scholarly journals Recyclable amine-functionalized magnetic nanoparticles for efficient demulsification of crude oil-in-water emulsions

2018 ◽  
Vol 4 (10) ◽  
pp. 1553-1563 ◽  
Author(s):  
Qing Wang ◽  
Maura C. Puerto ◽  
Sumedh Warudkar ◽  
Jack Buehler ◽  
Sibani L. Biswal

Produced water from the oil and gas industry often contains stable crude oil-in-water emulsions that are typically difficult to treat with conventional separation methods.

Water ◽  
2021 ◽  
Vol 13 (9) ◽  
pp. 1183
Author(s):  
Ashiqur Rahman ◽  
Shanglei Pan ◽  
Cymone Houston ◽  
Thinesh Selvaratnam

Produced water (PW) is the largest waste stream generated by the oil and gas industry. Traditional treatment of PW burdens the industry with significant expenses and environmental issues. Alternatively, microalgal-based bioremediation of PW is often viewed as an ecologically safe and sustainable platform for treating PW. Moreover, the nutrients in PW could support algal growth. However, significant dilution of PW is often required in algal-based systems due to the presence of complex chemical contaminants. In light of these facts, the current work has investigated the potential of cultivating Galdieria sulphuraria and Chlorella vulgaris in PW using multiple dilutions; 0% PW, 5% PW, 10% PW, 20% PW, 50% PW and 100% PW. While both algal strains can grow in PW, the current results indicated that G. sulphuraria has a higher potential of growth in up to 50% PW (total dissolved solids of up to 55 g L−1) with a growth rate of 0.72 ± 0.05 g L−1 d−1 and can achieve a final biomass density of 4.28 ± 0.16 g L−1 in seven days without the need for additional micronutrients. Additionally, the algae showed the potential of removing 99.6 ± 0.2% nitrogen and 74.2 ± 8.5% phosphorus from the PW.


Energies ◽  
2021 ◽  
Vol 14 (7) ◽  
pp. 1950
Author(s):  
Monika Gajec ◽  
Ewa Kukulska-Zając ◽  
Anna Król

Significant amounts of produced water, spent drilling fluid, and drill cuttings, which differ in composition and characteristics in each drilling operation, are generated in the oil and gas industry. Moreover, the oil and gas industry faces many technological development challenges to guarantee a safe and clean environment and to meet strict environmental standards in the field of processing and disposal of drilling waste. Due to increasing application of nanomaterials in the oil and gas industry, drilling wastes may also contain nanometer-scale materials. It is therefore necessary to characterize drilling waste in terms of nanomaterial content and to optimize effective methods for their determination, including a key separation step. The purpose of this study is to select the appropriate method of separation and pre-concentration of silver nanoparticles (AgNPs) from drilling wastewater samples and to determine their size distribution along with the state of aggregation using single-particle inductively coupled plasma mass spectrometry (spICP-MS). Two AgNP separation methods were compared: centrifugation and cloud point extraction. The first known use of spICP-MS for drilling waste matrices following mentioned separation methods is presented.


2021 ◽  
Vol 2021 ◽  
pp. 1-15
Author(s):  
Roselaine Facanali ◽  
Nathália de A. Porto ◽  
Juliana Crucello ◽  
Rogerio M. Carvalho ◽  
Boniek G. Vaz ◽  
...  

Naphthenic acids (NAs) are compounds naturally present in most petroleum sources comprised of complex mixtures with a highly variable composition depending on their origin. Their occurrence in crude oil can cause severe corrosion problems and catalysts deactivation, decreasing oil quality and consequently impacting its productivity and economic value. NAs structures also allow them to behave as surfactants, causing the formation and stabilization of emulsions. In face of the ongoing challenge of treatment of water-in-oil (W/O) or oil-in-water (O/W) emulsions in the oil and gas industry, it is important to understand how NAs act in emulsified systems and which acids are present in the interface. Considering that, this review describes the properties of NAs, their role in the formation and stability of oil emulsions, and the modern analytical methods used for the qualitative analysis of such acids.


2021 ◽  
Author(s):  
Afrah AlEdan ◽  
Tohid Erfani

<p>Currently, oil and gas industry dispose the produced water under the ground without treatment and with minimal consideration on the beneficial reuse applications. Yet, in recent years and in response to the worldwide water shortage concerns, produced water management and treatment has gained more attention and interest. Managing produced water is subject to different limitations specially if it is done for offsite applications. This includes the consideration of transportation cost and removal of dispersed and dissolved oil, metals, ammonia, salinity, alkalinity and ion toxicity for human and agricultural use which can result in a greater economic cost in terms of chemical usage and desalination operations. The importance of properly managing produced water is mainly rely on the clear vision of the treating method used which must be defined based on regulatory parameters and reuse standards. This study investigates mathematical modelling and optimisation to include the reuse specification into the produced water quality management and discusses its implication.</p>


2020 ◽  
Vol 20 (2020) ◽  
pp. 102-103
Author(s):  
Thuanny Moraes De Almeida ◽  
Emiliane Daher Pereira ◽  
Fabiola da Silveira Maranhão ◽  
Fernando Gomes De Souza Junior ◽  
Romildo Dias Toledo Filho ◽  
...  

Author(s):  
Lisa M. Gieg ◽  
Mohita Sharma ◽  
Trevor Place ◽  
Jennifer Sargent ◽  
Yin Shen

Abstract Corrosion of carbon steel infrastructure in the oil and gas industry can occur via a variety of chemical, physical, and/or microbiological mechanisms. Although microbial corrosion is known to lead to infrastructure failure in many upstream and downstream operations, predicting when and how microorganisms attack metal surfaces remains a challenge. In crude oil transmission pipelines, a kind of aggressive corrosion known as under deposit corrosion (UDC) can occur, wherein mixtures of solids (sands, clays, inorganic minerals), water, oily hydrocarbons, and microorganisms form discreet, (bio)corrosive sludges on the metal surface. To prevent UDC, operators will use physical cleaning methods (e.g., pigging) combined with chemical treatments such as biocides, corrosion inhibitors, and/or biodispersants. As such, it necessary to evaluate the efficacy of these treatments in preventing UDC by monitoring the sludge characteristics and the microorganisms that are potentially involved in the corrosion process. The efficacies of a biocide, corrosion inhibitor, and biodispersant being used to prevent microbial corrosion in a crude oil transmission pipeline were evaluated. A combination of various microbiological analyses and corrosivity tests were performed using sludge samples collected during pigging operations. The results indicated that the combined treatment using inhibitor, biocide 1 and biodispersant was the most effective in preventing metal damage, and both growth-based and Next-Generation Sequencing approaches provided value towards understanding the effects of the chemical treatments. The efficacy of a different biocide (#2) could be discriminated using these test methods. The results of this study demonstrate the importance of considering and monitoring for microbial corrosion of crucial metal infrastructure in the oil and gas industry, and the value of combining multiple lines of evidence to evaluate the performance of different chemical treatment scenarios.


2019 ◽  
Vol 37 (4) ◽  
pp. 425
Author(s):  
Alvaro Morelos-Moreno ◽  
José Fernando Martel-Valles ◽  
América Berenice Morales-Díaz ◽  
Rahim Foroughbakhch-Pournavab ◽  
Isidro Morales ◽  
...  

Oil and gas industry produces wastewater (produced water), which contains hydrocarbons, heavy metals, and other components, such as mineral salts essential for plant nutrition. Hydrocarbons presence on produced water limits its potential use in the agriculture, as its lead to inhibition of plant growth. The present study aimed to investigate the effect of hydrocarbons analogous contained in the produced water on 1) pH and electrical conductivity (EC) of irrigation leachate, 2) plant´s morphological variables, 3) mineral concentration, 4) fruit pH, EC and total dissolved solids (TDS), during flowering and fruiting stages in tomato grown into greenhouse conditions. As source of produced water were used diesel at concentrations of 20 and 25 mg L‑1, gasoline at 40, 50 and 60 mg L-1, and benzene at 75 mg L-1, applied in the substrate by means of a syringe. All plants treated with hydrocarbons reached the fruit setting and ripening stage at the 6-cluster. Depending on their type, concentration, and exposure time, hydrocarbons modif ied the pH and EC of the irrigation leachate, caused signif icant morphological changes with longer exposure time, and restricted the biomass production. Mineral concentration differed signif icantly among plant organs, affecting mainly the sodium uptake in stems and fruits. The variables of fruit quality, EC and TDS were favorably modif ied by most treatments.


Water ◽  
2021 ◽  
Vol 13 (24) ◽  
pp. 3573
Author(s):  
Hana D. Dawoud ◽  
Haleema Saleem ◽  
Nasser Abdullah Alnuaimi ◽  
Syed Javaid Zaidi

Qatar is one of the major natural gas (NG) producing countries, which has the world’s third-largest NG reserves besides the largest supplier of liquefied natural gas (LNG). Since the produced water (PW) generated in the oil and gas industry is considered as the largest waste stream, cost-effective PW management becomes fundamentally essential. The oil/gas industries in Qatar produce large amounts of PW daily, hence the key challenges facing these industries reducing the volume of PW injected in disposal wells by a level of 50% for ensuring the long-term sustainability of the reservoir. Moreover, it is important to study the characteristics of PW to determine the appropriate method to treat it and then use it for various applications such as irrigation, or dispose of it without harming the environment. This review paper targets to highlight the generation of PW in Qatar, as well as discuss the characteristics of chemical, physical, and biological treatment techniques in detail. These processes and methods discussed are not only applied by Qatari companies, but also by other companies associated or in collaboration with those in Qatar. Finally, case studies from different companies in Qatar and the challenges of treating the PW are discussed. From the different studies analyzed, various techniques as well as sequencing of different techniques were noted to be employed for the effective treatment of PW.


Author(s):  
Andressa Simões ◽  
Roberto Macêdo-Júnior ◽  
Brenda Santos ◽  
Lucas Silva ◽  
Daniel Silva ◽  
...  

Produced water is one of the single most significant waste streams in the oil and gas industry, and because it is a residue of complex chemical composition, it can't be simply discarded in the environment, it should receive appropriate treatments before. This paper presents a mapping of the quantitative evolution, referring to the leading publications on the study of water produced with a focus on treatments. A bibliometric method was then adopted to build a structured database with the selected articles and then analyzed the number of publications, countries, areas of impact, authors, keywords, periodicals, and affiliations. The thematic has proved to be an essential line of research over the years. The analysis was considered in the period between 1969 and 2017. Several indicators were observed regarding the development of academic and technological research on water produced as well as its treatment processes. The study was performed in the Scopus database search engine to gather data, and 2434 documents were identified, with 851 articles investigated more specifically. This paper highlights the need for constant future studies about the produced water to minimize not only pollution but also reduce operating costs.


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