Efficient and reversible absorption of ammonia by cobalt ionic liquids through Lewis acid–base and cooperative hydrogen bond interactions

2018 ◽  
Vol 20 (9) ◽  
pp. 2075-2083 ◽  
Author(s):  
Shaojuan Zeng ◽  
Lei Liu ◽  
Dawei Shang ◽  
Jianpeng Feng ◽  
Haifeng Dong ◽  
...  
Keyword(s):  
Hydrogen Bond ◽  
Ionic Liquids ◽  
Lewis Acid ◽  
Acid Base ◽  
Highly Efficient ◽  
Hydrogen Bond Interactions

Cobalt ionic liquids with highly efficient and reversible absorption of NH3 through Lewis acid–base and hydrogen bond interactions were designed.

Highly efficient CO2 capture by carbonyl-containing ionic liquids through Lewis acid–base and cooperative C–H⋯O hydrogen bonding interaction strengthened by the anion

2014 ◽  
Vol 50 (95) ◽  
pp. 15041-15044 ◽  
Author(s):  
Fang Ding ◽  
Xi He ◽  
Xiaoyan Luo ◽  
Wenjun Lin ◽  
Kaihong Chen ◽  
...  
Keyword(s):  
Hydrogen Bonding ◽  
Ionic Liquids ◽  
Lewis Acid ◽  
Co2 Capture ◽  
Significant Enhancement ◽  
Hydrogen Bonding Interaction ◽  
Acid Base ◽  
Highly Efficient ◽  
Bonding Interaction

Carbonyl-containing anion-functionalized ionic liquids exhibit a significant enhancement in CO2 capacity and excellent reversibility.

Solvation and redox properties of [Co(en)3]3+-[Co(en)3]2+ system

1980 ◽  
Vol 45 (2) ◽  
pp. 335-338 ◽  
Author(s):  
Adéla Kotočová ◽  
Ulrich Mayer
Keyword(s):  
Hydrogen Bond ◽  
Lewis Acid ◽  
Specific Interaction ◽  
Redox Properties ◽  
Solvation Effect ◽  
Interacting Particles ◽  
Acid Base ◽  
Polar Solvents ◽  
Oxidation Reduction ◽  
Solvent Molecules

The solvation effect of a number of nonaqueous polar solvents was studied on the oxidation-reduction properties of the [Co(en)3]3+-[Co(en)3]2+ system. Interactions of these ions with the solvent molecules are discussed in terms of their coordination, which is accompanied by a specific interaction of the Lewis acid-base type, namely formation of a hydrogen bond between the interacting particles. This is the main controlling factor of the redox properties of the studied system.

Highly efficient iron phthalocyanine catalyzed oxidative synthesis of imines from alcohols and amines

2013 ◽  
Vol 91 (8) ◽  
pp. 732-737 ◽  
Author(s):  
Manju Bala ◽  
Praveen Kumar Verma ◽  
Neeraj Kumar ◽  
Upendra Sharma ◽  
Bikram Singh
Keyword(s):  
Lewis Acid ◽  
Oxidative Coupling ◽  
Aliphatic Alcohols ◽  
Nucleophilic Attack ◽  
Iron Phthalocyanine ◽  
Acid Base ◽  
Base Interaction ◽  
Highly Efficient ◽  
Activation Of Alcohols ◽  
Acid Base Interaction

An efficient iron phthalocyanine catalyzed method was developed for direct oxidative coupling of alcohols with amines to afford corresponding imines. The present protocol is applicable to various substituted aromatic and aliphatic alcohols and amines. The reaction is believed to proceed via activation of alcohols by iron phthalocyanines through Lewis acid–base interaction to form aldehydes, which by nucleophilic attack of amines are converted into the corresponding imines.

MoIV3⋯[O8Mo4]3 Lewis acid–base cluster pairs: highly efficient and stable Lewis catalysis fields frustrated in crystalline nanoclusters

Nanoscale ◽  
2020 ◽  
Vol 12 (39) ◽  
pp. 20230-20238
Author(s):  
Fang Yu ◽  
Benlong Luo ◽  
Ruili Sang ◽  
Li Xu
Keyword(s):  
Lewis Acid ◽  
Acid Base ◽  
Highly Efficient ◽  
Base Cluster

A new concept of a Lewis catalysis field built of frustrated Lewis acid⋯base cluster pairs has been proposed.

scholarly journals Mutual Lewis Acid-Base Interactions of Cations and Anions in Ionic Liquids

2012 ◽  
Vol 19 (1) ◽  
pp. 288-293 ◽  
Author(s):  
Markus Holzweber ◽  
Ralf Lungwitz ◽  
Denise Doerfler ◽  
Stefan Spange ◽  
Mihkel Koel ◽  
...  
Keyword(s):  
Ionic Liquids ◽  
Lewis Acid ◽  
Acid Base
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