FLP behaviour of cationic titanium complexes with tridentate Cp,O,N-ligands: highly efficient syntheses and activation reactions of C–X bonds (X = Cl, F)
Keyword(s):
Titanium FLPs! Solvent- and catalyst-free Aza-Michael reaction provides β-amino ketones which were employed as ligand precursors for the convenient synthesis of novel cationic titanium complexes with tridentate Cp,O,N-ligand frameworks, which activate C–X bonds in a FLP-like manner.
Catalyst-free, aza-Michael polymerization of hydrazides: polymerizability, kinetics, and mechanistic origin of an α-effect