scholarly journals Plasma processes to detect fluorine with ICPMS/MS as [M–F]+: an argument for building a negative mode ICPMS/MS

2018 ◽  
Vol 33 (8) ◽  
pp. 1304-1309 ◽  
Author(s):  
Nor Laili Azua Jamari ◽  
Arne Behrens ◽  
Andrea Raab ◽  
Eva M. Krupp ◽  
Jörg Feldmann
Keyword(s):  
Bond Energy ◽  
Fluoride Ion ◽  
Metal Fluoride ◽  
Ionisation Potential ◽  
Negative Mode ◽  
The Difference ◽  
Oxygen Bond

The paper describes that the 2nd ionisation potential and the difference in bond energy of a metal to fluorine bond and of a metal to oxygen bond are the most important parameters to form a metal fluoride ion for the detection of fluorine in ICPMS/MS.

scholarly journals Fluoride Ion Interactions in Alkali-Metal Fluoride–Diol Complexes

2020 ◽  
Vol 59 (9) ◽  
pp. 6631-6639 ◽  
Author(s):  
Yuto Tonouchi ◽  
Kazuhiko Matsumoto ◽  
Takashi Nagata ◽  
Masato Katahira ◽  
Rika Hagiwara
Keyword(s):  
Alkali Metal ◽  
Fluoride Ion ◽  
Metal Fluoride ◽  
Alkali Metal Fluoride ◽  
Ion Interactions

A New Determination of the Fluoride Ion−Water Bond Energy

1999 ◽  
Vol 121 (14) ◽  
pp. 3531-3532 ◽  
Author(s):  
Patrick Weis ◽  
Paul R. Kemper ◽  
Michael T. Bowers ◽  
Sotiris S. Xantheas
Keyword(s):  
Bond Energy ◽  
Fluoride Ion

Der Einfluß der Überlappung in der Theorie der π-Elektronensysteme von HÜCKEL und HARTMANN

1961 ◽  
Vol 16 (12) ◽  
pp. 1328-1333 ◽  
Author(s):  
W. A. Bingel ◽  
H. Preuss ◽  
H.-H. Schmidtke
Keyword(s):  
Excitation Energy ◽  
Wave Functions ◽  
Electron Systems ◽  
Level Spacing ◽  
Ionisation Potential ◽  
Pairing Property ◽  
The Difference ◽  
Mo Theory

The simple MO—LCAO-method for alternant π-electron systems has been extended recently to include higher p π-orbitals. In this version of the MO-method- the pairing property between the energies and wave functions of the bonding and antibonding π-MO's is no longer correct, the level spacing of the antibonding MO's is now smaller than that of the bonding ones. This effect has been used to explain 1 the approximate constancy of the difference: 1st excitation energy—1st ionisation potential for a great number of molecules, which was observed by SCHEIBE 2. In the present work the influence of atomic overlap on the extended MO-theory is investigated.

Dependence of the catalytic properties of cobalt molybdate in propylene oxidation on the surface reduction and oxygen bond energy

1977 ◽  
Vol 7 (2) ◽  
pp. 187-191 ◽  
Author(s):  
T. V. Andrushkevich ◽  
G. K. Boreskov ◽  
Yu. D. Pankratiev ◽  
G. Ya. Popova ◽  
O. N. Kozmenko ◽  
...  
Keyword(s):  
Bond Energy ◽  
Catalytic Properties ◽  
Propylene Oxidation ◽  
Surface Reduction ◽  
Cobalt Molybdate ◽  
Oxygen Bond
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