐food biobased products. Now developing are biomass industries that make an array of commercial products, including fuels, electricity, chemicals, adhesives, lubricants and building materials, as well as new clothing fibers and plastics. Instead of fossil resources “green” biobased economy uses renewable grown or waste biomass. The lead supplying role to the biobased economy is held by a sector of agriculture, above all the crop production. In this manner an effective limitation of food surplus may occur in the EU market and enhance a value added to all vertical industry. Industrial‐scale production of biobased materials in time with consumers’ changing attitudes towards sustainable economic and social development may affect a wide array of consequences which nowadays can be tediously estimated. Food safety along with food security is one of the hottest issues especially in the United States, knowing that human population and biobased economy compete in using and processing a broad range of agricultural crops. An energy analysis aspect of this caloric relationship among agricultural sector on the supply side and human population and biobased economy on the other – demand side is assumed to represent the principal aim of this study. Consequently, there is the need to evaluate whether a quantity of Czech Crop Output Total is possible to nourish the Czech population and whether there is an available caloric surplus suitable as a biomass resource for biobased economy which is actually taking root.

scholarly journals Agroindustry Residues as a Source for Cellulose Nanofibers Production

2021 ◽  
Author(s):  
Mayra Mariño ◽  
Daniela Cypriano ◽  
Ljubica Tasic
Keyword(s):  
Crop Residues ◽  
Alkali Treatment ◽  
Cellulose Nanofibers ◽  
Value Added ◽  
Raw Material ◽  
Sodium Chlorite ◽  
Waste Biomass ◽  
Sugarcane Straw ◽  
Coffee Residues ◽  
Crop Waste

Our study was motivated by the large amount of crop residues produced in Brazil, which represent underutilized waste biomass and a serious threat to the environment because of the landfilling. For example, even though the corn crop is not popular in Brazil, it is produced in the area of around 18-20 million hectares with an average production of 5-6 t ha-1. That is the reason to seek for the crop residues value-added applications as proposed in the present study. Four Brazilian crop waste biomass: orange bagasse, corn husks, sugarcane straw and coffee residues were used for cellulose nanofibers (CNF) production. CNFs were prepared using alkali treatment, followed by bleaching with sodium chlorite and extraction with oxalic acid. All steps were applied under moderate conditions of temperature and pressure, such as temperature of 120 °C and below, water solutions with chemicals’ concentrations lower that 10% and short sonication pulses. CNFs with diameters in the range 50-70 nm were obtained and products from orange bagasse and corn husks presented high crystallinity indexes (CI), 0.72 and 0.75, respectively. The highest CNF yield was obtained from corn husks (38.5%) followed by sugarcane straw (24.0% with CI of 0.69). CNFs obtained from coffee residues showed a CI value of 0.65 after two bleaching steps. Different CNF morphologies were obtained according to the raw material. The four-crop waste biomass can be considered as excellent starting materials for CNF production in the four-steps process that adds new value to agro-industrial waste and might bring great economical valorization to Brazilian crops production.

scholarly journals Synthesis and characterization of rice husk biochar via hydrothermal carbonization for wastewater treatment and biofuel production

2020 ◽  
Vol 10 (1) ◽  
Author(s):  
Nazia Hossain ◽  
Sabzoi Nizamuddin ◽  
Gregory Griffin ◽  
Periasamy Selvakannan ◽  
Nabisab Mujawar Mubarak ◽  
...  
Keyword(s):  
Rice Husk ◽  
Agricultural Waste ◽  
Value Added ◽  
Hydrothermal Carbonization ◽  
Catalytic Performance ◽  
Biofuel Production ◽  
Suspension Stability ◽  
Waste Biomass ◽  
Suitable Material ◽  
Rice Husk Biochar

Abstract The recent implication of circular economy in Australia spurred the demand for waste material utilization for value-added product generations on a commercial scale. Therefore, this experimental study emphasized on agricultural waste biomass, rice husk (RH) as potential feedstock to produce valuable products. Rice husk biochar (RB) was obtained at temperature: 180 °C, pressure: 70 bar, reaction time: 20 min with water via hydrothermal carbonization (HTC), and the obtained biochar yield was 57.9%. Enhancement of zeta potential value from − 30.1 to − 10.6 mV in RB presented the higher suspension stability, and improvement of surface area and porosity in RB demonstrated the wastewater adsorption capacity. Along with that, an increase of crystallinity in RB, 60.5%, also indicates the enhancement of the catalytic performance of the material significantly more favorable to improve the adsorption efficiency of transitional compounds. In contrast, an increase of the atomic O/C ratio in RB, 0.51 delineated high breakdown of the cellulosic component, which is favorable for biofuel purpose. 13.98% SiO2 reduction in RB confirmed ash content minimization and better quality of fuel properties. Therefore, the rice husk biochar through HTC can be considered a suitable material for further application to treat wastewater and generate bioenergy.

Waste Biomass Utilization for Value-added Green Products

2019 ◽  
Vol 23 (14) ◽  
pp. 1497-1498 ◽  
Author(s):  
Umer Rashid ◽  
Abdul-Sattar Nizami ◽  
Mohammad Rehan
Keyword(s):  
Value Added ◽  
Waste Biomass ◽  
Green Products ◽  
Biomass Utilization

Valorization of underutilized waste biomass from invasive species to produce biochar for energy and other value-added applications

2020 ◽  
Vol 186 ◽  
pp. 109596 ◽  
Author(s):  
Ashfaq Ahmed ◽  
Muhammad S. Abu Bakar ◽  
Rasyidah Hamdani ◽  
Young-Kwon Park ◽  
Su Shiung Lam ◽  
...  
Keyword(s):  
Invasive Species ◽  
Value Added ◽  
Waste Biomass

Nitroaldol (Henry) reaction catalyzed by amberlyst A-21 as a far superior heterogeneous catalyst.

Tetrahedron ◽  
1996 ◽  
Vol 52 (5) ◽  
pp. 1677-1684 ◽  
Author(s):  
Roberto Ballini ◽  
Giovanna Bosica ◽  
Paola Forconi
Keyword(s):  
Heterogeneous Catalyst ◽  
Henry Reaction

scholarly journals Successive Saccharification of Waste Paper as a Resource for Bio-product Development

2021 ◽  
Vol 20 (3) ◽  
Author(s):  
K.M.P. Mokatse ◽  
J.P.H. van Wyk
Keyword(s):  
Environmental Pollution ◽  
Incubation Period ◽  
Filter Paper ◽  
Fossil Fuels ◽  
Trichoderma Viride ◽  
Value Added ◽  
Sugar Concentration ◽  
Waste Paper ◽  
Waste Biomass ◽  
Incubation Periods

Environmental pollution and the exploitation of fossil-based products are topical issues that should be a matter of concern to the global population. The production of bio-based substances from waste biomass is a way to reduce the consumption of fossil fuels and limit environmental pollution. Enzymatic catalysed saccharification of cellulose is an important step for the bio-conversion of biomass such as waste paper into glucose that could be utilized as a feedstock for the production of value added bioproducts and this process can also be considered as an alternative route of waste management. During this study, fresh cellulase enzyme from Trichoderma viride was incubated separately with seven different waste paper materials during twelve successive incubation periods of 2 h each. The amount of sugar released from each paper material during each incubation period was determined. The highest sugar concentration released from each paper materials was produced during the first incubation period except the filter paper for which the highest amount of sugar was produced during the 9th period of incubation. During these optimum sugar producing incubation periods the highest total sugar concentration was released from brown envelope paper (3.3 mg.mL-1 followed by foolscap paper (3.0 mg.mL-1) and office paper (2.8 mg.mL-1) while the lowest amount of sugar was released from Pick ’n Pay paper (0.6 mg.mL-1). The relative saccharification percentage was also calculated which showed that filter paper produced the highest amounts of sugar followed by newspaper, and foolscap paper with advertising paper from a retailer. Pick ’n Pay offered the highest resistance towards cellulase catalysed bio-conversion into sugar.

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