Structure, sensing and photocatalytic properties of two multifunctional 3D luminescent coordination polymers based on an N-heterocyclic carboxylic acid

2018 ◽  
Vol 42 (11) ◽  
pp. 8905-8913 ◽  
Author(s):  
Ziao Zong ◽  
Caifeng Bi ◽  
Zheng Zhu ◽  
Chuanbin Fan ◽  
Xiangmin Meng ◽  
...  

Two novel luminescent coordination polymers, {[Zn(tmlb)(H2tmlb)]·H2O}n (1) and [Zn(tmlb)(bbibp)]n (2) ((bbibp = bis(benzoimidazo-1-ly)biphenyl), H2tmlb = (1H-1,2,4-triazol-1-yl)methylenebis(benzoic acid)), have been rationally designed and successfully solvothermally synthesized.

CrystEngComm ◽  
2020 ◽  
Vol 22 (41) ◽  
pp. 6847-6855
Author(s):  
Chen-Lan Lin ◽  
Yan-Fei Chen ◽  
Li-Juan Qiu ◽  
Binglong Zhu ◽  
Xin Wang ◽  
...  

The photocatalytic activities of two novel different 2-D coordination polymers constructed from 5-hydroxy-1H-pyrazole-3-carboxylic acid ligand have been explored.


CrystEngComm ◽  
2019 ◽  
Vol 21 (5) ◽  
pp. 925-925
Author(s):  
Zi-ao Zong ◽  
Chuan-bin Fan ◽  
Xia Zhang ◽  
Xiang-min Meng ◽  
Fan Jin ◽  
...  

Correction for ‘Four Co(ii) coordination polymers based on 4,4′-(1H-1,2,4-triazol-1-yl)methylenebis(benzoic acid): syntheses, structural diversity, magnetic properties, dye adsorption and photocatalytic properties’ by Zi-ao Zong et al., CrystEngComm, 2019, DOI: 10.1039/c8ce01203b.


CrystEngComm ◽  
2019 ◽  
Vol 21 (4) ◽  
pp. 673-686 ◽  
Author(s):  
Zi-ao Zong ◽  
Chuan-bin Fan ◽  
Xia Zhang ◽  
Xiang-min Meng ◽  
Fan Jin ◽  
...  

Four multi-functional Co(ii) complexes are applied in removing organic dye molecules from the wastewater.


2014 ◽  
Vol 43 (33) ◽  
pp. 12790-12799 ◽  
Author(s):  
Lu Liu ◽  
Jie Ding ◽  
Ming Li ◽  
Xiaofeng Lv ◽  
Jie Wu ◽  
...  

Six interesting architectures with different structural and topological motifs have been obtained. 3, 4 and 6 exhibit good photocatalytic activities for methylene blue degradation.


2021 ◽  
Vol 0 (0) ◽  
Author(s):  
Shan-Bao Qiao

Abstract A new Cu(II) complex, [Cu2(1,3-BMIB)(OBA)2] n (1) (1,3-BMIB = 1,3-bis(2-methyl-1H-imidazol-1-yl)benzene, H2OBA = 4,4′-oxybis(benzoic acid)) was hydrothermally synthesized and has been structurally characterized. Complex 1 possesses a 3D 2-fold interpenetrating framework based on [Cu(OBA)] n layers with a Schläfli symbol {412.63}. Complex 1 displays excellent photocatalytic properties in the degradation of methylene blue (MB) and rhodamine B (RhB).


Inorganics ◽  
2021 ◽  
Vol 9 (3) ◽  
pp. 20
Author(s):  
Antonio A. García-Valdivia ◽  
Estitxu Echenique-Errandonea ◽  
Gloria B. Ramírez-Rodríguez ◽  
José M. Delgado-López ◽  
Belén Fernández ◽  
...  

Two new coordination polymers (CPs) based on Zn(II) and Cd(II) and 1H-indazole-6-carboxylic acid (H2L) of general formulae [Zn(L)(H2O)]n (1) and [Cd2(HL)4]n (2) have been synthesized and fully characterized by elemental analyses, Fourier transformed infrared spectroscopy and single crystal X-ray diffraction. The results indicate that compound 1 possesses double chains in its structure whereas 2 exhibits a 3D network. The intermolecular interactions, including hydrogen bonds, C–H···π and π···π stacking interactions, stabilize both crystal structures. Photoluminescence (PL) properties have shown that compounds 1 and 2 present similar emission spectra compared to the free-ligand. The emission spectra are also studied from the theoretical point of view by means of time-dependent density-functional theory (TD-DFT) calculations to confirm that ligand-centred π-π* electronic transitions govern emission of compound 1 and 2. Finally, the PL properties are also studied in aqueous solution to explore the stability and emission capacity of the compounds.


2008 ◽  
Vol 112 (46) ◽  
pp. 14637-14647 ◽  
Author(s):  
D. Akcakayiran ◽  
D. Mauder ◽  
C. Hess ◽  
T. K. Sievers ◽  
D. G. Kurth ◽  
...  

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