Ruthenium carbonyl complexes with pyridine-alkoxide ligands: synthesis, characterization and catalytic application in dehydrogenative oxidation of alcohols

2018 ◽  
Vol 42 (18) ◽  
pp. 15472-15478 ◽  
Author(s):  
Zhiqiang Hao ◽  
Xinlong Yan ◽  
Kang Liu ◽  
Xiaohui Yue ◽  
Zhangang Han ◽  
...  
Keyword(s):  
Secondary Alcohols ◽  
Carbonyl Complexes ◽  
Mild Conditions ◽  
Catalytic Application ◽  
Ruthenium Carbonyl ◽  
Oxidation Of Alcohols ◽  
Alkoxide Ligands

Dehydrogenative oxidation of secondary alcohols catalyzed by several new trinuclear ruthenium carbonyl complexes under mild conditions was proposed.

Ruthenium carbonyl complexes supported by pyridine-alkoxide ligands: synthesis, structure and catalytic oxidation of secondary alcohols

2019 ◽  
Vol 43 (35) ◽  
pp. 13947-13953 ◽  
Author(s):  
Siqi Zong ◽  
Kang Liu ◽  
Xiaohui Yue ◽  
Zhiqiang Hao ◽  
Zhihong Ma ◽  
...  
Keyword(s):  
Catalytic Oxidation ◽  
Secondary Alcohols ◽  
Carbonyl Complexes ◽  
Ruthenium Carbonyl ◽  
Alkoxide Ligands

Five novel trinuclear ruthenium carbonyl complexes were synthesized and their application in oxidation of secondary alcohols was also researched.

Ruthenium carbonyl complexes with pyridylalkanol ligands: synthesis, characterization and catalytic properties for aerobic oxidation of secondary alcohols

2018 ◽  
Vol 42 (9) ◽  
pp. 6968-6975 ◽  
Author(s):  
Zhiqiang Hao ◽  
Ning Li ◽  
Xinlong Yan ◽  
Ying Li ◽  
Siqi Zong ◽  
...  
Keyword(s):  
Catalytic Properties ◽  
Aerobic Oxidation ◽  
Secondary Alcohols ◽  
Carbonyl Complexes ◽  
Ruthenium Carbonyl

Several new trinuclear ruthenium carbonyl complexes were synthesized and their application in aerobic oxidation of secondary alcohols was also established.

Ruthenium carbonyl complexes bearing bidentate pyridine-alkoxide ligands: Synthesis, crystal structures and reactivity

2019 ◽  
Vol 484 ◽  
pp. 142-147 ◽  
Author(s):  
Zhihong Ma ◽  
Qian Liu ◽  
Suzhen Li ◽  
Ruitao Wu ◽  
Zhangang Han ◽  
...  
Keyword(s):  
Crystal Structures ◽  
Carbonyl Complexes ◽  
Ruthenium Carbonyl ◽  
Alkoxide Ligands

Syntheses and crystal structures of ruthenium carbonyl complexes containing pyridine-alkoxide ligands

2019 ◽  
Vol 45 (2) ◽  
pp. 83-90
Author(s):  
Zhi-Qiang Hao ◽  
Si-Qi Zong ◽  
Xin-Long Yan ◽  
Zhi-Hong Ma ◽  
Su-Zhen Li ◽  
...  
Keyword(s):  
Crystal Structures ◽  
Carbonyl Complexes ◽  
Ruthenium Carbonyl ◽  
Alkoxide Ligands

Revisiting Sodium Hypochlorite Pentahydrate (NaOCl·5H2O) for the Oxidation of Alcohols in Acetonitrile without Nitroxyl Radicals

Synlett ◽  
2018 ◽  
Vol 29 (18) ◽  
pp. 2404-2407 ◽  
Author(s):  
Tsunehisa Hirashita ◽  
Yuto Sugihara ◽  
Shota Ishikawa ◽  
Yohei Naito ◽  
Yuta Matsukawa ◽  
...  
Keyword(s):  
Sodium Hypochlorite ◽  
Nitroxyl Radicals ◽  
Secondary Alcohols ◽  
Primary Alcohols ◽  
Oxidation Of Alcohols

Sodium hypochlorite pentahydrate (NaOCl·5H2O) is capable of oxidizing alcohols in acetonitrile at 20 °C without the use of catalysts. The oxidation is selective to allylic, benzylic, and secondary alcohols. ­Aliphatic primary alcohols are not oxidized.

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