Zn(ii)–nucleobase metal–organic nanofibers and nanoflowers: synthesis and photocatalytic application

2018 ◽  
Vol 42 (22) ◽  
pp. 17983-17990 ◽  
Author(s):  
Bhagwati Sharma ◽  
Arup Mahata ◽  
Sonam Mandani ◽  
Neha Thakur ◽  
Biswarup Pathak ◽  
...  

The interaction of Zn2+ ions with pure nucleobases guanine and cytosine under alkaline conditions leads to the formation of nanoscale metal–organic nanofibers and nanoflowers with excellent photocatalytic activity for the degradation of organic pollutant dyes.

NANO ◽  
2016 ◽  
Vol 11 (05) ◽  
pp. 1650054 ◽  
Author(s):  
Bin Zeng ◽  
Yang Yin

CuS hexagonal nanosheet/graphene was fabricated by a facile one-pot microwave-thermal method. The samples possess excellent photocatalytic activity for degradation of organic pollutant under visible light. The high photocatalytic activity was attributed to the deposition of CuS hexagonal nanosheet onto graphene. CuS nanosheet serves as a transporter which efficiently inhibits the recombination of the photo-induced charge carriers in the nanocomposites. The developed method demonstrates a facile approach towards the synthesis of two-dimensional semiconductor-graphene nanocomposites with excellent photocatalytic performance under visible light.


2018 ◽  
Vol 18 (9) ◽  
pp. 5045-5053 ◽  
Author(s):  
Fa-Nian Shi ◽  
Miao Lu ◽  
Yi-Wen Bai ◽  
Fang Liang ◽  
Xiao-Yi Song ◽  
...  

NANO ◽  
2017 ◽  
Vol 12 (01) ◽  
pp. 1750013 ◽  
Author(s):  
Longhai Feng ◽  
Lirong Kong ◽  
Zhenyuan Ji ◽  
Yi Wang ◽  
Xiaoping Shen ◽  
...  

An efficient N-doped reduced graphene oxide (N-RGO)/Ag3PO4 nanocomposite with enhanced photocatalytic activity has been prepared through a facile solution-based approach. Since N-RGO could offer more sites for the anchoring of Ag3PO4 nanoparticles, and effectively promote the charge carriers separation and transfer due to its high electrical conductivity, the photocatalytic activity of N-RGO/Ag3PO4 nanocomposite is much higher than bare Ag3PO4 and N-RGO in the degradation of phenol pollutant under simulated solar light irradiation. The mechanism for the photocatalytic process was also investigated. The excellent photocatalytic performance makes the N-RGO/Ag3PO4 nanocomposite a promising photocatalyst for organic pollutant treatment.


CrystEngComm ◽  
2020 ◽  
Vol 22 (25) ◽  
pp. 4206-4209 ◽  
Author(s):  
Zhan-Guo Jiang ◽  
Xin Wu ◽  
Zhong-Xuan Xu ◽  
Cai-Hong Zhan ◽  
Jian Zhang

Two homochiral metal–organic frameworks with M3L2 cages exhibit interesting hydrogen bonding helices and excellent photocatalytic activity.


Catalysts ◽  
2019 ◽  
Vol 9 (7) ◽  
pp. 565 ◽  
Author(s):  
Nurafiqah Rosman ◽  
Wan Norharyati Wan Salleh ◽  
Farhana Aziz ◽  
Ahmad Fauzi Ismail ◽  
Zawati Harun ◽  
...  

The immobilization of photocatalyst onto substrate has a great potential for energy-intensive separation to avoid the costly separation process and unwanted release of photocatalyst into the treated water. In this study, electrospun nanofiber composed of polyvinylidene fluoride (PVDF) with the immobilized ZnO, ZnO/Ag2CO3, ZnO/Ag2CO3/Ag2O, and ZnO/Ag2O photocatalysts were prepared via the electrospinning process. The immobilized ZnO and heterojunctioned ZnO in the PVDF electrospun nanofiber were proven via X-ray diffraction (XRD) and Fourier transform infrared spectroscopy (FTIR). The electrospinning allowed high chemical binding of the nanofiber composite with good physical interaction between the photocatalyst and the electrospun nanofiber. AFM images obtained for the nanofibers were found to be rougher than that of the pristine PVDF electrospun nanofiber. Among the photocatalyst embedded, the immobilized ZnO/Ag2CO3/Ag2O had endowed the nanofiber with an excellent photocatalytic activity and recyclability for the degradation of the RR120 under UV light irradiation. Based on the results, effective immobilization of ZnO/Ag2CO3/Ag2O in PVDF nanofiber with 99.62% photodegradation in 300 min compared to PVDF-ZnO, PVDF-ZnO/Ag2CO3, and PVDF-ZnO/Ag2O of 28.14%, 90.49%, and 96.34%, respectively. The effective ZnO/Ag2CO3/Ag2O immobilization into polymers with affinity toward organic dye pollutants could both increase the efficiency and reduce the energy requirements for water treatment via the photocatalytic application.


2021 ◽  
Author(s):  
Tao Wang ◽  
Xiqing Liu ◽  
Mei Liu ◽  
runhua liao ◽  
Hongquan Zhan ◽  
...  

Black TiO2 and metal-organic frameworks (MOF) were the great materials with light-harvesting, redox power and consequently catalysis. Here, the integration of MIL-100(Fe) with TiO2(B) composite was designed for photocatalytic application,...


2018 ◽  
Vol 5 (3) ◽  
pp. 723-731 ◽  
Author(s):  
Xiaoling Lin ◽  
Beibei Liu ◽  
Hui Huang ◽  
Chunfeng Shi ◽  
Yang Liu ◽  
...  

ZnS-N/C derived from Zn-based chiral MOFs exhibits excellent photocatalytic activity for the selective oxidation of cis-cyclooctene under mild conditions.


2018 ◽  
Vol 6 (5) ◽  
pp. 2091-2099 ◽  
Author(s):  
Fan Wang ◽  
Xiaoxiao He ◽  
Liming Sun ◽  
Jinquan Chen ◽  
Xiaojun Wang ◽  
...  

N-doped porous carbon incorporating N-doped TiO2 with a butterfly-like structure has been synthesized by using a Ti-based metal–organic framework as a hard template. The nanocomposites exhibit excellent photocatalytic activity.


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