Iridium-catalysed primary alcohol oxidation and hydrogen shuttling for the depolymerisation of lignin

2018 ◽  
Vol 20 (14) ◽  
pp. 3214-3221 ◽  
Author(s):  
Christopher S. Lancefield ◽  
Lucas W. Teunissen ◽  
Bert M. Weckhuysen ◽  
Pieter C. A. Bruijnincx
Keyword(s):  
Primary Alcohol ◽  
Alcohol Oxidation

A new Ir catalysed approach for the selective cleavage of the Cα–Cβ bond in lignin β-O-4 units, allowing access to novel and tuneable monomeric product mixtures.

Domino Primary Alcohol Oxidation-Wittig Reaction: Total Synthesis of ABT-418 and (E)-4-Oxonon-2-enoic Acid

Synthesis ◽  
2004 ◽  
Vol 2004 (11) ◽  
pp. 1859-1863 ◽  
Author(s):  
Santosh Tilve ◽  
Jyoti Shet ◽  
Vidya Desai
Keyword(s):  
Total Synthesis ◽  
Wittig Reaction ◽  
Primary Alcohol ◽  
Alcohol Oxidation ◽  
Enoic Acid

Direct Oxidation of Primary Alcohols to Carboxylic Acids

Synthesis ◽  
2020 ◽  
Author(s):  
Travis J. Williams ◽  
Valeriy Cherepakhin
Keyword(s):  
Carboxylic Acids ◽  
Direct Synthesis ◽  
Primary Alcohol ◽  
Alcohol Oxidation ◽  
Atom Economy ◽  
Primary Alcohols ◽  
Direct Oxidation ◽  
Metal Compounds ◽  
New Methods ◽  
Active Research

AbstractOxidation of primary alcohols to carboxylic acids is a fundamental transformation in organic chemistry, yet despite its simplicity, extensive use, and relationship to pH, it remains a subject of active research for synthetic organic chemists. Since 2013, a great number of new methods have emerged that utilize transition-metal compounds as catalysts for acceptorless dehydrogenation of alcohols to carboxylates. The interest in this reaction is explained by its atom economy, which is in accord with the principles of sustainability and green chemistry. Therefore, the methods for the direct synthesis of carboxylic acids from alcohols is ripe for a modern survey, which we provide in this review.1 Introduction2 Thermodynamics of Primary Alcohol Oxidation3 Oxometalate Oxidation4 Transfer Dehydrogenation5 Acceptorless Dehydrogenation6 Electrochemical Methods7 Outlook

ChemInform Abstract: PRIMARY ALCOHOL OXIDATION WITH N-IODOSUCCINIMIDE

1984 ◽  
Vol 15 (6) ◽  
Author(s):  
T. R. BEEBE ◽  
R. L. ADKINS ◽  
C. C. BOGARDUS ◽  
B. CHAMPNEY ◽  
P. S. HII ◽  
...  
Keyword(s):  
Primary Alcohol ◽  
Alcohol Oxidation

scholarly journals Photocatalytic primary alcohol oxidation on WO3 nanoplatelets

RSC Advances ◽  
2019 ◽  
Vol 9 (49) ◽  
pp. 28688-28694 ◽  
Author(s):  
Kori D. McDonald ◽  
Bart M. Bartlett
Keyword(s):  
Microwave Irradiation ◽  
Aqueous Media ◽  
Primary Alcohol ◽  
Alcohol Oxidation ◽  
Synthesis Methods ◽  
Direct Heating ◽  
Lower Temperature

With the aid of direct heating through microwave irradiation in non-aqueous media, nanocrystalline tungsten(vi) oxide is achievable in 30 minutes at 200 °C, faster and at a lower temperature than conventional synthesis methods.

scholarly journals Organocatalytic Chemoselective Primary Alcohol Oxidation and Subsequent Cleavage of Lignin Model Compounds and Lignin

ChemSusChem ◽  
2017 ◽  
Vol 10 (13) ◽  
pp. 2707-2713 ◽  
Author(s):  
Saumya Dabral ◽  
José G. Hernández ◽  
Paul C. J. Kamer ◽  
Carsten Bolm
Keyword(s):  
Primary Alcohol ◽  
Alcohol Oxidation ◽  
Model Compounds ◽  
Lignin Model Compounds ◽  
Lignin Model

Primary alcohol oxidation with N-iodosuccinimide

1983 ◽  
Vol 48 (18) ◽  
pp. 3126-3128 ◽  
Author(s):  
T. R. Beebe ◽  
R. L. Adkins ◽  
C. C. Bogardus ◽  
B. Champney ◽  
P. S. Hii ◽  
...  
Keyword(s):  
Primary Alcohol ◽  
Alcohol Oxidation
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