scholarly journals Ionic liquids vs. microporous solids as reusable reaction media for the catalytic C–H functionalization of indoles with alcohols

2018 ◽  
Vol 20 (11) ◽  
pp. 2481-2485 ◽  
Author(s):  
Francisco G. Cirujano ◽  
Maxime Stalpaert ◽  
Dirk E. De Vos
Keyword(s):  
Ionic Liquids ◽  
High Performance ◽  
Solvent Free ◽  
Solvent Free Conditions ◽  
Reaction Media ◽  
Microporous Solids

High performance reusable catalysts and reaction media are evaluated for the green alkylation of indoles with alcohols under mild and solvent-free conditions.

Recent advances in N-formylation of amines and nitroarenes using efficient (nano)catalysts in eco-friendly media

2019 ◽  
Vol 21 (19) ◽  
pp. 5144-5167 ◽  
Author(s):  
Mahmoud Nasrollahzadeh ◽  
Narjes Motahharifar ◽  
Mohaddeseh Sajjadi ◽  
Amir Moradzadeh Aghbolagh ◽  
Mohammadreza Shokouhimehr ◽  
...  
Keyword(s):  
Ionic Liquids ◽  
Polyethylene Glycol ◽  
Solvent Free ◽  
Recent Advances ◽  
Solvent Free Conditions ◽  
Nano Catalysts

N-Formylation of amines or nitroarenes in water, polyethylene glycol, and ionic liquids, as well as under solvent-free conditions, is summarized.

Lewis basic ionic liquids-catalyzed synthesis of 5-aryl-2-oxazolidinones from aziridines and CO2 under solvent-free conditions

2010 ◽  
Vol 12 (10) ◽  
pp. 1850 ◽  
Author(s):  
Zhen-Zhen Yang ◽  
Liang-Nian He ◽  
Shi-Yong Peng ◽  
An-Hua Liu
Keyword(s):  
Ionic Liquids ◽  
Solvent Free ◽  
Solvent Free Conditions

scholarly journals N-Hydroxyphthalimide Supported on Silica Coated with Ionic Liquids Containing CoCl2 (SCILLs) as New Catalytic System for Solvent-Free Ethylbenzene Oxidation

Catalysts ◽  
2020 ◽  
Vol 10 (2) ◽  
pp. 252 ◽  
Author(s):  
Gabriela Dobras ◽  
Kornela Kasperczyk ◽  
Sebastian Jurczyk ◽  
Beata Orlińska
Keyword(s):  
Catalytic Activity ◽  
Ionic Liquids ◽  
Fold Increase ◽  
Solvent Free ◽  
High Catalytic Activity ◽  
Ethylbenzene Oxidation ◽  
Solvent Free Conditions ◽  
Ft Ir ◽  
Tga Analysis ◽  
Ft Ir Spectroscopy

N-Hydroxyphthalimide was immobilized via ester bond on commercially available silica gel (SiOCONHPI) and then coated with various ionic liquids containing dissolved CoCl2 (SiOCONHPI@CoCl2@IL). New catalysts were characterized by means of FT IR spectroscopy, elemental analysis, SEM and TGA analysis and used in ethylbenzene oxidation with oxygen under mild solvent-free conditions (80 °C, 0.1 MPa). High catalytic activity of SiOCONHPI was proved. In comparison to a non-catalytic reaction, a two-fold increase in conversion of ethylbenzene was observed (from 4.7% to 8.6%). Coating of SiOCONHPI with [bmim][OcOSO3], [bmim][Cl] and [bmim][CF3SO3] containing CoCl2 enabled to increase the catalytic activity in relation to systems in which IL and CoCl2 were added directly to reaction mixture. The highest conversion of ethylbenzene was obtained while SiOCONHPI@CoCl2@[bmim][OcOSO3] were used (12.1%). Catalysts recovery and reuse was also studied.

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