High-spin enforcement in first-row metal complexes of a constrained polyaromatic ligand: synthesis, structure, and properties

2018 ◽  
Vol 42 (23) ◽  
pp. 18667-18677 ◽  
Author(s):  
Lizhu Chen ◽  
Hunter A. Dulaney ◽  
Branford O. Wilkins ◽  
Sarah Farmer ◽  
Yanbing Zhang ◽  
...  
Keyword(s):  
Coordination Chemistry ◽  
Transition Metals ◽  
Metal Complexes ◽  
High Spin ◽  
Structure And Properties ◽  
Polypyridyl Ligand ◽  
Ligand Synthesis

The coordination chemistry of a rigid tetradentate polypyridyl ligand has been developed with first-row transition metals Mn(ii), Fe(ii), Co(ii), Ni(ii), and Zn(ii).

A novel bis-1,2,4-benzothiadiazine pincer ligand: synthesis, characterization and first row transition metal complexes

2018 ◽  
Vol 47 (44) ◽  
pp. 15725-15736 ◽  
Author(s):  
Konstantina Pringouri ◽  
Muhammad U. Anwar ◽  
Liz Mansour ◽  
Nathan Doupnik ◽  
Yassine Beldjoudi ◽  
...  
Keyword(s):  
Coordination Chemistry ◽  
Transition Metal ◽  
Transition Metals ◽  
Metal Complexes ◽  
Transition Metal Complexes ◽  
Pincer Ligand ◽  
Ligand Synthesis

The synthesis and coordination chemistry of ligand LH2 to first row transition metals is described in which it acts as a tridentate N,N′,N′′-donor.

15-Membered Triolefinic Macrocycles, Their Coordination Chemistry with Transition Metals, and the Catalytic Properties of Their Palladium Metal Complexes.

ChemInform ◽  
2004 ◽  
Vol 35 (46) ◽  
Author(s):  
Marcial Moreno-Manas ◽  
Roser Pleixats ◽  
Anna Roglans ◽  
Rosa M. Sebastian ◽  
Adelina Vallribera
Keyword(s):  
Coordination Chemistry ◽  
Transition Metals ◽  
Metal Complexes ◽  
Catalytic Properties ◽  
Palladium Metal

scholarly journals 15-Membered triolefinic macrocycles, their coordination chemistry with transition metals, and the catalytic properties of their palladium metal complexes. A review.

ARKIVOC ◽  
2004 ◽  
Vol 2004 (4) ◽  
pp. 109-129 ◽  
Author(s):  
Marcial Moreno-Mañas ◽  
Roser Pleixats ◽  
Anna Roglans ◽  
Rosa M. Sebastián ◽  
Adelina Vallribera
Keyword(s):  
Coordination Chemistry ◽  
Transition Metals ◽  
Metal Complexes ◽  
Catalytic Properties ◽  
Palladium Metal

scholarly journals First-row transition metal complexes of ENENES ligands: the ability of the thioether donor to impact the coordination chemistry

2016 ◽  
Vol 45 (4) ◽  
pp. 1560-1571 ◽  
Author(s):  
Pavel A. Dub ◽  
Brian L. Scott ◽  
John C. Gordon
Keyword(s):  
Magnetic Susceptibility ◽  
Coordination Chemistry ◽  
Transition Metal ◽  
Metal Complexes ◽  
High Spin ◽  
Transition Metal Complexes

The reactions of two variants of ENENES ligands, E(CH2)2NH(CH)2SR, where E = 4-morpholinyl, R = Ph (a), Bn (b) with MCl2 (M = Mn, Fe, Co, Ni and Cu) in coordinating solvents (MeCN, EtOH) affords isolable complexes, whose magnetic susceptibility measurements suggest paramagnetism and a high-spin formulation.

Bismuth Species in the Coordination Sphere of Transition Metals: Syntheses, Bonding, Coordination Chemistry, and Reactivity of Molecular Complexes

2021 ◽  
Author(s):  
Jacqueline Ramler ◽  
Crispin Lichtenberg
Keyword(s):  
Coordination Chemistry ◽  
Transition Metal ◽  
Transition Metals ◽  
Metal Complexes ◽  
Transition Metal Complexes ◽  
Coordination Sphere ◽  
Molecular Complexes ◽  
Molecular Transition

This contribution is focused on bismuth species in the coordination sphere of transition metals. In molecular transition metal complexes, three types of Bi–M bonding are considered, namely dative Bi→M interactions...

Fine-Tuning Electronic Properties of Luminescent Pt(II) Complexes via Vertex-Differentiated Coordination of Sterically Invariant Carborane-Based Ligands

2018 ◽  
Author(s):  
Kent O. Kirlikovali ◽  
Jonathan C. Axtell ◽  
Kierstyn Anderson ◽  
Peter I. Djurovich ◽  
Arnold L. Rheingold ◽  
...  
Keyword(s):  
Coordination Chemistry ◽  
Metal Complexes ◽  
Electronic Properties ◽  
Fine Tuning ◽  
Fine Tune

We report the synthesis of two isomeric Pt(II) complexes ligated by doubly deprotonated 1,1′-bis(<i>o</i>-carborane) (<b>bc</b>). This work provides a potential route to fine-tune the electronic properties of luminescent metal complexes by virtue of vertex-differentiated coordination chemistry of carborane-based ligands.

Endo- and exohedral chloro-fulleride as η5 ligands: A DFT study on the first-row transition metal complexes

2021 ◽  
Author(s):  
Sebastian Anila ◽  
Cherumuttathu Hariharan Suresh
Keyword(s):  
Transition Metal ◽  
Transition Metals ◽  
Metal Complexes ◽  
Transition Metal Complexes ◽  
Dft Study ◽  
C60 Fullerene ◽  
Ring Fusion ◽  
Coordination Modes

C60 fullerene coordinates to transition metals in η2-fashion through its C-C bond at [6,6] ring fusion whereas other coordination modes η3, η4, η5 and η6 are rarely observed. The coordination...

High-Spin Metal Complexes Containing a Ferromagnetically Coupled Tris(semiquinone) Ligand

2002 ◽  
Vol 41 (5) ◽  
pp. 1086-1092 ◽  
Author(s):  
Andrea Caneschi ◽  
Andrea Dei ◽  
Christopher P. Mussari ◽  
David A. Shultz ◽  
Lorenzo Sorace ◽  
...  
Keyword(s):  
Metal Complexes ◽  
High Spin
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