A new method to deconvolute binary mixture in LA-ICP-MS analyses to quantify the composition of phases smaller than the laser spot size

2018 ◽  
Vol 33 (9) ◽  
pp. 1518-1528 ◽  
Author(s):  
Longbo Yang ◽  
Vincent J. van Hinsberg ◽  
Iain M. Samson

New quantification strategy to deconvolute the data signal of a binary mixture in laser ablation ICP-MS analysis.

2020 ◽  
Vol 34 (4) ◽  
pp. 733-740
Author(s):  
Seiya Tanaka ◽  
Shin Yamada ◽  
Kimiya Komurasaki ◽  
Hiroyuki Koizumi

Author(s):  
Karl Schulmeister ◽  
Bernhard Seiser ◽  
Florian Edthofer ◽  
David J. Lund

Chemosensors ◽  
2021 ◽  
Vol 9 (4) ◽  
pp. 77
Author(s):  
Davide Spanu ◽  
Gilberto Binda ◽  
Marcello Marelli ◽  
Laura Rampazzi ◽  
Sandro Recchia ◽  
...  

A laser ablation–inductively coupled plasma–mass spectrometry (LA–ICP–MS) based method is proposed for the quantitative determination of the spatial distribution of metal nanoparticles (NPs) supported on planar substrates. The surface is sampled using tailored ablation patterns and the data are used to define three-dimensional functions describing the spatial distribution of NPs. The volume integrals of such interpolated surfaces are calibrated to obtain the mass distribution of Ag NPs by correlation with the total mass of metal as determined by metal extraction and ICP–MS analysis. Once this mass calibration is carried out on a sacrificial sample, quantifications can be performed over multiple samples by a simple micro-destructive LA–ICP–MS analysis without requiring the extraction/dissolution of metal NPs. The proposed approach is here tested using a model sample consisting of a low-density polyethylene (LDPE) disk decorated with silver NPs, achieving high spatial resolution over cm2-sized samples and very high sensitivity. The developed method is accordingly a useful analytical tool for applications requiring both the total mass and the spatial distribution of metal NPs to be determined without damaging the sample surface (e.g., composite functional materials and NPs, decorated catalysts or electrodic materials).


2021 ◽  
Vol 11 (1) ◽  
Author(s):  
E. Wang ◽  
V. N. Litvinenko ◽  
I. Pinayev ◽  
M. Gaowei ◽  
J. Skaritka ◽  
...  

AbstractHigh brightness, high charge electron beams are critical for a number of advanced accelerator applications. The initial emittance of the electron beam, which is determined by the mean transverse energy (MTE) and laser spot size, is one of the most important parameters determining the beam quality. The bialkali photocathodes illuminated by a visible laser have the advantages of high quantum efficiency (QE) and low MTE. Furthermore, Superconducting Radio Frequency (SRF) guns can operate in the continuous wave (CW) mode at high accelerating gradients, e.g. with significant reduction of the laser spot size at the photocathode. Combining the bialkali photocathode with the SRF gun enables generation of high charge, high brightness, and possibly high average current electron beams. However, integrating the high QE semiconductor photocathode into the SRF guns has been challenging. In this article, we report on the development of bialkali photocathodes for successful operation in the SRF gun with months-long lifetime while delivering CW beams with nano-coulomb charge per bunch. This achievement opens a new era for high charge, high brightness CW electron beams.


2014 ◽  
Vol 29 (5) ◽  
pp. 903 ◽  
Author(s):  
Jitka Míková ◽  
Jan Košler ◽  
Michael Wiedenbeck

2022 ◽  
Vol 73 ◽  
pp. 26-39
Author(s):  
Jordan S. Weaver ◽  
Jarred C. Heigel ◽  
Brandon M. Lane

2001 ◽  
Vol 48 (5) ◽  
pp. 757 ◽  
Author(s):  
E. A. Belousova ◽  
W. L. Griffin ◽  
S. R. Shee ◽  
S. E. Jackson ◽  
S. Y. O'Reilly

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