Aggregation-induced ratiometric emission and mechanochromic luminescence in a pyrene-benzohydrazonate conjugate

2018 ◽  
Vol 42 (15) ◽  
pp. 12644-12648 ◽  
Author(s):  
Yao Li ◽  
Wei Huang ◽  
Juan Yong ◽  
Shuaidan Huang ◽  
Yujie Li ◽  
...  

A structure tunable pyrene benzohydrazonate-based molecular platform exhibits a drastic aggregation-induced color change and a high solid-state quantum yield.

2014 ◽  
Vol 2014 (16) ◽  
pp. 2695-2703 ◽  
Author(s):  
Fabio Borbone ◽  
Ugo Caruso ◽  
Mauro Causà ◽  
Sandra Fusco ◽  
Barbara Panunzi ◽  
...  

Molecules ◽  
2021 ◽  
Vol 26 (11) ◽  
pp. 3393
Author(s):  
Mikhail A. Vershinin ◽  
Marianna I. Rakhmanova ◽  
Alexander S. Novikov ◽  
Maxim N. Sokolov ◽  
Sergey A. Adonin

Reactions between Zn(II) dihalides and 2-halogen-substituted pyridines 2-XPy result in a series of heteroleptic molecular complexes [(2-XPy)2ZnY2] (Y = Cl, X = Cl (1), Br (2), I (3); Y = Br, X = Cl (4), Br (5), I (6), Y = I, X = Cl (7), Br (8), and I (9)). Moreover, 1–7 are isostructural (triclinic), while 8 and 9 are monoclinic. In all cases, halogen bonding plays an important role in formation of crystal packing. Moreover, 1–9 demonstrate luminescence in asolid state; for the best emitting complexes, quantum yield (QY) exceeds 21%.


Inorganics ◽  
2021 ◽  
Vol 9 (10) ◽  
pp. 74
Author(s):  
Franz A. Mautner ◽  
Florian Bierbaumer ◽  
Roland C. Fischer ◽  
Ana Torvisco ◽  
Ramon Vicente ◽  
...  

Ten mononuclear rare earth complexes of formula [La(btfa)3(H2O)2] (1), [La(btfa)3(4,4′-Mt2bipy)] (2), [La(btfa)3(4,4′-Me2bipy)2] (3), [La(btfa)3(5,5′-Me2bipy)2] (4), [La(btfa)3(terpy)] (5), [La(btfa)3(phen)(EtOH)] (6), [La(btfa)3(4,4′-Me2bipy)(EtOH)] (7), [La(btfa)3(2-benzpy)(MeOH)] (8), [Tb(btfa)3(4,4′-Me2bipy)] (9) and (Hpy)[Eu(btfa)4] (10), where btfa = 4,4,4-trifuoro-1-phenylbutane-1,3-dionato anion, 4,4′-Mt2bipy = 4,4′-dimethoxy-2,2′-bipyridine, 4,4′-Me2bipy = 4,4′-dimethyl-2,2′-bipyridine, 5,5′-Me2bipy = 5,5′-dimethyl-2,2′-bipyridine, terpy = 2,2′:6′,2′-terpyridine, phen = 1,10-phenathroline, 2-benzpy = 2-(2-pyridyl)benzimidazole, Hpy = pyridiniumH+ cation) have been synthesized and structurally characterized. The complexes display coordination numbers (CN) eight for 1, 2, 9, 10, nine for 5, 6, 7, 8 and ten for 3 and 4. The solid-state luminescence spectra of Tb-9 and Eu-10 complexes showed the same characteristic bands predicted from the Tb(III) and Eu(III) ions. The Overall Quantum Yield measured (ϕTOT) at the excitation wavelength of 371 nm for both compounds yielded 1.04% for 9 and up to 34.56% for 10.


RSC Advances ◽  
2015 ◽  
Vol 5 (67) ◽  
pp. 54622-54628 ◽  
Author(s):  
Xinguo Zhang ◽  
Liya Zhou ◽  
Qi Pang ◽  
Menglian Gong

LiGd5P2O13 : Eu3+ red phosphors were prepared by solid-state reaction method. Phosphors could be efficiently excited by NUV/blue light and emit pure-red light. LiGd5P2O13 : Eu3+ shows good thermal stability with quantum yield of 46.5%.


2021 ◽  
Author(s):  
Hai-Jiao Wang ◽  
Wan-Yi Hou ◽  
Jing Kang ◽  
Xin-Yu Zhai ◽  
Hongli Chen ◽  
...  

Due to the direct π - π interaction and excessive energy resonance transfer, it is very challenging to prepare CDs with high fluorescence quantum yield (QY) in solid state. In...


2019 ◽  
Vol 7 (10) ◽  
pp. 3100-3104 ◽  
Author(s):  
Ning-Ning Zhang ◽  
Rong-Jian Sa ◽  
Shan-Shan Sun ◽  
Ming-De Li ◽  
Ming-Sheng Wang ◽  
...  

An unprecedented series of triazole-based donor–acceptor molecules were found to form highly air/heat-stable triplet diradicals in the solid state accompanied by a color change after photoinduced intramolecular charge separation.


CrystEngComm ◽  
2019 ◽  
Vol 21 (38) ◽  
pp. 5699-5706 ◽  
Author(s):  
Suguru Ito ◽  
Chika Nishimoto ◽  
Sayaka Nagai

A stepwise temperature-controlled emission-color switch has been achieved in a system that combines halochromic and mechanochromic luminescence in series.


Nanoscale ◽  
2020 ◽  
Vol 12 (29) ◽  
pp. 15791-15799 ◽  
Author(s):  
Hao-Hua Deng ◽  
Qiong-Qiong Zhuang ◽  
Kai-Yuan Huang ◽  
Paramasivam Balasubramanian ◽  
Zhen Lin ◽  
...  

White-light-emitting devices are successfully fabricated by using solid-state copper nanoclusters as the sole phosphors with aggregation-induced emission properties.


2020 ◽  
Vol 30 (31) ◽  
pp. 2002481 ◽  
Author(s):  
Pattarawadee Therdkatanyuphong ◽  
Pongsakorn Chasing ◽  
Chokchai Kaiyasuan ◽  
Sumita Boonnab ◽  
Taweesak Sudyoadsuk ◽  
...  

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