Experimental and theoretical investigations on Se(iv) and Se(vi) adsorption to UiO-66-based metal–organic frameworks

2018 ◽  
Vol 5 (6) ◽  
pp. 1441-1453 ◽  
Author(s):  
Jingmiao Wei ◽  
Wei Zhang ◽  
Weiyi Pan ◽  
Chaoran Li ◽  
Weiling Sun
Keyword(s):  
Hydrogen Bonding ◽  
Lewis Acid ◽  
Metal Organic Frameworks ◽  
Acid Base ◽  
Theoretical Investigations ◽  
Metal Organic

HSeO3−/SeO32− bonds to UiO-66 on Zr mainly through Lewis acid/base complexation and H2SeO3 bonds on Zr–O–C mainly through hydrogen bonding.

Heteroaggregation behavior of graphene oxide on Zr-based metal–organic frameworks in aqueous solutions: a combined experimental and theoretical study

2017 ◽  
Vol 5 (38) ◽  
pp. 20398-20406 ◽  
Author(s):  
Jie Li ◽  
Qunyan Wu ◽  
Xiangxue Wang ◽  
Zhifang Chai ◽  
Weiqun Shi ◽  
...  
Keyword(s):  
Hydrogen Bonding ◽  
Graphene Oxide ◽  
Aqueous Solutions ◽  
Theoretical Study ◽  
Metal Organic Frameworks ◽  
Acid Base ◽  
Π Interactions ◽  
Metal Organic

Electrostatic attractions combined with the non-negligible π–π interactions, hydrogen bonding and acid–base interactions lead to the heteroaggregation between GO and Zr based MOFs.

scholarly journals Metal-Organic Framework Thin Films as Versatile Chemical Sensing Materials

2021 ◽  
Author(s):  
James Ellis ◽  
Scott Crawford ◽  
Ki-Joong Kim
Keyword(s):  
Thin Films ◽  
Optical Properties ◽  
Lewis Acid ◽  
Chemical Sensing ◽  
Metal Organic Framework ◽  
Metal Organic Frameworks ◽  
Acid Base ◽  
Metal Organic ◽  
Organic Framework

Metal-organic frameworks (MOFs) have been widely investigated as chemical sensing materials due to their periodic porosity, tunable chemical functionalities such as Lewis acid/base sites, potential conductivity and/or sensitive optical properties....

scholarly journals Hf-based metal–organic frameworks as acid–base catalysts for the transformation of biomass-derived furanic compounds into chemicals

2018 ◽  
Vol 20 (13) ◽  
pp. 3081-3091 ◽  
Author(s):  
Sergio Rojas-Buzo ◽  
Pilar García-García ◽  
Avelino Corma
Keyword(s):  
Aldol Condensation ◽  
Condensation Reaction ◽  
Metal Organic Frameworks ◽  
Acid Base ◽  
Base Catalysts ◽  
Metal Organic ◽  
Furanic Compounds

Hafnium-based metal–organic frameworks are promising catalysts for upgrading biomass derivatives via an aldol condensation reaction.

One-pot synthesis of bimetallic metal–organic frameworks (MOFs) as acid–base bifunctional catalysts for tandem reaction

2020 ◽  
Vol 10 (2) ◽  
pp. 315-322 ◽  
Author(s):  
Yanjing Hu ◽  
Jian Zhang ◽  
Hang Huo ◽  
Zhe Wang ◽  
Xianzhu Xu ◽  
...  
Keyword(s):  
Metal Organic Frameworks ◽  
Bifunctional Catalysts ◽  
Pore System ◽  
Acid Base ◽  
One Pot ◽  
System P ◽  
Synergistic Mechanism ◽  
Metal Organic ◽  
Hierarchical Pore System ◽  
Hierarchical Pore

Bimetallic MIL-101(Al/Fe)–NH2 exhibits enhanced acid–base bifunctional catalytic activity due to its synergistic mechanism and hierarchical pore system.

Multiferroic Behavior Associated with an Order−Disorder Hydrogen Bonding Transition in Metal−Organic Frameworks (MOFs) with the Perovskite ABX3Architecture

2009 ◽  
Vol 131 (38) ◽  
pp. 13625-13627 ◽  
Author(s):  
Prashant Jain ◽  
Vasanth Ramachandran ◽  
Ronald J. Clark ◽  
Hai Dong Zhou ◽  
Brian H. Toby ◽  
...  
Keyword(s):  
Hydrogen Bonding ◽  
Metal Organic Frameworks ◽  
Metal Organic

Anion Coordination in Metal−Organic Frameworks Functionalized with Urea Hydrogen-Bonding Groups

2006 ◽  
Vol 6 (2) ◽  
pp. 555-563 ◽  
Author(s):  
Radu Custelcean ◽  
Bruce A. Moyer ◽  
Vyacheslav S. Bryantsev ◽  
Benjamin P. Hay
Keyword(s):  
Hydrogen Bonding ◽  
Metal Organic Frameworks ◽  
Anion Coordination ◽  
Metal Organic

scholarly journals Two metal–organic frameworks based on Sr2+ and 1,2,4,5-tetrakis(4-carboxyphenyl)benzene linkers

2021 ◽  
Vol 77 (12) ◽  
Author(s):  
Muhammad Usman ◽  
Lydia Ogebule ◽  
Raúl Castañeda ◽  
Evgenii Oskolkov ◽  
Tatiana Timofeeva
Keyword(s):  
Hydrogen Bonding ◽  
Single Crystal ◽  
Crystal Structures ◽  
Structural Control ◽  
Metal Organic Frameworks ◽  
X Ray Diffraction ◽  
X Ray ◽  
Metal Organic ◽  
Solvent Systems ◽  
Semiconductor Properties

Two structurally different metal–organic frameworks based on Sr2+ ions and 1,2,4,5-tetrakis(4-carboxyphenyl)benzene linkers have been synthesized solvothermally in different solvent systems and studied with single-crystal X-ray diffraction technique. These are poly[[μ12-4,4′,4′′,4′′′-(benzene-1,2,4,5-tetrayl)tetrabenzoato](dimethylformamide)distrontium(II)], [Sr2(C34H18O8)(C3H7NO)2] n , and poly[tetraaqua{μ2-4,4′-[4,5-bis(4-carboxyphenyl)benzene-1,2-diyl]dibenzoato}tristrontium(II)], [Sr3(C34H20O8)2(H2O)4]. The differences are noted between the crystal structures and coordination modes of these two MOFs, which are responsible for their semiconductor properties, where structural control over the bandgap is desirable. Hydrogen bonding is present in only one of the compounds, suggesting it has a slightly higher structural stability.

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