scholarly journals Electric field induced rotation of halogenated organic linkers in isoreticular metal–organic frameworks for nanofluidic applications

2018 ◽  
Vol 3 (6) ◽  
pp. 951-958 ◽  
Author(s):  
Sadanandam Namsani ◽  
A. Ozgur Yazaydin

Electric field induced rotation of IRMOF linkers provides opportunities for controlling the diffusion of molecules for nanofluidic applications.

2019 ◽  
Author(s):  
Liviu Zarbo ◽  
Marius Oancea ◽  
Emmanuel Klontzas ◽  
Emmanuel Tylianakis ◽  
Ioana G. Grosu ◽  
...  

<p>Using a multiscale approach, we show that applied electric field does not affect significantly the hydrogen uptake of weakly polarizable metal-organic frameworks (MOFs). Nonetheless, we show that, for large MOF polarizabilities, the hydrogen uptake can double in applied electric field. We propose searching for a novel class of hydrogen storage materials, that of highly polarizable porous MOFs. Hydrogen uptake in such materials would be controlled by electric field, a much easier to adjust parameter than pressure or temperature.</p>


2020 ◽  
Vol 132 (31) ◽  
pp. 13201-13208
Author(s):  
Jiayue Tian ◽  
Feilong Jiang ◽  
Daqiang Yuan ◽  
Linjie Zhang ◽  
Qihui Chen ◽  
...  

Author(s):  
Liviu Zarbo ◽  
Marius Oancea ◽  
Emmanuel Klontzas ◽  
Emmanuel Tylianakis ◽  
Ioana G. Grosu ◽  
...  

<p>Using a multiscale approach, we show that applied electric field does not affect significantly the hydrogen uptake of weakly polarizable metal-organic frameworks (MOFs). Nonetheless, we show that, for large MOF polarizabilities, the hydrogen uptake can double in applied electric field. We propose searching for a novel class of hydrogen storage materials, that of highly polarizable porous MOFs. Hydrogen uptake in such materials would be controlled by electric field, a much easier to adjust parameter than pressure or temperature.</p>


2017 ◽  
Vol 5 (18) ◽  
pp. 8690-8696 ◽  
Author(s):  
Benjamin Tam ◽  
Ozgur Yazaydin

Molecular gates mounted on MOFs act like nanovalves and control diffusion of molecules.


2021 ◽  
Vol 516 ◽  
pp. 111970
Author(s):  
Jarinya Sittiwong ◽  
Thanaporn Jaturajamrenchai ◽  
Pitchaya Wongkampuan ◽  
Nutchanon Somwatcharajit ◽  
Sarawoot Impeng ◽  
...  

2021 ◽  
Author(s):  
Lars Öhrström ◽  
Francoise M. Amombo Noa

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