Iodide reagent controlled reaction pathway of iodoperoxidation of alkenes: a high regioselectivity synthesis of α- and β-iodoperoxidates under solvent-free conditions

2018 ◽  
Vol 20 (10) ◽  
pp. 2225-2230 ◽  
Author(s):  
Xiaofang Gao ◽  
Hongling Yang ◽  
Chen Cheng ◽  
Qi Jia ◽  
Fang Gao ◽  
...  
Keyword(s):  
Reaction Pathway ◽  
Environmentally Friendly ◽  
Solvent Free ◽  
Solvent Free Conditions

A highly atom-economical, efficient and environmentally friendly iodoperoxidation of alkenes with TBHP and iodide/iodine is reported.

scholarly journals Homocoupling of terminal alkynes catalyzed by CuCl under solvent-free conditions

2021 ◽  
pp. 174751982110325
Author(s):  
Yan Xiao ◽  
Jiyu Gao ◽  
Peng Chen ◽  
Guangliang Chen ◽  
Zicheng Li ◽  
...  
Keyword(s):  
Functional Group ◽  
Reaction Times ◽  
Environmentally Friendly ◽  
Solvent Free ◽  
Copper Salt ◽  
Terminal Alkynes ◽  
Mild Conditions ◽  
Solvent Free Conditions ◽  
Environmentally Friendly Process

A series of symmetrical 1,4-disubstituted buta-1,3-diynes is prepared with excellent yields (up to 95%) through homocoupling of terminal alkynes catalyzed by a copper salt under solvent-free conditions. This method provides an environmentally friendly process to prepare 1,3-diynes in short reaction times under mild conditions. Furthermore, the method is suitable for a wide substrate scope and has excellent functional group compatibility. The reaction can also be scaled up to gram level.

Environmentally friendly cyclotrimerization of substituted acetophenones catalyzed by a new nanocomposite of γ-Al2O3 nanoparticles decorated with H5PW10V2O40

RSC Advances ◽  
2016 ◽  
Vol 6 (60) ◽  
pp. 55319-55326 ◽  
Author(s):  
Reza Tayebee ◽  
Kokab Savoji ◽  
Maryam Kargar Razi ◽  
Behrooz Maleki
Keyword(s):  
Environmentally Friendly ◽  
Solvent Free ◽  
Reusable Catalyst ◽  
Al2o3 Nanoparticles ◽  
Solvent Free Conditions

An efficient protocol for the synthesis of C3-symmetrical 1,3,5-triarylbenzenes under solvent-free conditions. γ-Al2O3/H5PW10V2O40 nanocomposite is introduced as a highly reusable catalyst.

scholarly journals ZnO Nanoparticles: A Highly Effective and Readily Recyclable Catalyst for the One-Pot Synthesis of 1,8-dioxo-decahydroacridine and 1,8-dioxooctahydro-xanthene Derivatives

2017 ◽  
Vol 57 (1) ◽  
Author(s):  
Javad Safaei-Ghomi ◽  
Mohammad Ali Ghasemzadeh ◽  
Safura Zahedi
Keyword(s):  
Zno Nanoparticles ◽  
Environmentally Friendly ◽  
Recyclable Catalyst ◽  
Solvent Free ◽  
One Pot ◽  
One Pot Synthesis ◽  
Solvent Free Conditions ◽  
Xanthene Derivatives ◽  
Highly Effective ◽  
The One

ZnO nanoparticles as a worthwhile and recyclable catalyst have been used for the one-pot synthesis of 1,8-dioxo-decahydroacridines and 1,8-dioxooctahydro-xanthenes via multi-component reactions under solvent-free conditions. The presented method is mild, environmentally friendly, inexpensive and highly effective to give the products in good to excellent yields.

scholarly journals Nano-Fe3O4@walnut shell/Cu(ii) as a highly effective environmentally friendly catalyst for the one-pot pseudo three-component synthesis of 1,3-oxazine derivatives under solvent-free conditions

RSC Advances ◽  
2020 ◽  
Vol 10 (53) ◽  
pp. 31874-31880
Author(s):  
Arefeh Dehghani Tafti ◽  
Bi Bi Fatemeh Mirjalili
Keyword(s):  
Alkaline Medium ◽  
Environmentally Friendly ◽  
Solvent Free ◽  
Walnut Shell ◽  
One Pot ◽  
Nano Catalyst ◽  
Solvent Free Conditions ◽  
Highly Effective ◽  
Nano Fe3o4 ◽  
The One

Fe3O4@walnut shell/Cu(ii) as an eco-friendly bio-based magnetic nano-catalyst was prepared by adding CuCl2 to Fe3O4@walnut shell in alkaline medium.

Thermochemical transformation in the single-step synthesis of zeolitic imidazole frameworks under solvent-free conditions

2020 ◽  
Vol 49 (9) ◽  
pp. 2811-2818
Author(s):  
Guangyong Shi ◽  
Wei Xu ◽  
Jichao Wang ◽  
Nikom Klomkliang ◽  
Bibimaryam Mousavi ◽  
...  
Keyword(s):  
Thermal Treatment ◽  
Environmentally Friendly ◽  
Single Step ◽  
Solvent Free ◽  
Thermochemical Transformation ◽  
Solvent Free Conditions ◽  
Zeolitic Imidazole Frameworks

An environmentally friendly and economical route for the synthesis of zeolitic imidazole frameworks (ZIFs) was developed based on the thermal treatment of mixed solid precursors in the absence of solvent and additive compounds.

Mild, efficient, and environmentally friendly synthesis of symmetrical N,N′-alkylidenebisamides under solvent-free conditions catalyzed by H7[(P2W17O61)FeIII(H2O)]

RSC Advances ◽  
2016 ◽  
Vol 6 (25) ◽  
pp. 20687-20694 ◽  
Author(s):  
R. Tayebee ◽  
B. Maleki ◽  
F. M. Zonoz ◽  
R. M. Kakhki ◽  
T. Kunani
Keyword(s):  
Environmentally Friendly ◽  
Solvent Free ◽  
One Pot ◽  
Effective Catalyst ◽  
One Pot Synthesis ◽  
Solvent Free Conditions ◽  
Noticeable Reduction ◽  
The One

H7[(P2W17O61)FeIII(H2O)] is introduced as an effective catalyst for the one-pot synthesis ofN,N′-alkylidenebisamides. The catalyst could be easily separated without noticeable reduction in activity.

Environmentally Friendly Organic Synthesis Using Bismuth Compounds. Bismuth Trifluoromethanesulfonate-Catalyzed Allylation of Dioxolanes

2008 ◽  
Vol 61 (6) ◽  
pp. 419 ◽  
Author(s):  
Matthew J. Spafford ◽  
James E. Christensen ◽  
Matthew G. Huddle ◽  
Joshua R. Lacey ◽  
Ram S. Mohan
Keyword(s):  
Organic Synthesis ◽  
Multicomponent Reaction ◽  
Scale Up ◽  
Environmentally Friendly ◽  
Solvent Free ◽  
Bismuth Compounds ◽  
Solvent Free Conditions ◽  
In Situ Derivatization

A bismuth trifluoromethanesulfonate (triflate)-catalyzed (2.0 mol-%) multicomponent reaction involving the allylation of dioxolanes followed by in situ derivatization with anhydrides to generate highly functionalized esters has been developed under solvent-free conditions. Most reagents used to date for allylation of dioxolanes are highly corrosive and are often required in stoichiometric amounts. In contrast, the use of a relatively non-toxic and non-corrosive bismuth(iii)-based catalyst makes this methodology especially attractive for scale-up.

ChemInform Abstract: Environmentally Friendly Tetrahydrofuranylation of Alcohols Using NaHSO4-SiO2under Solvent-Free Conditions.

ChemInform ◽  
2012 ◽  
Vol 43 (34) ◽  
pp. no-no
Author(s):  
Henok H. Kinfe ◽  
Sullivan Terblanche ◽  
Konanani D. Tshivhase ◽  
Livhuwani Ravhura
Keyword(s):  
Environmentally Friendly ◽  
Solvent Free ◽  
Solvent Free Conditions

scholarly journals Montmorillonite K10-Catalyzed Solvent-Free Conversion of Furfural into Cyclopentenones

Catalysts ◽  
2019 ◽  
Vol 9 (3) ◽  
pp. 301 ◽  
Author(s):  
Sonia Bonacci ◽  
Monica Nardi ◽  
Paola Costanzo ◽  
Antonio De Nino ◽  
Maria Di Gioia ◽  
...  
Keyword(s):  
Reaction Time ◽  
Heterogeneous Catalysis ◽  
Heterogeneous Catalyst ◽  
Environmentally Friendly ◽  
Solvent Free ◽  
Short Reaction Time ◽  
Montmorillonite K10 ◽  
Solvent Free Conditions

A simple and eco-friendly montmorillonite K10 (MK10)-catalyzed method for the synthesis of cyclopentenone derivatives from biomass-produced furfural has been developed. The versatility of this protocol is that the reactions were performed under solvent-free conditions and in a short reaction time under heterogeneous catalysis. Montmorillonite K10 is mostly explored as a heterogeneous catalyst since it is inexpensive and environmentally friendly.

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