Degradation of polyethylene glycols and polypropylene glycols in microcosms simulating a spill of produced water in shallow groundwater

2019 ◽  
Vol 21 (2) ◽  
pp. 256-268 ◽  
Author(s):  
Jessica D. Rogers ◽  
E. Michael Thurman ◽  
Imma Ferrer ◽  
James S. Rosenblum ◽  
Morgan V. Evans ◽  
...  
Keyword(s):  
Polyethylene Glycol ◽  
Groundwater Contamination ◽  
Produced Water ◽  
Degradation Products ◽  
Shallow Groundwater ◽  
Polyethylene Glycols ◽  
Polypropylene Glycol

Polyethylene glycol, polypropylene glycol, and their degradation products could be utilized to better characterize shallow groundwater contamination following a spill of produced water.

Europium and cerium extraction by the nitrobenzene solution of dicarbolide in the presence of polyethylene glycols

1986 ◽  
Vol 51 (3) ◽  
pp. 498-515 ◽  
Author(s):  
Emanuel Makrlík ◽  
Petr Vaňura
Keyword(s):  
Molecular Weight ◽  
Polyethylene Glycol ◽  
Organic Phase ◽  
Perchloric Acid ◽  
Equilibrium Constants ◽  
Polyethylene Glycols ◽  
Individual Species ◽  
Nitrobenzene Solution ◽  
Separation Factors ◽  
Equilibrium Data

Extraction of Eu3+ and Ce3+ microamounts from 0.1-0.4M perchloric acid by the nitrobenzene solution of dicarbolide H+[Co(C2B9H11)2]- in the presence of polyethylene glycols (Mr = 200, 300, 400) has been studied. The equilibrium data and the typical maxima on the dependence of the metal distribution ratio on the total analytical concentration of polyethylene glycol in the system can be explained assuming that the species ML3+org, ML3+2org, ML3+3org, MLH2+-1org, and HL+org (where M3+ = Eu3+, Ce3+; L = polyethylene glycol) are extracted into the organic phase. The values of extraction and equilibrium constants in the organic phase were determined and the effect of the polyethylene glycol molecular weight on the equilibrium constants and on the abundances of individual species in the organic phase is discussed. It has been found that the addition of polyethylene glycol to the acid - nitrobezene - dicarbolide system increases the values of the separation factors αCe/Eu.

Extraction of polyethylene glycols with dicarbolide solutions in nitrobenzene

1990 ◽  
Vol 55 (8) ◽  
pp. 1959-1967 ◽  
Author(s):  
Petr Vaňura ◽  
Pavel Selucký
Keyword(s):  
Polyethylene Glycol ◽  
Molecular Mass ◽  
Extraction Constant ◽  
Metal Extraction ◽  
Polyethylene Glycols ◽  
Relative Molecular Mass ◽  
Published Data ◽  
Average Molecular Mass ◽  
Peg 400 ◽  
Extraction Constants

The extraction of polyethylene glycol of average molecular mass 400 (PEG 400) with dicarbolide solution in nitrobenzene and of longer-chain polyethylene glycol, of average molecular mass 1 500 (PEG 1 500), with chlorinated dicarbolide solution in nitrobenzene was studied. During the extraction of PEG 400, the polyethylene glycol solvates the Horg+ ion in the organic phase giving rise to the HLorg+ species (L is polyethylene glycol). The obtained value of the extraction constant Kex(HLorg+) = 933 is consistent with published data of metal extraction. Extraction of PEG 1 500 was treated applying the simplified assumption that the thermodynamic behaviour of PEG 1 500 is the same as that of n molecules of polyethylene glycol with relative molecular mass 1 500/n, each solvating one cation. For this model, the value of n = 3.2 ± 1.1 and the values of the extraction constants of the HL1/n,org+ and HL2/n,org+ species were obtained by using the adapted program LETAGROP. This value of n is consistent with published extraction data in the presence of polyethylene glycol with a relative molecular mass from 200 to 1 000.

scholarly journals Using intrinsic vulnerability and anthropogenic impacts to evaluate and compare groundwater risk potential at northwestern and western coastal aquifers of Sri Lanka through coupling DRASTIC and GIS approach

2021 ◽  
Vol 11 (7) ◽  
Author(s):  
Ratha Phok ◽  
Nandalal Kosgallana Duwage Wasantha ◽  
Weerakoon Sumana Bandara ◽  
Pitawala Herath Mudiyanselage Thalapitiye Ge ◽  
Dharmagunawardhane Hingure Arachchilage
Keyword(s):  
Sri Lanka ◽  
Groundwater Contamination ◽  
Anthropogenic Impacts ◽  
Shallow Groundwater ◽  
Monitoring Network ◽  
Groundwater Vulnerability ◽  
Moderate Risk ◽  
Pollution Risk ◽  
Intrinsic Vulnerability ◽  
Contamination Risk

AbstractGroundwater vulnerability assessment has become a crucial step in successfully protecting groundwater against pollution. An attempt of this study has been made to evaluate groundwater contamination risk using intrinsic vulnerability and land-uses in Vanathavillu, Kalpitiya and Katana area in Sri Lanka, using coupled DRASTIC with GIS as feasible methodology. The findings reveal that the groundwater in the areas under study falls under very low to high contamination risk. The higher risk of contamination has been identified in most of the Kalpitiya (about 82%) with the moderate along the beach in the west and next to Puttalam lagoon in the northeast and southeast. This is mainly due to pollution risk inherent with intense vegetable cultivation, over pumping, shallow groundwater tables and permeable sandy soil. Vanathavillu is under very low to moderate contamination risk, in which the moderate risk (about 13%) has especially been found the center, central southwest and west of the area. The relative less deep groundwater tables, possible seepage from the underlying limestone aquifer and less permeable red earth soil could be cause for the moderate risk in the area. Furthermore, results show that the Katana has low to moderately high groundwater contamination risk. Nitrate has a good agreement with the different pollution risk classes and that nitrate can be used as an indicator of aquifer degradation inherent with land-use activities in the coastal areas. Groundwater quality monitoring network should be set up to minimize the anthropogenic acts, particularly in high and moderate contamination risk zones.

scholarly journals Development of Antifouling Polysulfone Membranes by Synergistic Modification with Two Different Additives in Casting Solution and Coagulation Bath: Synperonic F108 and Polyacrylic Acid

Materials ◽  
2022 ◽  
Vol 15 (1) ◽  
pp. 359
Author(s):  
Katsiaryna S. Burts ◽  
Tatiana V. Plisko ◽  
Mikael Sjölin ◽  
Goncalo Rodrigues ◽  
Alexandr V. Bildyukevich ◽  
...  
Keyword(s):  
Polyethylene Glycol ◽  
Polyacrylic Acid ◽  
Process Water ◽  
Coagulation Bath ◽  
Interpolymer Complex ◽  
Polypropylene Glycol ◽  
Layer Surface ◽  
Membrane Modification ◽  
Selective Layer ◽  
Casting Solution

This study deals with the development of antifouling ultrafiltration membranes based on polysulfone (PSF) for wastewater treatment and the concentration and purification of hemicellulose and lignin in the pulp and paper industry. The efficient simple and reproducible technique of PSF membrane modification to increase antifouling performance by simultaneous addition of triblock copolymer polyethylene glycol-polypropylene glycol-polyethylene glycol (Synperonic F108, Mn =14 × 103 g mol−1) to the casting solution and addition of polyacrylic acid (PAA, Mn = 250 × 103 g mol−1) to the coagulation bath is proposed for the first time. The effect of the PAA concentration in the aqueous solution on the PSF/Synperonic F108 membrane structure, surface characteristics, performance, and antifouling stability was investigated. PAA concentrations were varied from 0.35 to 2.0 wt.%. Membrane composition, structure, and topology were investigated by Fourier-transform infrared spectroscopy (FTIR), X-ray photoelectron spectroscopy (XPS), atomic force microscopy (AFM), and scanning electron microscopy (SEM). The addition of PAA into the coagulation bath was revealed to cause the formation of a thicker and denser selective layer with decreasing its pore size and porosity; according to the structural characterization, an interpolymer complex of the two additives was formed on the surface of the PSF membrane. Hydrophilicity of the membrane selective layer surface was shown to increase significantly. The selective layer surface charge was found to become more negative in comparison to the reference membrane. It was shown that PSF/Synperonic F108/PAA membranes are characterized by better antifouling performance in ultrafiltration of humic acid solution and thermomechanical pulp mill (ThMP) process water. Membrane modification with PAA results in higher ThMP process water flux, fouling recovery ratio, and hemicellulose and total lignin rejection compared to the reference PSF/Synperonic F108 membrane. This suggests the possibility of applying the developed membranes for hemicellulose concentration and purification.

Evaluation of β-cyclodextrin–polyethylene glycol as green scale inhibitors for produced-water in shale gas well

Desalination ◽  
2016 ◽  
Vol 377 ◽  
pp. 28-33 ◽  
Author(s):  
Yuan Liu ◽  
Changjun Zou ◽  
Chaoqun Li ◽  
Lang Lin ◽  
Wenjing Chen
Keyword(s):  
Polyethylene Glycol ◽  
Shale Gas ◽  
Produced Water ◽  
Gas Well ◽  
Green Scale Inhibitors
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