scholarly journals The application of hierarchical structures in energy devices: new insights into the design of solid oxide fuel cells with enhanced mass transport

2018 ◽  
Vol 11 (9) ◽  
pp. 2390-2403 ◽  
Author(s):  
Xuekun Lu ◽  
Tao Li ◽  
Antonio Bertei ◽  
Jason I. S. Cho ◽  
Thomas M. M. Heenan ◽  
...  
Keyword(s):  
Fuel Cells ◽  
Mass Transport ◽  
Solid Oxide Fuel Cells ◽  
Phase Inversion ◽  
Hierarchical Structures ◽  
Solid Oxide ◽  
Oxide Fuel ◽  
Flow Physics ◽  
Energy Devices ◽  
Multi Scale

Multi-scale microstructure and flow physics investigations reveal the enhancement of mass transport by hierarchical-structured SOFC anodes fabricated by Phase Inversion.

Effects of Mass Transport on the Performance of Solid Oxide Fuel Cells Composite Electrodes

2006 ◽  
Vol 4 (1) ◽  
pp. 99-106 ◽  
Author(s):  
Marco Cannarozzo ◽  
Simone Grosso ◽  
Gerry Agnew ◽  
Adriana Del Borghi ◽  
Paola Costamagna
Keyword(s):  
Fuel Cells ◽  
Mass Transport ◽  
Solid Oxide Fuel Cells ◽  
Gas Diffusion ◽  
Transport Equations ◽  
Solid Oxide ◽  
The Other ◽  
Oxide Fuel ◽  
Composite Electrodes ◽  
The Impact

Composite electrodes are of great interest in the field of solid oxide fuel cells because their use can improve the performance of these cells. However, an important correlation exists between composition, microstructure, and thickness of an electrode and its performance. This correlation has been investigated in this work using a theoretical model. The model, in order to consider all the losses occurring in an electrode, includes Ohm’s law for ionic and electronic charge transport, and the Butler-Volmer equation to evaluate the activation polarizations, and mass transport equations, taking into account diffusion through porous media, to evaluate the concentration losses. The model shows that the best electrode performance is a trade-off between activation and concentration losses. This is because a decrease in the dimensions of the particles or an increase in its thickness result, on the one hand, in a reduction of the activation polarizations, because of a larger active area for the electrochemical reaction, and, on the other hand, in an increase in the concentration losses due to a more difficult gas diffusion. In particular, in order to understand the impact of concentration losses on the performance of composite electrodes, the simulations have been run with two models, one including and the other one neglecting the mass transport equations. The results show that concentration losses play a role only with thick electrodes composed of small particles, operating at high fuel utilization.

Co-Extrusion / Phase Inversion / Co-Sintering for Fabrication of Hollow Fiber Solid Oxide Fuel Cells

2019 ◽  
Vol 25 (2) ◽  
pp. 665-672 ◽  
Author(s):  
Nicolas D. Droushiotis ◽  
Uttam Doraswami ◽  
Mohd Othman ◽  
Kang Li ◽  
Geoff Kelsall
Keyword(s):  
Fuel Cells ◽  
Solid Oxide Fuel Cells ◽  
Hollow Fiber ◽  
Phase Inversion ◽  
Solid Oxide ◽  
Oxide Fuel
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