scholarly journals Stable solvent for solution-based electrical doping of semiconducting polymer films and its application to organic solar cells

2018 ◽  
Vol 11 (8) ◽  
pp. 2216-2224 ◽  
Author(s):  
Felipe A. Larrain ◽  
Canek Fuentes-Hernandez ◽  
Wen-Fang Chou ◽  
Victor A. Rodriguez-Toro ◽  
Tzu-Yen Huang ◽  
...  

A solution-based method to electrically p-dope organic semiconductors enabling the fabrication of organic solar cells with simplified geometry is implemented with acetonitrile as an alternative to nitromethane.

Author(s):  
Dorota Zając ◽  
Dariusz Przybylski ◽  
Jadwiga Sołoducho

AbstractDeveloping effective and low‐cost organic semiconductors is an opportunity for the development of organic solar cells (OPV). Herein, we report the molecular design, synthesis and characterization of two molecules with D–A–D–A configuration: 2-cyano-3-(5-(8-(3,4-ethylenodioxythiophen-5-yl)-2,3-diphenylquinoxalin-5-yl)thiophen-2-yl)acrylic acid (6) and 2-cyano-3-(5-(2,3-diphenyl-8-(thiophen-2-yl)quinoxalin-5-yl)thiophen-2-yl)acrylic acid (7). Moreover, we investigated the structural, theoretical and optical properties. The distribution of HOMO/LUMO orbitals and the values of the ionization potential indicate good semiconducting properties of the compounds and that they can be a bipolar material. Also, the optical study show good absorption in visible light (λabs 380–550 nm). We investigate the theoretical optoelectronic properties of obtained compounds as potential materials for solar cells.


2015 ◽  
Vol 115 ◽  
pp. 35-49 ◽  
Author(s):  
Sheng-Yi Shiau ◽  
Chun-Ho Chang ◽  
Wei-Jen Chen ◽  
Hsing-Ju Wang ◽  
Ru-Jong Jeng ◽  
...  

2016 ◽  
Vol 845 ◽  
pp. 224-227 ◽  
Author(s):  
Danila Saranin ◽  
Marina Orlova ◽  
Sergey Didenko ◽  
Oleg Rabinovich ◽  
Andrey Kryukov

This article presents the results of research output voltage characteristics of solar cells on an organic basis with the use of P3HT: PCBM system. There were produced organic solar cells in a coating in air, current-voltage characteristics were measured. It was determined the characteristic influence of a substrate cleaning and annealing temperature of layers applied on fill factor and conversion efficiency.


2005 ◽  
Vol 20 (12) ◽  
pp. 3167-3179 ◽  
Author(s):  
Sophie E. Gledhill ◽  
Brian Scott ◽  
Brian A. Gregg

Organic photovoltaic devices are poised to fill the low-cost, low power niche in the solar cell market. Recently measured efficiencies of solid-state organic cells are nudging 5% while Grätzel’s more established dye-sensitized solar cell technology is more than double this. A fundamental understanding of the excitonic nature of organic materials is an essential backbone for device engineering. Bound electron-hole pairs, “excitons,” are formed in organic semiconductors on photo-absorption. In the organic solar cell, the exciton must diffuse to the donor–accepter interface for simultaneous charge generation and separation. This interface is critical as the concentration of charge carriers is high and recombination here is higher than in the bulk. Nanostructured engineering of the interface has been utilized to maximize organic materials properties, namely to compensate the poor exciton diffusion lengths and lower mobilities. Excitonic solar cells have different limitations on their open-circuit photo-voltages due to these high interfacial charge carrier concentrations, and their behavior cannot be interpreted as if they were conventional solar cells. This article briefly reviews some of the differences between excitonic organic solar cells and conventional inorganic solar cells and highlights some of the technical strategies used in this rapidly progressing field, whose ultimate aim is for organic solar cells to be a commercial reality.


2010 ◽  
Vol 16 (S2) ◽  
pp. 1382-1383
Author(s):  
M Pfaff ◽  
E Müller ◽  
MFG Klein ◽  
A Colsmann ◽  
U Lemmer ◽  
...  

Extended abstract of a paper presented at Microscopy and Microanalysis 2010 in Portland, Oregon, USA, August 1 – August 5, 2010.


2020 ◽  
Vol 8 (35) ◽  
pp. 12265-12271
Author(s):  
Jong-Woon Ha ◽  
Hee Su Kim ◽  
Chang Eun Song ◽  
Hea Jung Park ◽  
Do-Hoon Hwang

A new heterocyclic aromatic structure, thieno[3,2-c]quinolin-4(5H)-one (TQO), was designed and synthesized as an electron-accepting building block for donor–acceptor-type copolymers.


Tetrahedron ◽  
2014 ◽  
Vol 70 (36) ◽  
pp. 6235-6240 ◽  
Author(s):  
Jae Kwan Lee ◽  
Jooyoung Kim ◽  
Hyeju Choi ◽  
Kimin Lim ◽  
Kihyung Song ◽  
...  

The theoretical background is an essential part of any experimental work, and unless the understanding of proper theory associated with any experiment, the explanation of results not considered as accomplished. This chapter highlights the related approaches for calculating and explaining the effects of different parameters of the proposed studies. The concepts applied to investigate the microstructural and optoelectrical properties of semiconducting polymer films, Schottky, and heterojunction junctions are discussed and explained.


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